IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-36709-4.html
   My bibliography  Save this article

In-situ forming dynamic covalently crosslinked nanofibers with one-pot closed-loop recyclability

Author

Listed:
  • Sheng Wang

    (Energy and Environment (ISCE2), Agency for Science, Technology, and Research (A*STAR))

  • Nannan Wang

    (Energy and Environment (ISCE2), Agency for Science, Technology, and Research (A*STAR))

  • Dan Kai

    (Energy and Environment (ISCE2), Agency for Science, Technology, and Research (A*STAR)
    Agency for Science, Technology, and Research (A*STAR))

  • Bofan Li

    (Energy and Environment (ISCE2), Agency for Science, Technology, and Research (A*STAR))

  • Jing Wu

    (Agency for Science, Technology, and Research (A*STAR))

  • Jayven Chee Chuan YEO

    (Agency for Science, Technology, and Research (A*STAR))

  • Xiwei Xu

    (Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences (CAS))

  • Jin Zhu

    (Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences (CAS))

  • Xian Jun Loh

    (Agency for Science, Technology, and Research (A*STAR))

  • Nikos Hadjichristidis

    (Physical Sciences and Engineering Division, KAUST Catalysis Center, King Abdullah University of Science and Technology (KAUST))

  • Zibiao Li

    (Energy and Environment (ISCE2), Agency for Science, Technology, and Research (A*STAR)
    Agency for Science, Technology, and Research (A*STAR)
    National University of Singapore)

Abstract

Polymeric nanofibers are attractive nanomaterials owing to their high surface-area-to-volume ratio and superior flexibility. However, a difficult choice between durability and recyclability continues to hamper efforts to design new polymeric nanofibers. Herein, we integrate the concept of covalent adaptable networks (CANs) to produce a class of nanofibers ⎯ referred to dynamic covalently crosslinked nanofibers (DCCNFs) via electrospinning systems with viscosity modulation and in-situ crosslinking. The developed DCCNFs possess homogeneous morphology, flexibility, mechanical robustness, and creep resistance, as well as good thermal and solvent stability. Moreover, to solve the inevitable issues of performance degradation and crack of nanofibrous membranes, DCCNF membranes can be one-pot closed-loop recycled or welded through thermal-reversible Diels-Alder reaction. This study may unlock strategies to fabricate the next generation nanofibers with recyclable features and consistently high performance via dynamic covalent chemistry for intelligent and sustainable applications.

Suggested Citation

  • Sheng Wang & Nannan Wang & Dan Kai & Bofan Li & Jing Wu & Jayven Chee Chuan YEO & Xiwei Xu & Jin Zhu & Xian Jun Loh & Nikos Hadjichristidis & Zibiao Li, 2023. "In-situ forming dynamic covalently crosslinked nanofibers with one-pot closed-loop recyclability," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36709-4
    DOI: 10.1038/s41467-023-36709-4
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-36709-4
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-36709-4?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Mingkai Liu & Peng Zhang & Zehua Qu & Yan Yan & Chao Lai & Tianxi Liu & Shanqing Zhang, 2019. "Conductive carbon nanofiber interpenetrated graphene architecture for ultra-stable sodium ion battery," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    2. Peyton Shieh & Wenxu Zhang & Keith E. L. Husted & Samantha L. Kristufek & Boya Xiong & David J. Lundberg & Jet Lem & David Veysset & Yuchen Sun & Keith A. Nelson & Desiree L. Plata & Jeremiah A. Johns, 2020. "Publisher Correction: Cleavable comonomers enable degradable, recyclable thermoset plastics," Nature, Nature, vol. 585(7823), pages 4-4, September.
    3. Peyton Shieh & Wenxu Zhang & Keith E. L. Husted & Samantha L. Kristufek & Boya Xiong & David J. Lundberg & Jet Lem & David Veysset & Yuchen Sun & Keith A. Nelson & Desiree L. Plata & Jeremiah A. Johns, 2020. "Cleavable comonomers enable degradable, recyclable thermoset plastics," Nature, Nature, vol. 583(7817), pages 542-547, July.
    4. Manuel Häußler & Marcel Eck & Dario Rothauer & Stefan Mecking, 2021. "Closed-loop recycling of polyethylene-like materials," Nature, Nature, vol. 590(7846), pages 423-427, February.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xun Zhang & Ximin Feng & Wenqi Guo & Chengjian Zhang & Xinghong Zhang, 2024. "Chemically recyclable polyvinyl chloride-like plastics," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Ye Sha & Xiaofan Chen & Wei Sun & Junfeng Zhou & Yucheng He & Enhua Xu & Zhenyang Luo & Yonghong Zhou & Puyou Jia, 2024. "Biorenewable and circular polyolefin thermoplastic elastomers," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    3. Alexander D. Snyder & Zachary J. Phillips & Jack S. Turicek & Charles E. Diesendruck & Kalyana B. Nakshatrala & Jason F. Patrick, 2022. "Prolonged in situ self-healing in structural composites via thermo-reversible entanglement," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    4. Bo Qin & Siyuan Liu & Zehuan Huang & Lingda Zeng & Jiang-Fei Xu & Xi Zhang, 2022. "Closed-loop chemical recycling of cross-linked polymeric materials based on reversible amidation chemistry," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Junheng Zhang & Can Jiang & Guoyan Deng & Mi Luo & Bangjiao Ye & Hongjun Zhang & Menghe Miao & Tingcheng Li & Daohong Zhang, 2024. "Closed-loop recycling of tough epoxy supramolecular thermosets constructed with hyperbranched topological structure," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    6. Daniel H. Weinland & Kevin van der Maas & Yue Wang & Bruno Bottega Pergher & Robert-Jan van Putten & Bing Wang & Gert-Jan M. Gruter, 2022. "Overcoming the low reactivity of biobased, secondary diols in polyester synthesis," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    7. Xing-Wang Han & Xun Zhang & Youyun Zhou & Aizezi Maimaitiming & Xiu-Li Sun & Yanshan Gao & Peizhi Li & Boyu Zhu & Eugene Y.-X. Chen & Xiaokang Kuang & Yong Tang, 2024. "Circular olefin copolymers made de novo from ethylene and α-olefins," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    8. Haijun Feng & Ning Zheng & Wenjun Peng & Chujun Ni & Huijie Song & Qian Zhao & Tao Xie, 2022. "Upcycling of dynamic thiourea thermoset polymers by intrinsic chemical strengthening," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    9. Salarizadeh, Parisa & Rastgoo-Deylami, Mohadese & Askari, Mohammad Bagher, 2022. "Electrochemical properties of Ni3S2@MoS2-rGO ternary nanocomposite as a promising cathode for Ni–Zn batteries and catalyst towards hydrogen evolution reaction," Renewable Energy, Elsevier, vol. 194(C), pages 152-162.
    10. Xiaozhuang Zhou & Yijun Zheng & Haohui Zhang & Li Yang & Yubo Cui & Baiju P. Krishnan & Shihua Dong & Michael Aizenberg & Xinhong Xiong & Yuhang Hu & Joanna Aizenberg & Jiaxi Cui, 2023. "Reversibly growing crosslinked polymers with programmable sizes and properties," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    11. Robin Lemmens & Jannick Vercammen & Lander Belleghem & Dirk Vos, 2024. "Upcycling polyethylene into closed-loop recyclable polymers through titanosilicate catalyzed C-H oxidation and in-chain heteroatom insertion," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36709-4. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.