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Microenvironment reconstitution of highly active Ni single atoms on oxygen-incorporated Mo2C for water splitting

Author

Listed:
  • Mengyun Hou

    (Beijing Institute of Technology)

  • Lirong Zheng

    (Chinese Academy of Sciences)

  • Di Zhao

    (Beijing Institute of Technology)

  • Xin Tan

    (Tsinghua University)

  • Wuyi Feng

    (Beijing Institute of Technology)

  • Jiantao Fu

    (Beijing Institute of Technology)

  • Tianxin Wei

    (Beijing Institute of Technology)

  • Minhua Cao

    (Beijing Institute of Technology)

  • Jiatao Zhang

    (Beijing Institute of Technology)

  • Chen Chen

    (Tsinghua University)

Abstract

The rational design of efficient bifunctional single-atom electrocatalysts for industrial water splitting and the comprehensive understanding of its complex catalytic mechanisms remain challenging. Here, we report a Ni single atoms supported on oxygen-incorporated Mo2C via Ni-O-Mo bridge bonds, that gives high oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) bifunctional activity. By ex situ synchrotron X-ray absorption spectroscopy and electron microscopy, we found that after HER, the coordination number and bond lengths of Ni-O and Ni-Mo (Ni-O-Mo) were all altered, yet the Ni species still remain atomically dispersed. In contrast, after OER, the atomically dispersed Ni were agglomerated into very small clusters with new Ni-Ni (Ni-O-Ni) bonds appeared. Combining experimental results and DFT calculations, we infer the oxidation degree of Mo2C and the configuration of single-atom Ni are both vital for HER or OER. This study provides both a feasible strategy and model to rational design highly efficient electrocatalysts for water electrolysis.

Suggested Citation

  • Mengyun Hou & Lirong Zheng & Di Zhao & Xin Tan & Wuyi Feng & Jiantao Fu & Tianxin Wei & Minhua Cao & Jiatao Zhang & Chen Chen, 2024. "Microenvironment reconstitution of highly active Ni single atoms on oxygen-incorporated Mo2C for water splitting," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45533-3
    DOI: 10.1038/s41467-024-45533-3
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    References listed on IDEAS

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    1. Bryan H. R. Suryanto & Yun Wang & Rosalie K. Hocking & William Adamson & Chuan Zhao, 2019. "Overall electrochemical splitting of water at the heterogeneous interface of nickel and iron oxide," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    2. Zuyun He & Jun Zhang & Zhiheng Gong & Hang Lei & Deng Zhou & Nian Zhang & Wenjie Mai & Shijun Zhao & Yan Chen, 2022. "Activating lattice oxygen in NiFe-based (oxy)hydroxide for water electrolysis," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    3. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    4. Hua Zhou & Yue Ren & Zhenhua Li & Ming Xu & Ye Wang & Ruixiang Ge & Xianggui Kong & Lirong Zheng & Haohong Duan, 2021. "Electrocatalytic upcycling of polyethylene terephthalate to commodity chemicals and H2 fuel," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    5. Haotian Wang & Hyun-Wook Lee & Yong Deng & Zhiyi Lu & Po-Chun Hsu & Yayuan Liu & Dingchang Lin & Yi Cui, 2015. "Bifunctional non-noble metal oxide nanoparticle electrocatalysts through lithium-induced conversion for overall water splitting," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    6. Guangkai Li & Haeseong Jang & Shangguo Liu & Zijian Li & Min Gyu Kim & Qing Qin & Xien Liu & Jaephil Cho, 2022. "The synergistic effect of Hf-O-Ru bonds and oxygen vacancies in Ru/HfO2 for enhanced hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. Kang Jiang & Min Luo & Ming Peng & Yaqian Yu & Ying-Rui Lu & Ting-Shan Chan & Pan Liu & Frank M. F. Groot & Yongwen Tan, 2020. "Dynamic active-site generation of atomic iridium stabilized on nanoporous metal phosphides for water oxidation," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
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    Cited by:

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    2. Siyao Cheng & Daohu Sheng & Soumya Mukherjee & Wei Dong & Yuanbiao Huang & Rong Cao & Aming Xie & Roland A. Fischer & Weijin Li, 2024. "Carbon nanolayer-mounted single metal sites enable dipole polarization loss under electromagnetic field," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

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