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Phonon transition across an isotopic interface

Author

Listed:
  • Ning Li

    (Peking University
    Peking University
    Peking University)

  • Ruochen Shi

    (Peking University
    Peking University)

  • Yifei Li

    (Peking University)

  • Ruishi Qi

    (Peking University
    Peking University
    University of California at Berkeley)

  • Fachen Liu

    (Peking University
    Peking University
    Peking University)

  • Xiaowen Zhang

    (Peking University
    Peking University)

  • Zhetong Liu

    (Peking University
    Peking University
    Peking University)

  • Yuehui Li

    (Peking University
    Peking University)

  • Xiangdong Guo

    (CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

  • Kaihui Liu

    (Peking University
    Collaborative Innovation Center of Quantum Matter)

  • Ying Jiang

    (Peking University
    Collaborative Innovation Center of Quantum Matter
    Peking University)

  • Xin-Zheng Li

    (Peking University
    Peking University
    Peking University)

  • Ji Chen

    (Peking University
    Collaborative Innovation Center of Quantum Matter
    Peking University)

  • Lei Liu

    (Peking University
    Peking University)

  • En-Ge Wang

    (Peking University
    Peking University
    Songshan Lake Materials Laboratory
    Shanghai University)

  • Peng Gao

    (Peking University
    Peking University
    Collaborative Innovation Center of Quantum Matter
    Peking University)

Abstract

Isotopic mixtures result in distinct properties of materials such as thermal conductivity and nuclear process. However, the knowledge of isotopic interface remains largely unexplored mainly due to the challenges in atomic-scale isotopic identification. Here, using electron energy-loss spectroscopy in a scanning transmission electron microscope, we reveal momentum-transfer-dependent phonon behavior at the h−10BN/h-11BN isotope heterostructure with sub-unit-cell resolution. We find the phonons’ energy changes gradually across the interface, featuring a wide transition regime. Phonons near the Brillouin zone center have a transition regime of ~3.34 nm, whereas phonons at the Brillouin zone boundary have a transition regime of ~1.66 nm. We propose that the isotope-induced charge effect at the interface accounts for the distinct delocalization behavior. Moreover, the variation of phonon energy between atom layers near the interface depends on both of momentum transfer and mass change. This study provides new insights into the isotopic effects in natural materials.

Suggested Citation

  • Ning Li & Ruochen Shi & Yifei Li & Ruishi Qi & Fachen Liu & Xiaowen Zhang & Zhetong Liu & Yuehui Li & Xiangdong Guo & Kaihui Liu & Ying Jiang & Xin-Zheng Li & Ji Chen & Lei Liu & En-Ge Wang & Peng Gao, 2023. "Phonon transition across an isotopic interface," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38053-z
    DOI: 10.1038/s41467-023-38053-z
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    References listed on IDEAS

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