IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-28643-8.html
   My bibliography  Save this article

Assembling covalent organic framework membranes with superior ion exchange capacity

Author

Listed:
  • Xiaoyao Wang

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Benbing Shi

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Hao Yang

    (Soochow University)

  • Jingyuan Guan

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Xu Liang

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Chunyang Fan

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Xinda You

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Yanan Wang

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin))

  • Zhe Zhang

    (Soochow University)

  • Hong Wu

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Tianjin University)

  • Tao Cheng

    (Soochow University)

  • Runnan Zhang

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Zhejiang Institute of Tianjin University)

  • Zhongyi Jiang

    (Tianjin University
    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
    Zhejiang Institute of Tianjin University
    International Campus of Tianjin University)

Abstract

Ionic covalent organic framework membranes (iCOFMs) hold great promise in ion conduction-relevant applications because the high content and monodispersed ionic groups could afford superior ion conduction. The key to push the upper limit of ion conductivity is to maximize the ion exchange capacity (IEC). Here, we explore iCOFMs with a superhigh ion exchange capacity of 4.6 mmol g−1, using a dual-activation interfacial polymerization strategy. Fukui function is employed as a descriptor of monomer reactivity. We use Brønsted acid to activate aldehyde monomers in organic phase and Brønsted base to activate ionic amine monomers in water phase. After the dual-activation, the reaction between aldehyde monomer and amine monomer at the water-organic interface is significantly accelerated, leading to iCOFMs with high crystallinity. The resultant iCOFMs display a prominent proton conductivity up to 0.66 S cm−1, holding great promise in ion transport and ionic separation applications.

Suggested Citation

  • Xiaoyao Wang & Benbing Shi & Hao Yang & Jingyuan Guan & Xu Liang & Chunyang Fan & Xinda You & Yanan Wang & Zhe Zhang & Hong Wu & Tao Cheng & Runnan Zhang & Zhongyi Jiang, 2022. "Assembling covalent organic framework membranes with superior ion exchange capacity," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28643-8
    DOI: 10.1038/s41467-022-28643-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-28643-8
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-28643-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Hao Yang & Leixin Yang & Hongjian Wang & Ziang Xu & Yumeng Zhao & Yi Luo & Nayab Nasir & Yimeng Song & Hong Wu & Fusheng Pan & Zhongyi Jiang, 2019. "Covalent organic framework membranes through a mixed-dimensional assembly for molecular separations," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    2. Yang Li & Qianxun Wu & Xinghua Guo & Meicheng Zhang & Bin Chen & Guanyi Wei & Xing Li & Xiaofeng Li & Shoujian Li & Lijian Ma, 2020. "Laminated self-standing covalent organic framework membrane with uniformly distributed subnanopores for ionic and molecular sieving," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yang Xie & Wenjing Wang & Zeyue Zhang & Jian Li & Bo Gui & Junliang Sun & Daqiang Yuan & Cheng Wang, 2024. "Fine-tuning the pore environment of ultramicroporous three-dimensional covalent organic frameworks for efficient one-step ethylene purification," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    2. Tianhao Zhu & Yan Kong & Bohui Lyu & Li Cao & Benbing Shi & Xiaoyao Wang & Xiao Pang & Chunyang Fan & Chao Yang & Hong Wu & Zhongyi Jiang, 2023. "3D covalent organic framework membrane with fast and selective ion transport," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Guohua Zhang & Xinyue Li & Gang Chen & Yue Zhang & Mingfeng Wei & Xiaofei Chen & Bao Li & Yuqing Wu & Lixin Wu, 2023. "Supramolecular framework membrane for precise sieving of small molecules, nanoparticles and proteins," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Niaz Ali Khan & Runnan Zhang & Xiaoyao Wang & Li Cao & Chandra S. Azad & Chunyang Fan & Jinqiu Yuan & Mengying Long & Hong Wu & Mark. A. Olson & Zhongyi Jiang, 2022. "Assembling covalent organic framework membranes via phase switching for ultrafast molecular transport," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Yisa Zhou & Ying Wu & Haoyu Wu & Jian Xue & Li Ding & Rui Wang & Haihui Wang, 2022. "Fast hydrogen purification through graphitic carbon nitride nanosheet membranes," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    4. Changwei Zhao & Yanjun Zhang & Yuewen Jia & Bojun Li & Wenjing Tang & Chuning Shang & Rui Mo & Pei Li & Shaomin Liu & Sui Zhang, 2023. "Polyamide membranes with nanoscale ordered structures for fast permeation and highly selective ion-ion separation," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    5. Weipeng Xian & Xiuhui Zuo & Changjia Zhu & Qing Guo & Qing-Wei Meng & Xincheng Zhu & Sai Wang & Shengqian Ma & Qi Sun, 2022. "Anomalous thermo-osmotic conversion performance of ionic covalent-organic-framework membranes in response to charge variations," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    6. Hao Yang & Jinhui Xu & Hui Cao & Jie Wu & Dan Zhao, 2023. "Recovery of homogeneous photocatalysts by covalent organic framework membranes," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    7. Shijie Yin & Jianguo Li & Zhuozhi Lai & Qing-Wei Meng & Weipeng Xian & Zhifeng Dai & Sai Wang & Li Zhang & Yubing Xiong & Shengqian Ma & Qi Sun, 2024. "Giant gateable thermoelectric conversion by tuning the ion linkage interactions in covalent organic framework membranes," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    8. Ningning He & Yingdi Zou & Cheng Chen & Minghao Tan & Yingdan Zhang & Xiaofeng Li & Zhimin Jia & Jie Zhang & Honghan Long & Haiyue Peng & Kaifu Yu & Bo Jiang & Ziqian Han & Ning Liu & Yang Li & Lijian, 2024. "Constructing ordered and tunable extrinsic porosity in covalent organic frameworks via water-mediated soft-template strategy," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28643-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.