IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-44132-y.html
   My bibliography  Save this article

Unconventional polarization fatigue in van der Waals layered ferroelectric ionic conductor CuInP2S6

Author

Listed:
  • Ziwen Zhou

    (Soochow University)

  • Shun Wang

    (Soochow University)

  • Zhou Zhou

    (Soochow University)

  • Yiqi Hu

    (Soochow University)

  • Qiankun Li

    (Soochow University)

  • Jinshuo Xue

    (Soochow University)

  • Zhijian Feng

    (Soochow University)

  • Qingyu Yan

    (Soochow University)

  • Zhongshen Luo

    (Soochow University)

  • Yuyan Weng

    (Soochow University)

  • Rujun Tang

    (Soochow University)

  • Xiaodong Su

    (Soochow University)

  • Fengang Zheng

    (Soochow University)

  • Kazuki Okamoto

    (Tokyo Institute of Technology)

  • Hiroshi Funakubo

    (Tokyo Institute of Technology)

  • Lixing Kang

    (Chinese Academy of Sciences)

  • Liang Fang

    (Soochow University)

  • Lu You

    (Soochow University)

Abstract

Recent progress in two-dimensional ferroelectrics greatly expands the versatility and tunability in van der Waals heterostructure based electronics. However, the switching endurance issue that widely plagues conventional ferroelectrics in practical applications is hitherto unexplored for van der Waals layered ferroelectrics. Herein, we report the observation of unusual polarization fatigue behaviors in van der Waals layered CuInP2S6, which also possesses finite ionic conductivity at room temperature. The strong intertwinement of the short-range polarization switching and long-range ionic movement in conjunction with the van der Waals layered structure gives rise to unique morphological and polarization evolutions under repetitive electric cycles. With the help of concerted chemical, structural, lattice vibrational and dielectric analyses, we unravel the critical role of the synergy of ionic migration and surface oxidation on the anomalous polarization enhancement and the eventual polarization degradation. This work provides a general insight into the polarization fatigue characteristics in ionically-active van der Waals ferroelectrics and delivers potential solutions for the realization of fatigue-free capacitors.

Suggested Citation

  • Ziwen Zhou & Shun Wang & Zhou Zhou & Yiqi Hu & Qiankun Li & Jinshuo Xue & Zhijian Feng & Qingyu Yan & Zhongshen Luo & Yuyan Weng & Rujun Tang & Xiaodong Su & Fengang Zheng & Kazuki Okamoto & Hiroshi F, 2023. "Unconventional polarization fatigue in van der Waals layered ferroelectric ionic conductor CuInP2S6," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-44132-y
    DOI: 10.1038/s41467-023-44132-y
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-44132-y
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-44132-y?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Fei Li & Shujun Zhang & Tiannan Yang & Zhuo Xu & Nan Zhang & Gang Liu & Jianjun Wang & Jianli Wang & Zhenxiang Cheng & Zuo-Guang Ye & Jun Luo & Thomas R. Shrout & Long-Qing Chen, 2016. "The origin of ultrahigh piezoelectricity in relaxor-ferroelectric solid solution crystals," Nature Communications, Nature, vol. 7(1), pages 1-9, December.
    2. B. H. Park & B. S. Kang & S. D. Bu & T. W. Noh & J. Lee & W. Jo, 1999. "Lanthanum-substituted bismuth titanate for use in non-volatile memories," Nature, Nature, vol. 401(6754), pages 682-684, October.
    3. Anton V. Ievlev & Santosh KC & Rama K. Vasudevan & Yunseok Kim & Xiaoli Lu & Marin Alexe & Valentino R. Cooper & Sergei V. Kalinin & Olga S. Ovchinnikova, 2019. "Non-conventional mechanism of ferroelectric fatigue via cation migration," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Jinhyoung Lee & Gunhoo Woo & Jinill Cho & Sihoon Son & Hyelim Shin & Hyunho Seok & Min-Jae Kim & Eungchul Kim & Ziyang Wang & Boseok Kang & Won-Jun Jang & Taesung Kim, 2024. "Free-standing two-dimensional ferro-ionic memristor," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sajid Husain & Isaac Harris & Guanhui Gao & Xinyan Li & Peter Meisenheimer & Chuqiao Shi & Pravin Kavle & Chi Hun Choi & Tae Yeon Kim & Deokyoung Kang & Piush Behera & Didier Perrodin & Hua Guo & Jame, 2024. "Low-temperature grapho-epitaxial La-substituted BiFeO3 on metallic perovskite," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Liya Yang & Houbing Huang & Zengzhe Xi & Limei Zheng & Shiqi Xu & Gang Tian & Yuzhi Zhai & Feifei Guo & Lingping Kong & Yonggang Wang & Weiming Lü & Long Yuan & Minglei Zhao & Haiwu Zheng & Gang Liu, 2022. "Simultaneously achieving giant piezoelectricity and record coercive field enhancement in relaxor-based ferroelectric crystals," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Xiaolei Wang & Zixuan Shang & Chen Zhang & Jiaqian Kang & Tao Liu & Xueyun Wang & Siliang Chen & Haoliang Liu & Wei Tang & Yu-Jia Zeng & Jianfeng Guo & Zhihai Cheng & Lei Liu & Dong Pan & Shucheng Ton, 2023. "Electrical and magnetic anisotropies in van der Waals multiferroic CuCrP2S6," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    4. Yongke Yan & Liwei D. Geng & Hairui Liu & Haoyang Leng & Xiaotian Li & Yu U. Wang & Shashank Priya, 2022. "Near-ideal electromechanical coupling in textured piezoelectric ceramics," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Zhengqian Fu & Xuefeng Chen & Henchang Nie & Yanyu Liu & Jiawang Hong & Tengfei Hu & Ziyi Yu & Zhenqin Li & Linlin Zhang & Heliang Yao & Yuanhua Xia & Zhipeng Gao & Zheyi An & Nan Zhang & Fei Cao & He, 2022. "Atomic reconfiguration among tri-state transition at ferroelectric/antiferroelectric phase boundaries in Pb(Zr,Ti)O3," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    6. Jie Yin & Xiaoming Shi & Hong Tao & Zhi Tan & Xiang Lv & Xiangdong Ding & Jun Sun & Yang Zhang & Xingmin Zhang & Kui Yao & Jianguo Zhu & Houbing Huang & Haijun Wu & Shujun Zhang & Jiagang Wu, 2022. "Deciphering the atomic-scale structural origin for large dynamic electromechanical response in lead-free Bi0.5Na0.5TiO3-based relaxor ferroelectrics," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    7. Hui Liu & Xiaoming Shi & Yonghao Yao & Huajie Luo & Qiang Li & Houbing Huang & He Qi & Yuanpeng Zhang & Yang Ren & Shelly D. Kelly & Krystian Roleder & Joerg C. Neuefeind & Long-Qing Chen & Xianran Xi, 2023. "Emergence of high piezoelectricity from competing local polar order-disorder in relaxor ferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    8. Yuqi Jiang & Mao-Hua Zhang & Chao-Feng Wu & Ze Xu & Zhao Li & Jing-Tong Lu & Hao-Feng Huang & Jia-Jun Zhou & Yi-Xuan Liu & Tianhang Zhou & Wen Gong & Ke Wang, 2024. "Low-field-driven large strain in lead zirconate titanium-based piezoceramics incorporating relaxor lead magnesium niobate for actuation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-44132-y. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.