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Cellulose Nanocrystals Obtained from Cynara Cardunculus and Their Application in the Paper Industry

Author

Listed:
  • Valentina Coccia

    (CIRIAF, University of Perugia, via G. Duranti, 67, 06125 Perugia, Italy)

  • Franco Cotana

    (CIRIAF, University of Perugia, via G. Duranti, 67, 06125 Perugia, Italy
    These authors contributed equally to this work.)

  • Gianluca Cavalaglio

    (CIRIAF, University of Perugia, via G. Duranti, 67, 06125 Perugia, Italy
    These authors contributed equally to this work.)

  • Mattia Gelosia

    (CIRIAF, University of Perugia, via G. Duranti, 67, 06125 Perugia, Italy
    These authors contributed equally to this work.)

  • Alessandro Petrozzi

    (CIRIAF, University of Perugia, via G. Duranti, 67, 06125 Perugia, Italy)

Abstract

Biorefinery aims at designing new virtuous and high-efficiency energy chains, achieving the combined production of biofuels (e.g., bioethanol) and biobased products. This emerging philosophy can represent an important opportunity for the industrial world, exploiting a new kind of nano-smart biomaterials in their production chains. This paper will present the lab experience carried out by the Biomass Research Centre (CRB) in extracting cellulose nanocrystals (NCC) from a pretreated ( via Steam Explosion ) fraction of Cynara cardunculus . This is a very common and invasive arboreal variety in central Italy. The NCC extraction methodology allows the separation of the crystalline content of cellulose. Such a procedure has been considered in the literature with the exception of one step in which the conditions have been optimized by CRB Lab. This procedure has been applied for the production of NCC from both Cynara cardunculus and microcrystalline cellulose (MCC). The paper will discuss some of the results achieved using the obtained nanocrystals as reinforcing filler in a paper sheet; it was found that the tensile strength increased from 3.69 kg/15 mm to 3.98 kg/15 mm, the durability behavior (measured by bending number) changed from the value 95 to the value 141, and the barrier properties (measured by Gurley porosity) were improved, increasing from 38 s to 45 s.

Suggested Citation

  • Valentina Coccia & Franco Cotana & Gianluca Cavalaglio & Mattia Gelosia & Alessandro Petrozzi, 2014. "Cellulose Nanocrystals Obtained from Cynara Cardunculus and Their Application in the Paper Industry," Sustainability, MDPI, vol. 6(8), pages 1-13, August.
    • Handle: RePEc:gam:jsusta:v:6:y:2014:i:8:p:5252-5264:d:39130
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    References listed on IDEAS

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    1. Beatrice, Carlo & Di Blasio, Gabriele & Lazzaro, Maurizio & Cannilla, Catia & Bonura, Giuseppe & Frusteri, Francesco & Asdrubali, Francesco & Baldinelli, Giorgio & Presciutti, Andrea & Fantozzi, Franc, 2013. "Technologies for energetic exploitation of biodiesel chain derived glycerol: Oxy-fuels production by catalytic conversion," Applied Energy, Elsevier, vol. 102(C), pages 63-71.
    2. Antonio Messineo & Roberto Volpe & Francesco Asdrubali, 2012. "Evaluation of Net Energy Obtainable from Combustion of Stabilised Olive Mill By-Products," Energies, MDPI, vol. 5(5), pages 1-14, May.
    3. Gani, Asri & Naruse, Ichiro, 2007. "Effect of cellulose and lignin content on pyrolysis and combustion characteristics for several types of biomass," Renewable Energy, Elsevier, vol. 32(4), pages 649-661.
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    Cited by:

    1. Tommaso Giannoni & Mattia Gelosia & Alessandro Bertini & Giacomo Fabbrizi & Andrea Nicolini & Valentina Coccia & Paola Iodice & Gianluca Cavalaglio, 2021. "Fractionation of Cynara cardunculus L. by Acidified Organosolv Treatment for the Extraction of Highly Digestible Cellulose and Technical Lignin," Sustainability, MDPI, vol. 13(16), pages 1-16, August.
    2. Luigi Pari & Francesco Latterini & Walter Stefanoni, 2020. "Herbaceous Oil Crops, a Review on Mechanical Harvesting State of the Art," Agriculture, MDPI, vol. 10(8), pages 1-25, July.

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