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Precise solid-phase synthesis of CoFe@FeOx nanoparticles for efficient polysulfide regulation in lithium/sodium-sulfur batteries

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Listed:
  • Yanping Chen

    (Chinese Academy of Sciences)

  • Yu Yao

    (University of Science and Technology of China)

  • Wantong Zhao

    (Taiyuan University of Technology)

  • Lifeng Wang

    (University of Science and Technology of China)

  • Haitao Li

    (Chinese Academy of Sciences)

  • Jiangwei Zhang

    (Inner Mongolia University)

  • Baojun Wang

    (Taiyuan University of Technology)

  • Yi Jia

    (Zhejiang University of Technology)

  • Riguang Zhang

    (Taiyuan University of Technology)

  • Yan Yu

    (University of Science and Technology of China)

  • Jian Liu

    (Chinese Academy of Sciences
    Inner Mongolia University
    University of Surrey
    University of Chinese Academy of Sciences)

Abstract

Complex metal nanoparticles distributed uniformly on supports demonstrate distinctive physicochemical properties and thus attract a wide attention for applications. The commonly used wet chemistry methods display limitations to achieve the nanoparticle structure design and uniform dispersion simultaneously. Solid-phase synthesis serves as an interesting strategy which can achieve the fabrication of complex metal nanoparticles on supports. Herein, the solid-phase synthesis strategy is developed to precisely synthesize uniformly distributed CoFe@FeOx core@shell nanoparticles. Fe atoms are preferentially exsolved from CoFe alloy bulk to the surface and then be carburized into a FexC shell under thermal syngas atmosphere, subsequently the formed FexC shell is passivated by air, obtaining CoFe@FeOx with a CoFe alloy core and a FeOx shell. This strategy is universal for the synthesis of MFe@FeOx (M = Co, Ni, Mn). The CoFe@FeOx exhibits bifunctional effect on regulating polysulfides as the separator coating layer for Li-S and Na-S batteries. This method could be developed into solid-phase synthetic systems to construct well distributed complex metal nanoparticles.

Suggested Citation

  • Yanping Chen & Yu Yao & Wantong Zhao & Lifeng Wang & Haitao Li & Jiangwei Zhang & Baojun Wang & Yi Jia & Riguang Zhang & Yan Yu & Jian Liu, 2023. "Precise solid-phase synthesis of CoFe@FeOx nanoparticles for efficient polysulfide regulation in lithium/sodium-sulfur batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42941-9
    DOI: 10.1038/s41467-023-42941-9
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    References listed on IDEAS

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    2. Yadong Yin & A. Paul Alivisatos, 2005. "Colloidal nanocrystal synthesis and the organic–inorganic interface," Nature, Nature, vol. 437(7059), pages 664-670, September.
    3. Sangwook Joo & Ohhun Kwon & Kyeounghak Kim & Seona Kim & Hyunmin Kim & Jeeyoung Shin & Hu Young Jeong & Sivaprakash Sengodan & Jeong Woo Han & Guntae Kim, 2019. "Cation-swapped homogeneous nanoparticles in perovskite oxides for high power density," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
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