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Large breathing effect in ZIF-65(Zn) with expansion and contraction of the SOD cage

Author

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  • Meizhen Gao

    (Taiyuan University of Technology)

  • Rui-Kang Huang

    (Sun Yat-Sen University)

  • Bin Zheng

    (Xiʹan University of Science and Technology)

  • Pengfei Wang

    (Chinese Academy of Sciences)

  • Qi Shi

    (Taiyuan University of Technology)

  • Wei-Xiong Zhang

    (Sun Yat-Sen University)

  • Jinxiang Dong

    (Taiyuan University of Technology)

Abstract

The flexibility and guest-responsive behavior of some metal-organic frameworks (MOFs) indicate their potential in the fields of sensors and molecular recognition. As a subfamily of MOFs, the flexible zeolitic imidazolate frameworks (ZIFs) typically feature a small displacive transition due to the rigid zeolite topology. Herein, an atypical reversible displacive transition (6.4 Å) is observed for the sodalite (SOD) cage in flexible ZIF-65(Zn), which represents an unusually large breathing effect compared to other ZIFs. ZIF-65(Zn) exhibits a stepwise II → III → I expansion between an unusual ellipsoidal SOD cage (8.6 Å × 15.9 Å for II) and a spherical SOD cage (15.0 Å for I). The breathing behavior of ZIF-65(Zn) varies depending on the nature of the guest molecules (polarity and shape). Computational simulations are employed to rationalize the differences in the breathing behavior depending on the structure of the ZIF-65(Zn) cage and the nature of the guest-associated host–guest and guest–guest interactions.

Suggested Citation

  • Meizhen Gao & Rui-Kang Huang & Bin Zheng & Pengfei Wang & Qi Shi & Wei-Xiong Zhang & Jinxiang Dong, 2022. "Large breathing effect in ZIF-65(Zn) with expansion and contraction of the SOD cage," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32332-x
    DOI: 10.1038/s41467-022-32332-x
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    1. Stéphane Diring & Dan Ohtan Wang & Chiwon Kim & Mio Kondo & Yong Chen & Susumu Kitagawa & Ken-ichiro Kamei & Shuhei Furukawa, 2013. "Localized cell stimulation by nitric oxide using a photoactive porous coordination polymer platform," Nature Communications, Nature, vol. 4(1), pages 1-8, December.
    2. Jun Wang & Yan Zhang & Yun Su & Xing Liu & Peixin Zhang & Rui-Biao Lin & Shixia Chen & Qiang Deng & Zheling Zeng & Shuguang Deng & Banglin Chen, 2022. "Fine pore engineering in a series of isoreticular metal-organic frameworks for efficient C2H2/CO2 separation," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Pu Zhao & Hong Fang & Sanghamitra Mukhopadhyay & Aurelia Li & Svemir Rudić & Ian J. McPherson & Chiu C. Tang & David Fairen-Jimenez & S. C. Edman Tsang & Simon A. T. Redfern, 2019. "Structural dynamics of a metal–organic framework induced by CO2 migration in its non-uniform porous structure," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    4. Yong Kun Jo & Seong-Yong Jeong & Young Kook Moon & Young-Moo Jo & Ji-Wook Yoon & Jong-Heun Lee, 2021. "Exclusive and ultrasensitive detection of formaldehyde at room temperature using a flexible and monolithic chemiresistive sensor," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
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