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Waste plastics upcycled for high-efficiency H2O2 production and lithium recovery via Ni-Co/carbon nanotubes composites

Author

Listed:
  • Baolong Qiu

    (Northeastern University)

  • Mengjie Liu

    (Hung Hom)

  • Xin Qu

    (Wuhan University)

  • Fengying Zhou

    (Wuhan University)

  • Hongwei Xie

    (Northeastern University)

  • Dihua Wang

    (Wuhan University)

  • Lawrence Yoon Suk Lee

    (Hung Hom)

  • Huayi Yin

    (Northeastern University
    Wuhan University
    Northeastern University)

Abstract

The disposal and management of waste lithium-ion batteries (LIBs) and low-density polyethylene (LDPE) plastics pose significant environmental challenges. Here we show a synergistic pyrolysis approach that employs spent lithium transition metal oxides and waste LDPE plastics in one sealed reactor to achieve the separation of Li and transition metal. Additionally, we demonstrate the preparation of nanoscale NiCo alloy@carbon nanotubes (CNTs) through co-pyrolysis of LiNi0.6Co0.2Mn0.2O2 and LDPE. The NiCo alloy@CNTs exhibits excellent catalytic activity (Eonset = ~0.85 V) and the selectivity (~90%) for H2O2 production through the electrochemical reduction of oxygen. This can be attributed to the NiCo nanoalloy core and the presence of CNTs with abundant oxygen-containing functional groups (e.g., –COOH and C–O–C), as confirmed by density function theory calculations. Overall, this work presents a straightforward and green approach for valorizing and upcycling various waste LIBs and LDPE plastics.

Suggested Citation

  • Baolong Qiu & Mengjie Liu & Xin Qu & Fengying Zhou & Hongwei Xie & Dihua Wang & Lawrence Yoon Suk Lee & Huayi Yin, 2024. "Waste plastics upcycled for high-efficiency H2O2 production and lithium recovery via Ni-Co/carbon nanotubes composites," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50679-1
    DOI: 10.1038/s41467-024-50679-1
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    References listed on IDEAS

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    1. Coralie Jehanno & Jill W. Alty & Martijn Roosen & Steven Meester & Andrew P. Dove & Eugene Y.-X. Chen & Frank A. Leibfarth & Haritz Sardon, 2022. "Critical advances and future opportunities in upcycling commodity polymers," Nature, Nature, vol. 603(7903), pages 803-814, March.
    2. Gavin Harper & Roberto Sommerville & Emma Kendrick & Laura Driscoll & Peter Slater & Rustam Stolkin & Allan Walton & Paul Christensen & Oliver Heidrich & Simon Lambert & Andrew Abbott & Karl Ryder & L, 2019. "Recycling lithium-ion batteries from electric vehicles," Nature, Nature, vol. 575(7781), pages 75-86, November.
    3. Yunqing Zhu & Charles Romain & Charlotte K. Williams, 2016. "Sustainable polymers from renewable resources," Nature, Nature, vol. 540(7633), pages 354-362, December.
    4. Junxiong Wang & Kai Jia & Jun Ma & Zheng Liang & Zhaofeng Zhuang & Yun Zhao & Baohua Li & Guangmin Zhou & Hui-Ming Cheng, 2023. "Sustainable upcycling of spent LiCoO2 to an ultra-stable battery cathode at high voltage," Nature Sustainability, Nature, vol. 6(7), pages 797-805, July.
    5. Christian Bauer & Simon Burkhardt & Neil P. Dasgupta & Linda Ager-Wick Ellingsen & Linda L. Gaines & Han Hao & Roland Hischier & Liangbing Hu & Yunhui Huang & Jürgen Janek & Chengdu Liang & Hong Li & , 2022. "Charging sustainable batteries," Nature Sustainability, Nature, vol. 5(3), pages 176-178, March.
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