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RuO2 electronic structure and lattice strain dual engineering for enhanced acidic oxygen evolution reaction performance

Author

Listed:
  • Yin Qin

    (Harbin Institute of Technology (Shenzhen))

  • Tingting Yu

    (Harbin Institute of Technology (Shenzhen))

  • Sihao Deng

    (Spallation Neutron Source Science Center)

  • Xiao-Ye Zhou

    (Shenzhen University)

  • Dongmei Lin

    (The Hong Kong Polytechnic University)

  • Qian Zhang

    (Shanghai University)

  • Zeyu Jin

    (Harbin Institute of Technology (Shenzhen))

  • Danfeng Zhang

    (Tsinghua University Shenzhen)

  • Yan-Bing He

    (Tsinghua University Shenzhen)

  • Hua-Jun Qiu

    (Harbin Institute of Technology (Shenzhen))

  • Lunhua He

    (Spallation Neutron Source Science Center
    Chinese Academic of Sciences
    Songshan Lake Materials Laboratory)

  • Feiyu Kang

    (Tsinghua University Shenzhen)

  • Kaikai Li

    (Harbin Institute of Technology (Shenzhen))

  • Tong-Yi Zhang

    (The Hong Kong University of Science and Technology (Guangzhou), Advanced Materials Thrust and Sustainable Energy and Environment Thrust, Nansha, Guangzhou)

Abstract

Developing highly active and durable electrocatalysts for acidic oxygen evolution reaction remains a great challenge due to the sluggish kinetics of the four-electron transfer reaction and severe catalyst dissolution. Here we report an electrochemical lithium intercalation method to improve both the activity and stability of RuO2 for acidic oxygen evolution reaction. The lithium intercalates into the lattice interstices of RuO2, donates electrons and distorts the local structure. Therefore, the Ru valence state is lowered with formation of stable Li-O-Ru local structure, and the Ru–O covalency is weakened, which suppresses the dissolution of Ru, resulting in greatly enhanced durability. Meanwhile, the inherent lattice strain results in the surface structural distortion of LixRuO2 and activates the dangling O atom near the Ru active site as a proton acceptor, which stabilizes the OOH* and dramatically enhances the activity. This work provides an effective strategy to develop highly efficient catalyst towards water splitting.

Suggested Citation

  • Yin Qin & Tingting Yu & Sihao Deng & Xiao-Ye Zhou & Dongmei Lin & Qian Zhang & Zeyu Jin & Danfeng Zhang & Yan-Bing He & Hua-Jun Qiu & Lunhua He & Feiyu Kang & Kaikai Li & Tong-Yi Zhang, 2022. "RuO2 electronic structure and lattice strain dual engineering for enhanced acidic oxygen evolution reaction performance," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31468-0
    DOI: 10.1038/s41467-022-31468-0
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    References listed on IDEAS

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    1. Zhen-Feng Huang & Shibo Xi & Jiajia Song & Shuo Dou & Xiaogang Li & Yonghua Du & Caozheng Diao & Zhichuan J. Xu & Xin Wang, 2021. "Tuning of lattice oxygen reactivity and scaling relation to construct better oxygen evolution electrocatalyst," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
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    1. Chang Jiang & Hongyuan He & Hongquan Guo & Xiaoxin Zhang & Qingyang Han & Yanhong Weng & Xianzhu Fu & Yinlong Zhu & Ning Yan & Xin Tu & Yifei Sun, 2024. "Transfer learning guided discovery of efficient perovskite oxide for alkaline water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    2. Yu Du & Fakang Xie & Mengfei Lu & Rongxian Lv & Wangxi Liu & Yuandong Yan & Shicheng Yan & Zhigang Zou, 2024. "Continuous strain tuning of oxygen evolution catalysts with anisotropic thermal expansion," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Qianqian Ji & Bing Tang & Xilin Zhang & Chao Wang & Hao Tan & Jie Zhao & Ruiqi Liu & Mei Sun & Hengjie Liu & Chang Jiang & Jianrong Zeng & Xingke Cai & Wensheng Yan, 2024. "Operando identification of the oxide path mechanism with different dual-active sites for acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Ding Chen & Ruohan Yu & Kesong Yu & Ruihu Lu & Hongyu Zhao & Jixiang Jiao & Youtao Yao & Jiawei Zhu & Jinsong Wu & Shichun Mu, 2024. "Bicontinuous RuO2 nanoreactors for acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Hongnan Jia & Na Yao & Yiming Jin & Liqing Wu & Juan Zhu & Wei Luo, 2024. "Stabilizing atomic Ru species in conjugated sp2 carbon-linked covalent organic framework for acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    6. Yu Shen & Xiao-Long Zhang & Ming-Rong Qu & Jie Ma & Sheng Zhu & Yu-Lin Min & Min-Rui Gao & Shu-Hong Yu, 2024. "Cr dopant mediates hydroxyl spillover on RuO2 for high-efficiency proton exchange membrane electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    7. Yanrong Xue & Jiwu Zhao & Liang Huang & Ying-Rui Lu & Abdul Malek & Ge Gao & Zhongbin Zhuang & Dingsheng Wang & Cafer T. Yavuz & Xu Lu, 2023. "Stabilizing ruthenium dioxide with cation-anchored sulfate for durable oxygen evolution in proton-exchange membrane water electrolyzers," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    8. Fangqing Wang & Peichao Zou & Yangyang Zhang & Wenli Pan & Ying Li & Limin Liang & Cong Chen & Hui Liu & Shijian Zheng, 2023. "Activating lattice oxygen in high-entropy LDH for robust and durable water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    9. Dafeng Zhang & Mengnan Li & Xue Yong & Haoqiang Song & Geoffrey I. N. Waterhouse & Yunfei Yi & Bingjie Xue & Dongliang Zhang & Baozhong Liu & Siyu Lu, 2023. "Construction of Zn-doped RuO2 nanowires for efficient and stable water oxidation in acidic media," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    10. Lingxi Zhou & Yangfan Shao & Fang Yin & Jia Li & Feiyu Kang & Ruitao Lv, 2023. "Stabilizing non-iridium active sites by non-stoichiometric oxide for acidic water oxidation at high current density," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    11. Xinyu Ping & Yongduo Liu & Lixia Zheng & Yang Song & Lin Guo & Siguo Chen & Zidong Wei, 2024. "Locking the lattice oxygen in RuO2 to stabilize highly active Ru sites in acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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