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Selective CO2 electroreduction to methanol via enhanced oxygen bonding

Author

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  • Gong Zhang

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Haihe Laboratory of Sustainable Chemical Transformations)

  • Tuo Wang

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Haihe Laboratory of Sustainable Chemical Transformations
    Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City)

  • Mengmeng Zhang

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Haihe Laboratory of Sustainable Chemical Transformations)

  • Lulu Li

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Haihe Laboratory of Sustainable Chemical Transformations)

  • Dongfang Cheng

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Haihe Laboratory of Sustainable Chemical Transformations)

  • Shiyu Zhen

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Haihe Laboratory of Sustainable Chemical Transformations)

  • Yongtao Wang

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Haihe Laboratory of Sustainable Chemical Transformations)

  • Jian Qin

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Haihe Laboratory of Sustainable Chemical Transformations)

  • Zhi-Jian Zhao

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Haihe Laboratory of Sustainable Chemical Transformations)

  • Jinlong Gong

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Haihe Laboratory of Sustainable Chemical Transformations)

Abstract

The reduction of carbon dioxide using electrochemical cells is an appealing technology to store renewable electricity in a chemical form. The preferential adsorption of oxygen over carbon atoms of intermediates could improve the methanol selectivity due to the retention of C–O bond. However, the adsorbent-surface interaction is mainly related to the d states of transition metals in catalysts, thus it is difficult to promote the formation of oxygen-bound intermediates without affecting the carbon affinity. This paper describes the construction of a molybdenum-based metal carbide catalyst that promotes the formation and adsorption of oxygen-bound intermediates, where the sp states in catalyst are enabled to participate in the bonding of intermediates. A high Faradaic efficiency of 80.4% for methanol is achieved at −1.1 V vs. the standard hydrogen electrode.

Suggested Citation

  • Gong Zhang & Tuo Wang & Mengmeng Zhang & Lulu Li & Dongfang Cheng & Shiyu Zhen & Yongtao Wang & Jian Qin & Zhi-Jian Zhao & Jinlong Gong, 2022. "Selective CO2 electroreduction to methanol via enhanced oxygen bonding," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35450-8
    DOI: 10.1038/s41467-022-35450-8
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    References listed on IDEAS

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    2. Jiqing Jiao & Qing Yuan & Meijie Tan & Xiaoqian Han & Mingbin Gao & Chao Zhang & Xuan Yang & Zhaolin Shi & Yanbin Ma & Hai Xiao & Jiangwei Zhang & Tongbu Lu, 2023. "Constructing asymmetric double-atomic sites for synergistic catalysis of electrochemical CO2 reduction," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

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