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A comprehensive review on recent advances of polyanionic cathode materials in Na‐ion batteries for cost effective energy storage applications

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  • Simranjot K. Sapra
  • Jayashree Pati
  • Pravin K. Dwivedi
  • Suddhasatwa Basu
  • Jeng‐Kuei Chang
  • Rajendra S. Dhaka

Abstract

Sustainable and efficient energy storage devices are crucial to meet the soaring global energy demand. In this context, Na‐ion batteries (NIBs) have emerged as one of the excellent alternatives to the Li‐ion batteries, due to the uniform geographical distribution, abundance, cost‐effectiveness, comparable operating voltage as well as similar intercalation chemistry. However, due to larger size of Na and other related issues, a subtle strategy of research is required for the development of electrode materials for NIBs to enhance overall electrochemical performance. Here, we provide a comprehensive review on recent advances of polyanionic cathode materials for NIBs for cost effective and large scale energy storage applications. Owing to their great thermal and chemical stability, high redox potential (inductive effect), and rich structural diversity, polyanionic cathodes have been considered potential candidates in recent years. We cover a large number of polyanionic materials and conclude with the strategies to improve the energy and power density of NIB. This article is categorized under: Energy Research & Innovation > Science and Materials Energy and Development > Science and Materials Energy and Transport > Science and Materials

Suggested Citation

  • Simranjot K. Sapra & Jayashree Pati & Pravin K. Dwivedi & Suddhasatwa Basu & Jeng‐Kuei Chang & Rajendra S. Dhaka, 2021. "A comprehensive review on recent advances of polyanionic cathode materials in Na‐ion batteries for cost effective energy storage applications," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 10(5), September.
    • Handle: RePEc:bla:wireae:v:10:y:2021:i:5:n:e400
    DOI: 10.1002/wene.400
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    1. Dongxue Wang & Xiaofei Bie & Qiang Fu & Ditty Dixon & Natalia Bramnik & Yong-Sheng Hu & Francois Fauth & Yingjin Wei & Helmut Ehrenberg & Gang Chen & Fei Du, 2017. "Sodium vanadium titanium phosphate electrode for symmetric sodium-ion batteries with high power and long lifespan," Nature Communications, Nature, vol. 8(1), pages 1-7, August.
    2. Huang Zhang & Daniel Buchholz & Stefano Passerini, 2017. "Synthesis, Structure, and Sodium Mobility of Sodium Vanadium Nitridophosphate: A Zero-Strain and Safe High Voltage Cathode Material for Sodium-Ion Batteries," Energies, MDPI, vol. 10(7), pages 1-9, June.
    3. Guochun Yan & Sathiya Mariyappan & Gwenaelle Rousse & Quentin Jacquet & Michael Deschamps & Renald David & Boris Mirvaux & John William Freeland & Jean-Marie Tarascon, 2019. "Higher energy and safer sodium ion batteries via an electrochemically made disordered Na3V2(PO4)2F3 material," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
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