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Hierarchical micro/nanostructured silver hollow fiber boosts electroreduction of carbon dioxide

Author

Listed:
  • Shoujie Li

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences
    ShanghaiTech University)

  • Wei Chen

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Xiao Dong

    (Chinese Academy of Sciences)

  • Chang Zhu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Aohui Chen

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences
    ShanghaiTech University)

  • Yanfang Song

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Guihua Li

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Wei Wei

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences
    ShanghaiTech University)

  • Yuhan Sun

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences
    ShanghaiTech University)

Abstract

Efficient conversion of CO2 to commodity chemicals by sustainable way is of great significance for achieving carbon neutrality. Although considerable progress has been made in CO2 utilization, highly efficient CO2 conversion with high space velocity under mild conditions remains a challenge. Here, we report a hierarchical micro/nanostructured silver hollow fiber electrode that reduces CO2 to CO with a faradaic efficiency of 93% and a current density of 1.26 A · cm−2 at a potential of −0.83 V vs. RHE. Exceeding 50% conversions of as high as 31,000 mL · gcat−1 · h−1 CO2 are achieved at ambient temperature and pressure. Electrochemical results and time-resolved operando Raman spectra demonstrate that enhanced three-phase interface reactions and oriented mass transfers synergistically boost CO production.

Suggested Citation

  • Shoujie Li & Wei Chen & Xiao Dong & Chang Zhu & Aohui Chen & Yanfang Song & Guihua Li & Wei Wei & Yuhan Sun, 2022. "Hierarchical micro/nanostructured silver hollow fiber boosts electroreduction of carbon dioxide," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30733-6
    DOI: 10.1038/s41467-022-30733-6
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    1. Dohyung Kim & Sunmoon Yu & Fan Zheng & Inwhan Roh & Yifan Li & Sheena Louisia & Zhiyuan Qi & Gabor A. Somorjai & Heinz Frei & Lin-Wang Wang & Peidong Yang, 2020. "Selective CO2 electrocatalysis at the pseudocapacitive nanoparticle/ordered-ligand interlayer," Nature Energy, Nature, vol. 5(12), pages 1032-1042, December.
    2. Yueshen Wu & Zhan Jiang & Xu Lu & Yongye Liang & Hailiang Wang, 2019. "Domino electroreduction of CO2 to methanol on a molecular catalyst," Nature, Nature, vol. 575(7784), pages 639-642, November.
    3. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    4. Fengwang Li & Arnaud Thevenon & Alonso Rosas-Hernández & Ziyun Wang & Yilin Li & Christine M. Gabardo & Adnan Ozden & Cao Thang Dinh & Jun Li & Yuhang Wang & Jonathan P. Edwards & Yi Xu & Christopher , 2020. "Molecular tuning of CO2-to-ethylene conversion," Nature, Nature, vol. 577(7791), pages 509-513, January.
    5. Smriti Mallapaty, 2020. "How China could be carbon neutral by mid-century," Nature, Nature, vol. 586(7830), pages 482-483, October.
    6. Min Liu & Yuanjie Pang & Bo Zhang & Phil De Luna & Oleksandr Voznyy & Jixian Xu & Xueli Zheng & Cao Thang Dinh & Fengjia Fan & Changhong Cao & F. Pelayo García de Arquer & Tina Saberi Safaei & Adam Me, 2016. "Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration," Nature, Nature, vol. 537(7620), pages 382-386, September.
    7. Joshua A. Rabinowitz & Matthew W. Kanan, 2020. "The future of low-temperature carbon dioxide electrolysis depends on solving one basic problem," Nature Communications, Nature, vol. 11(1), pages 1-3, December.
    8. Recep Kas & Khalid Khazzal Hummadi & Ruud Kortlever & Patrick de Wit & Alexander Milbrat & Mieke W. J. Luiten-Olieman & Nieck E. Benes & Marc T. M. Koper & Guido Mul, 2016. "Three-dimensional porous hollow fibre copper electrodes for efficient and high-rate electrochemical carbon dioxide reduction," Nature Communications, Nature, vol. 7(1), pages 1-7, April.
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