IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-022-35699-z.html
   My bibliography  Save this article

Enhanced chiroptic properties of nanocomposites of achiral plasmonic nanoparticles decorated with chiral dye-loaded micelles

Author

Listed:
  • Tonghan Zhao

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Dejing Meng

    (CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Zhijian Hu

    (CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Wenjing Sun

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Yinglu Ji

    (CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Jianlei Han

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Xue Jin

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Xiaochun Wu

    (CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao
    University of Chinese Academy of Sciences)

  • Pengfei Duan

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao
    University of Chinese Academy of Sciences)

Abstract

The development of circularly polarized luminescence (CPL)-active materials with both large luminescence dissymmetry factor (glum) and high emission efficiency continues to be a major challenge. Here, we present an approach to improve the overall CPL performance by integrating triplet-triplet annihilation-based photon upconversion (TTA-UC) with localized surface plasmon resonance. Dye-loaded chiral micelles possessing TTA-UC ability are designed and attached on the surface of achiral gold nanorods (AuNRs). The longitudinal and transversal resonance peaks of AuNRs overlap with the absorption and emission of dye-loaded chiral micelles, respectively. Typically, 43-fold amplification of glum value accompanied by 3-fold enhancement of upconversion are obtained simultaneously when Au@Ag nanorods are employed in the composites. More importantly, transient absorption spectra reveal a fast accumulation of spin-polarized triplet excitons in the composites. Therefore, the enhancement of chirality-induced spin polarization should be in charge of the amplification of glum value. Our design strategy suggests that combining plasmonic nanomaterials with chiral organic materials could aid in the development of chiroptical nanomaterials.

Suggested Citation

  • Tonghan Zhao & Dejing Meng & Zhijian Hu & Wenjing Sun & Yinglu Ji & Jianlei Han & Xue Jin & Xiaochun Wu & Pengfei Duan, 2023. "Enhanced chiroptic properties of nanocomposites of achiral plasmonic nanoparticles decorated with chiral dye-loaded micelles," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-022-35699-z
    DOI: 10.1038/s41467-022-35699-z
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-35699-z
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-35699-z?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Ling Huang & Timmy Le & Kai Huang & Gang Han, 2021. "Enzymatic enhancing of triplet–triplet annihilation upconversion by breaking oxygen quenching for background-free biological sensing," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    2. Hye-Eun Lee & Hyo-Yong Ahn & Jungho Mun & Yoon Young Lee & Minkyung Kim & Nam Heon Cho & Kiseok Chang & Wook Sung Kim & Junsuk Rho & Ki Tae Nam, 2018. "Amino-acid- and peptide-directed synthesis of chiral plasmonic gold nanoparticles," Nature, Nature, vol. 556(7701), pages 360-365, April.
    3. Chenlu He & Guang Yang & Yan Kuai & Sizhen Shan & Lin Yang & Jingang Hu & Douguo Zhang & Qijin Zhang & Gang Zou, 2018. "Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yonghong Shi & Jianlei Han & Chengxi Li & Tonghan Zhao & Xue Jin & Pengfei Duan, 2023. "Recyclable soft photonic crystal film with overall improved circularly polarized luminescence," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jiawei Lv & Jeong Hyun Han & Geonho Han & Seongmin An & Seung Ju Kim & Ryeong Myeong Kim & Jung‐El Ryu & Rena Oh & Hyuckjin Choi & In Han Ha & Yoon Ho Lee & Minje Kim & Gyeong-Su Park & Ho Won Jang & , 2024. "Spatiotemporally modulated full-polarized light emission for multiplexed optical encryption," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Xiali Lv & Yu Tian & Fengxia Wu & Xiaoxi Luan & Fenghua Li & Zhili Shen & Guobao Xu & Kun Liu & Wenxin Niu, 2024. "Chiral plasmonic-dielectric coupling enables strong near-infrared chiroptical responses from helicoidal core-shell nanoparticles," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    3. Baofu Ding & Pengyuan Zeng & Ziyang Huang & Lixin Dai & Tianshu Lan & Hao Xu & Yikun Pan & Yuting Luo & Qiangmin Yu & Hui-Ming Cheng & Bilu Liu, 2022. "A 2D material–based transparent hydrogel with engineerable interference colours," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    4. Minju Song & Yoonkyum Kim & Du San Baek & Ho Young Kim & Da Hwi Gu & Haiyang Li & Benjamin V. Cunning & Seong Eun Yang & Seung Hwae Heo & Seunghyun Lee & Minhyuk Kim & June Sung Lim & Hu Young Jeong &, 2023. "3D microprinting of inorganic porous materials by chemical linking-induced solidification of nanocrystals," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    5. Chi Zhang & Huatian Hu & Chunmiao Ma & Yawen Li & Xujie Wang & Dongyao Li & Artur Movsesyan & Zhiming Wang & Alexander Govorov & Quan Gan & Tao Ding, 2024. "Quantum plasmonics pushes chiral sensing limit to single molecules: a paradigm for chiral biodetections," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    6. Jing Ai & Xueliang Zhang & Te Bai & Qing Shen & Peter Oleynikov & Yingying Duan & Osamu Terasaki & Shunai Che & Lu Han, 2022. "Synchronous quantitative analysis of chiral mesostructured inorganic crystals by 3D electron diffraction tomography," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. Pengqing Bi & Tao Zhang & Yuanyuan Guo & Jianqiu Wang & Xian Wei Chua & Zhihao Chen & Wei Peng Goh & Changyun Jiang & Elbert E. M. Chia & Jianhui Hou & Le Yang, 2024. "Donor-acceptor bulk-heterojunction sensitizer for efficient solid-state infrared-to-visible photon up-conversion," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    8. Geon Yeong Kim & Shinho Kim & Ki Hyun Park & Hanhwi Jang & Moohyun Kim & Tae Won Nam & Kyeong Min Song & Hongjoo Shin & Yemin Park & Yeongin Cho & Jihyeon Yeom & Min-Jae Choi & Min Seok Jang & Yeon Si, 2024. "Chiral 3D structures through multi-dimensional transfer printing of multilayer quantum dot patterns," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    9. Yoon Ho Lee & Yousang Won & Jungho Mun & Sanghyuk Lee & Yeseul Kim & Bongjun Yeom & Letian Dou & Junsuk Rho & Joon Hak Oh, 2023. "Hierarchically manufactured chiral plasmonic nanostructures with gigantic chirality for polarized emission and information encryption," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    10. Sungwook Choi & Sang Won Im & Ji-Hyeok Huh & Sungwon Kim & Jaeseung Kim & Yae-Chan Lim & Ryeong Myeong Kim & Jeong Hyun Han & Hyeohn Kim & Michael Sprung & Su Yong Lee & Wonsuk Cha & Ross Harder & Seu, 2023. "Strain and crystallographic identification of the helically concaved gap surfaces of chiral nanoparticles," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    11. Si Li & Xinxin Xu & Liguang Xu & Hengwei Lin & Hua Kuang & Chuanlai Xu, 2024. "Emerging trends in chiral inorganic nanomaterials for enantioselective catalysis," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    12. Shengfu Wu & Xin Song & Cong Du & Minghua Liu, 2024. "Macroscopic homochiral helicoids self-assembled via screw dislocations," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    13. Nam Heon Cho & Young Bi Kim & Yoon Young Lee & Sang Won Im & Ryeong Myeong Kim & Jeong Won Kim & Seok Daniel Namgung & Hye-Eun Lee & Hyeohn Kim & Jeong Hyun Han & Hye Won Chung & Yoon Ho Lee & Jeong W, 2022. "Adenine oligomer directed synthesis of chiral gold nanoparticles," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    14. Ufuk Kilic & Matthew Hilfiker & Shawn Wimer & Alexander Ruder & Eva Schubert & Mathias Schubert & Christos Argyropoulos, 2024. "Controlling the broadband enhanced light chirality with L-shaped dielectric metamaterials," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    15. Jiapeng Zheng & Christina Boukouvala & George R. Lewis & Yicong Ma & Yang Chen & Emilie Ringe & Lei Shao & Zhifeng Huang & Jianfang Wang, 2023. "Halide-assisted differential growth of chiral nanoparticles with threefold rotational symmetry," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    16. Zhihua Cheng & Matthew R. Jones, 2022. "Assembly of planar chiral superlattices from achiral building blocks," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    17. Xinyu Wang & Fangwei Ding & Tao Jia & Feng Li & Xiping Ding & Ruibin Deng & Kaifeng Lin & Yulin Yang & Wenzhi Wu & Debin Xia & Guanying Chen, 2024. "Molecular near-infrared triplet-triplet annihilation upconversion with eigen oxygen immunity," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    18. Bing Ni & Dustin Vivod & Jonathan Avaro & Haoyuan Qi & Dirk Zahn & Xun Wang & Helmut Cölfen, 2024. "Reversible chirality inversion of an AuAgx-cysteine coordination polymer by pH change," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    19. Chang Liu & Yan Zhao & Tai-Song Zhang & Cheng-Bo Tao & Wenwen Fei & Sheng Zhang & Man-Bo Li, 2023. "Asymmetric transformation of achiral gold nanoclusters with negative nonlinear dependence between chiroptical activity and enantiomeric excess," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    20. Seok Daniel Namgung & Ryeong Myeong Kim & Yae-Chan Lim & Jong Woo Lee & Nam Heon Cho & Hyeohn Kim & Jin-Suk Huh & Hanju Rhee & Sanghee Nah & Min-Kyu Song & Jang-Yeon Kwon & Ki Tae Nam, 2022. "Circularly polarized light-sensitive, hot electron transistor with chiral plasmonic nanoparticles," Nature Communications, Nature, vol. 13(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-022-35699-z. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.