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A recyclable polyester library from reversible alternating copolymerization of aldehyde and cyclic anhydride

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  • Xun Zhang

    (Zhejiang University)

  • Wenqi Guo

    (Zhejiang University)

  • Chengjian Zhang

    (Zhejiang University)

  • Xinghong Zhang

    (Zhejiang University
    Zhejiang University)

Abstract

Our society is pursuing chemically recyclable polymers to accelerate the green revolution in plastics. Here, we develop a recyclable polyester library from the alternating copolymerization of aldehyde and cyclic anhydride. Although these two monomer sets have little or no thermodynamic driving force for homopolymerization, their copolymerization demonstrates the unexpected alternating characteristics. In addition to readily available monomers, the method is performed under mild conditions, uses common Lewis/Brønsted acids as catalysts, achieves the facile tuning of polyester structure using two distinct monomer sets, and yields 60 polyesters. Interestingly, the copolymerization exhibits the chemical reversibility attributed to its relatively low enthalpy, which makes the resulting polyesters perform closed-loop recycling to monomers at high temperatures. This study provides a modular, efficient, and facile synthesis of recyclable polyesters using sustainable monomers.

Suggested Citation

  • Xun Zhang & Wenqi Guo & Chengjian Zhang & Xinghong Zhang, 2023. "A recyclable polyester library from reversible alternating copolymerization of aldehyde and cyclic anhydride," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-41136-6
    DOI: 10.1038/s41467-023-41136-6
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    References listed on IDEAS

    as
    1. Yunqing Zhu & Charles Romain & Charlotte K. Williams, 2016. "Sustainable polymers from renewable resources," Nature, Nature, vol. 540(7633), pages 354-362, December.
    2. Coralie Jehanno & Jill W. Alty & Martijn Roosen & Steven Meester & Andrew P. Dove & Eugene Y.-X. Chen & Frank A. Leibfarth & Haritz Sardon, 2022. "Critical advances and future opportunities in upcycling commodity polymers," Nature, Nature, vol. 603(7903), pages 803-814, March.
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    Cited by:

    1. Xun Zhang & Ximin Feng & Wenqi Guo & Chengjian Zhang & Xinghong Zhang, 2024. "Chemically recyclable polyvinyl chloride-like plastics," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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