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Precursor engineering of hydrotalcite-derived redox sorbents for reversible and stable thermochemical oxygen storage

Author

Listed:
  • Michael High

    (Imperial College London)

  • Clemens F. Patzschke

    (Imperial College London)

  • Liya Zheng

    (Imperial College London)

  • Dewang Zeng

    (Imperial College London
    Southeast University)

  • Oriol Gavalda-Diaz

    (Imperial College London
    University of Nottingham, Jubilee Campus)

  • Nan Ding

    (Imperial College London)

  • Ka Ho Horace Chien

    (Imperial College London)

  • Zili Zhang

    (Imperial College London)

  • George E. Wilson

    (Imperial College London)

  • Andrey V. Berenov

    (Imperial College London)

  • Stephen J. Skinner

    (Imperial College London)

  • Kyra L. Sedransk Campbell

    (The University of Sheffield, Western Bank)

  • Rui Xiao

    (Southeast University)

  • Paul S. Fennell

    (Imperial College London)

  • Qilei Song

    (Imperial College London)

Abstract

Chemical looping processes based on multiple-step reduction and oxidation of metal oxides hold great promise for a variety of energy applications, such as CO2 capture and conversion, gas separation, energy storage, and redox catalytic processes. Copper-based mixed oxides are one of the most promising candidate materials with a high oxygen storage capacity. However, the structural deterioration and sintering at high temperatures is one key scientific challenge. Herein, we report a precursor engineering approach to prepare durable copper-based redox sorbents for use in thermochemical looping processes for combustion and gas purification. Calcination of the CuMgAl hydrotalcite precursors formed mixed metal oxides consisting of CuO nanoparticles dispersed in the Mg-Al oxide support which inhibited the formation of copper aluminates during redox cycling. The copper-based redox sorbents demonstrated enhanced reaction rates, stable O2 storage capacity over 500 redox cycles at 900 °C, and efficient gas purification over a broad temperature range. We expect that our materials design strategy has broad implications on synthesis and engineering of mixed metal oxides for a range of thermochemical processes and redox catalytic applications.

Suggested Citation

  • Michael High & Clemens F. Patzschke & Liya Zheng & Dewang Zeng & Oriol Gavalda-Diaz & Nan Ding & Ka Ho Horace Chien & Zili Zhang & George E. Wilson & Andrey V. Berenov & Stephen J. Skinner & Kyra L. S, 2022. "Precursor engineering of hydrotalcite-derived redox sorbents for reversible and stable thermochemical oxygen storage," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32593-6
    DOI: 10.1038/s41467-022-32593-6
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    References listed on IDEAS

    as
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