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Development of vanadium-based polyanion positive electrode active materials for high-voltage sodium-based batteries

Author

Listed:
  • Semyon D. Shraer

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology
    Lomonosov Moscow State University)

  • Nikita D. Luchinin

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology)

  • Ivan A. Trussov

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology)

  • Dmitry A. Aksyonov

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology)

  • Anatoly V. Morozov

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology)

  • Sergey V. Ryazantsev

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology
    Lomonosov Moscow State University)

  • Anna R. Iarchuk

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology)

  • Polina A. Morozova

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology)

  • Victoria A. Nikitina

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology
    Lomonosov Moscow State University)

  • Keith J. Stevenson

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology)

  • Evgeny V. Antipov

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology
    Lomonosov Moscow State University)

  • Artem M. Abakumov

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology)

  • Stanislav S. Fedotov

    (Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology)

Abstract

Polyanion compounds offer a playground for designing prospective electrode active materials for sodium-ion storage due to their structural diversity and chemical variety. Here, by combining a NaVPO4F composition and KTiOPO4-type framework via a low-temperature (e.g., 190 °C) ion-exchange synthesis approach, we develop a high-capacity and high-voltage positive electrode active material. When tested in a coin cell configuration in combination with a Na metal negative electrode and a NaPF6-based non-aqueous electrolyte solution, this cathode active material enables a discharge capacity of 136 mAh g−1 at 14.3 mA g−1 with an average cell discharge voltage of about 4.0 V. Furthermore, a specific discharge capacity of 123 mAh g−1 at 5.7 A g−1 is also reported for the same cell configuration. Through ex situ and operando structural characterizations, we also demonstrate that the reversible Na-ion storage at the positive electrode occurs mostly via a solid-solution de/insertion mechanism.

Suggested Citation

  • Semyon D. Shraer & Nikita D. Luchinin & Ivan A. Trussov & Dmitry A. Aksyonov & Anatoly V. Morozov & Sergey V. Ryazantsev & Anna R. Iarchuk & Polina A. Morozova & Victoria A. Nikitina & Keith J. Steven, 2022. "Development of vanadium-based polyanion positive electrode active materials for high-voltage sodium-based batteries," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31768-5
    DOI: 10.1038/s41467-022-31768-5
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    References listed on IDEAS

    as
    1. Guochun Yan & Sathiya Mariyappan & Gwenaelle Rousse & Quentin Jacquet & Michael Deschamps & Renald David & Boris Mirvaux & John William Freeland & Jean-Marie Tarascon, 2019. "Higher energy and safer sodium ion batteries via an electrochemically made disordered Na3V2(PO4)2F3 material," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
    2. Zubi, Ghassan & Dufo-López, Rodolfo & Carvalho, Monica & Pasaoglu, Guzay, 2018. "The lithium-ion battery: State of the art and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 89(C), pages 292-308.
    3. Artem M. Abakumov & Stanislav S. Fedotov & Evgeny V. Antipov & Jean-Marie Tarascon, 2020. "Solid state chemistry for developing better metal-ion batteries," Nature Communications, Nature, vol. 11(1), pages 1-14, December.
    4. Stanislav S. Fedotov & Nikita D. Luchinin & Dmitry A. Aksyonov & Anatoly V. Morozov & Sergey V. Ryazantsev & Mattia Gaboardi & Jasper R. Plaisier & Keith J. Stevenson & Artem M. Abakumov & Evgeny V. A, 2020. "Titanium-based potassium-ion battery positive electrode with extraordinarily high redox potential," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
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