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The origin of ultrahigh piezoelectricity in relaxor-ferroelectric solid solution crystals

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  • Fei Li

    (Materials Research Institute, Pennsylvania State University
    Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education and International Center for Dielectric Research, Xi’an Jiaotong University)

  • Shujun Zhang

    (Materials Research Institute, Pennsylvania State University
    Institute for Superconducting and Electronic Materials, Australian Institute of Innovative Materials, University of Wollongong)

  • Tiannan Yang

    (Materials Research Institute, Pennsylvania State University)

  • Zhuo Xu

    (Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education and International Center for Dielectric Research, Xi’an Jiaotong University)

  • Nan Zhang

    (Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education and International Center for Dielectric Research, Xi’an Jiaotong University)

  • Gang Liu

    (High Pressure Synergetic Consortium, Geophysical Laboratory, Carnegie Institute of Washington
    Center for High Pressure Science and Technology Advanced Research)

  • Jianjun Wang

    (Materials Research Institute, Pennsylvania State University)

  • Jianli Wang

    (Institute for Superconducting and Electronic Materials, Australian Institute of Innovative Materials, University of Wollongong)

  • Zhenxiang Cheng

    (Institute for Superconducting and Electronic Materials, Australian Institute of Innovative Materials, University of Wollongong)

  • Zuo-Guang Ye

    (Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education and International Center for Dielectric Research, Xi’an Jiaotong University
    Simon Fraser University)

  • Jun Luo

    (TRS Technologies Inc.)

  • Thomas R. Shrout

    (Materials Research Institute, Pennsylvania State University)

  • Long-Qing Chen

    (Materials Research Institute, Pennsylvania State University)

Abstract

The discovery of ultrahigh piezoelectricity in relaxor-ferroelectric solid solution single crystals is a breakthrough in ferroelectric materials. A key signature of relaxor-ferroelectric solid solutions is the existence of polar nanoregions, a nanoscale inhomogeneity, that coexist with normal ferroelectric domains. Despite two decades of extensive studies, the contribution of polar nanoregions to the underlying piezoelectric properties of relaxor ferroelectrics has yet to be established. Here we quantitatively characterize the contribution of polar nanoregions to the dielectric/piezoelectric responses of relaxor-ferroelectric crystals using a combination of cryogenic experiments and phase-field simulations. The contribution of polar nanoregions to the room-temperature dielectric and piezoelectric properties is in the range of 50–80%. A mesoscale mechanism is proposed to reveal the origin of the high piezoelectricity in relaxor ferroelectrics, where the polar nanoregions aligned in a ferroelectric matrix can facilitate polarization rotation. This mechanism emphasizes the critical role of local structure on the macroscopic properties of ferroelectric materials.

Suggested Citation

  • Fei Li & Shujun Zhang & Tiannan Yang & Zhuo Xu & Nan Zhang & Gang Liu & Jianjun Wang & Jianli Wang & Zhenxiang Cheng & Zuo-Guang Ye & Jun Luo & Thomas R. Shrout & Long-Qing Chen, 2016. "The origin of ultrahigh piezoelectricity in relaxor-ferroelectric solid solution crystals," Nature Communications, Nature, vol. 7(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:7:y:2016:i:1:d:10.1038_ncomms13807
    DOI: 10.1038/ncomms13807
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    1. Sajid Husain & Isaac Harris & Guanhui Gao & Xinyan Li & Peter Meisenheimer & Chuqiao Shi & Pravin Kavle & Chi Hun Choi & Tae Yeon Kim & Deokyoung Kang & Piush Behera & Didier Perrodin & Hua Guo & Jame, 2024. "Low-temperature grapho-epitaxial La-substituted BiFeO3 on metallic perovskite," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Ziwen Zhou & Shun Wang & Zhou Zhou & Yiqi Hu & Qiankun Li & Jinshuo Xue & Zhijian Feng & Qingyu Yan & Zhongshen Luo & Yuyan Weng & Rujun Tang & Xiaodong Su & Fengang Zheng & Kazuki Okamoto & Hiroshi F, 2023. "Unconventional polarization fatigue in van der Waals layered ferroelectric ionic conductor CuInP2S6," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Yongke Yan & Liwei D. Geng & Hairui Liu & Haoyang Leng & Xiaotian Li & Yu U. Wang & Shashank Priya, 2022. "Near-ideal electromechanical coupling in textured piezoelectric ceramics," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
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    5. Hui Liu & Xiaoming Shi & Yonghao Yao & Huajie Luo & Qiang Li & Houbing Huang & He Qi & Yuanpeng Zhang & Yang Ren & Shelly D. Kelly & Krystian Roleder & Joerg C. Neuefeind & Long-Qing Chen & Xianran Xi, 2023. "Emergence of high piezoelectricity from competing local polar order-disorder in relaxor ferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Jie Yin & Xiaoming Shi & Hong Tao & Zhi Tan & Xiang Lv & Xiangdong Ding & Jun Sun & Yang Zhang & Xingmin Zhang & Kui Yao & Jianguo Zhu & Houbing Huang & Haijun Wu & Shujun Zhang & Jiagang Wu, 2022. "Deciphering the atomic-scale structural origin for large dynamic electromechanical response in lead-free Bi0.5Na0.5TiO3-based relaxor ferroelectrics," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    7. Zhengqian Fu & Xuefeng Chen & Henchang Nie & Yanyu Liu & Jiawang Hong & Tengfei Hu & Ziyi Yu & Zhenqin Li & Linlin Zhang & Heliang Yao & Yuanhua Xia & Zhipeng Gao & Zheyi An & Nan Zhang & Fei Cao & He, 2022. "Atomic reconfiguration among tri-state transition at ferroelectric/antiferroelectric phase boundaries in Pb(Zr,Ti)O3," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    8. Yuqi Jiang & Mao-Hua Zhang & Chao-Feng Wu & Ze Xu & Zhao Li & Jing-Tong Lu & Hao-Feng Huang & Jia-Jun Zhou & Yi-Xuan Liu & Tianhang Zhou & Wen Gong & Ke Wang, 2024. "Low-field-driven large strain in lead zirconate titanium-based piezoceramics incorporating relaxor lead magnesium niobate for actuation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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