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Intrinsic 1 $${T}^{{\prime} }$$ T ′ phase induced in atomically thin 2H-MoTe2 by a single terahertz pulse

Author

Listed:
  • Jiaojian Shi

    (Massachusetts Institute of Technology)

  • Ya-Qing Bie

    (Massachusetts Institute of Technology
    Sun Yat-sen University)

  • Alfred Zong

    (Massachusetts Institute of Technology
    University of California)

  • Shiang Fang

    (Harvard University
    Rutgers University
    Massachusetts Institute of Technology)

  • Wei Chen

    (Harvard University)

  • Jinchi Han

    (Massachusetts Institute of Technology
    Peking University)

  • Zhaolong Cao

    (Sun Yat-sen University)

  • Yong Zhang

    (Massachusetts Institute of Technology)

  • Takashi Taniguchi

    (National Institute for Materials Science)

  • Kenji Watanabe

    (National Institute for Materials Science)

  • Xuewen Fu

    (Nankai University)

  • Vladimir Bulović

    (Massachusetts Institute of Technology)

  • Efthimios Kaxiras

    (Harvard University)

  • Edoardo Baldini

    (The University of Texas at Austin)

  • Pablo Jarillo-Herrero

    (Massachusetts Institute of Technology)

  • Keith A. Nelson

    (Massachusetts Institute of Technology)

Abstract

The polymorphic transition from 2H to 1 $${T}^{{\prime} }$$ T ′ -MoTe2, which was thought to be induced by high-energy photon irradiation among many other means, has been intensely studied for its technological relevance in nanoscale transistors due to the remarkable improvement in electrical performance. However, it remains controversial whether a crystalline 1 $${T}^{{\prime} }$$ T ′ phase is produced because optical signatures of this putative transition are found to be associated with the formation of tellurium clusters instead. Here we demonstrate the creation of an intrinsic 1 $${T}^{{\prime} }$$ T ′ lattice after irradiating a mono- or few-layer 2H-MoTe2 with a single field-enhanced terahertz pulse. Unlike optical pulses, the low terahertz photon energy limits possible structural damages. We further develop a single-shot terahertz-pump-second-harmonic-probe technique and reveal a transition out of the 2H-phase within 10 ns after photoexcitation. Our results not only provide important insights to resolve the long-standing debate over the light-induced polymorphic transition in MoTe2 but also highlight the unique capability of strong-field terahertz pulses in manipulating quantum materials.

Suggested Citation

  • Jiaojian Shi & Ya-Qing Bie & Alfred Zong & Shiang Fang & Wei Chen & Jinchi Han & Zhaolong Cao & Yong Zhang & Takashi Taniguchi & Kenji Watanabe & Xuewen Fu & Vladimir Bulović & Efthimios Kaxiras & Edo, 2023. "Intrinsic 1 $${T}^{{\prime} }$$ T ′ phase induced in atomically thin 2H-MoTe2 by a single terahertz pulse," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-41291-w
    DOI: 10.1038/s41467-023-41291-w
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