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Enhanced chiroptic properties of nanocomposites of achiral plasmonic nanoparticles decorated with chiral dye-loaded micelles

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  • Tonghan Zhao

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Dejing Meng

    (CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Zhijian Hu

    (CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Wenjing Sun

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Yinglu Ji

    (CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Jianlei Han

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Xue Jin

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao)

  • Xiaochun Wu

    (CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao
    University of Chinese Academy of Sciences)

  • Pengfei Duan

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), No.11, ZhongGuanCun BeiYiTiao
    University of Chinese Academy of Sciences)

Abstract

The development of circularly polarized luminescence (CPL)-active materials with both large luminescence dissymmetry factor (glum) and high emission efficiency continues to be a major challenge. Here, we present an approach to improve the overall CPL performance by integrating triplet-triplet annihilation-based photon upconversion (TTA-UC) with localized surface plasmon resonance. Dye-loaded chiral micelles possessing TTA-UC ability are designed and attached on the surface of achiral gold nanorods (AuNRs). The longitudinal and transversal resonance peaks of AuNRs overlap with the absorption and emission of dye-loaded chiral micelles, respectively. Typically, 43-fold amplification of glum value accompanied by 3-fold enhancement of upconversion are obtained simultaneously when Au@Ag nanorods are employed in the composites. More importantly, transient absorption spectra reveal a fast accumulation of spin-polarized triplet excitons in the composites. Therefore, the enhancement of chirality-induced spin polarization should be in charge of the amplification of glum value. Our design strategy suggests that combining plasmonic nanomaterials with chiral organic materials could aid in the development of chiroptical nanomaterials.

Suggested Citation

  • Tonghan Zhao & Dejing Meng & Zhijian Hu & Wenjing Sun & Yinglu Ji & Jianlei Han & Xue Jin & Xiaochun Wu & Pengfei Duan, 2023. "Enhanced chiroptic properties of nanocomposites of achiral plasmonic nanoparticles decorated with chiral dye-loaded micelles," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-022-35699-z
    DOI: 10.1038/s41467-022-35699-z
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    References listed on IDEAS

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    1. Hye-Eun Lee & Hyo-Yong Ahn & Jungho Mun & Yoon Young Lee & Minkyung Kim & Nam Heon Cho & Kiseok Chang & Wook Sung Kim & Junsuk Rho & Ki Tae Nam, 2018. "Amino-acid- and peptide-directed synthesis of chiral plasmonic gold nanoparticles," Nature, Nature, vol. 556(7701), pages 360-365, April.
    2. Chenlu He & Guang Yang & Yan Kuai & Sizhen Shan & Lin Yang & Jingang Hu & Douguo Zhang & Qijin Zhang & Gang Zou, 2018. "Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    3. Ling Huang & Timmy Le & Kai Huang & Gang Han, 2021. "Enzymatic enhancing of triplet–triplet annihilation upconversion by breaking oxygen quenching for background-free biological sensing," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
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    Cited by:

    1. Yonghong Shi & Jianlei Han & Chengxi Li & Tonghan Zhao & Xue Jin & Pengfei Duan, 2023. "Recyclable soft photonic crystal film with overall improved circularly polarized luminescence," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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