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Effects of Synthesis Gas Concentration, Composition, and Operational Time on Tubular Solid Oxide Fuel Cell Performance

Author

Listed:
  • Alexander R. Hartwell

    (Mechanical and Aerospace Engineering, Syracuse University, 263 Link Hall, Syracuse, NY 13244, USA)

  • Cole A. Wilhelm

    (Mechanical and Aerospace Engineering, Syracuse University, 263 Link Hall, Syracuse, NY 13244, USA)

  • Thomas S. Welles

    (Mechanical and Aerospace Engineering, Syracuse University, 263 Link Hall, Syracuse, NY 13244, USA)

  • Ryan J. Milcarek

    (School for Engineering of Matter, Transport and Energy, Arizona State University, 501 E. Tyler Mall, Tempe, AZ 85281, USA)

  • Jeongmin Ahn

    (Mechanical and Aerospace Engineering, Syracuse University, 263 Link Hall, Syracuse, NY 13244, USA)

Abstract

There is tremendous potential to utilize the exhaust gases and heat already present within combustion chambers to generate electrical power via solid oxide fuel cells (SOFCs). Variations in system design have been investigated as well as thorough examinations into the impacts of environmental conditions and fuel composition/concentration on SOFC performance. In an attempt to isolate the impacts of carbon monoxide and hydrogen concentration ratios within the exhaust stream, this work utilizes multi-temperature performance analyses with simulated methane combustion exhaust as fuel combined with dilute hydrogen baseline tests. These comparisons reveal the impacts of the complex reaction pathways carbon monoxide participates in when used as an SOFC fuel. Despite these complexities, performance reductions as a result of the presence of carbon monoxide are low when compared to similarly dilute hydrogen as a fuel. This provides further motivation for the continued development of SOFC-CHP systems. Stability testing performed over 80 h reveals the need for careful control of the operating environment as well as signs of carbon deposition. As a result of gas flow disruption, impacts of anode oxidation that may normally not hinder power production become significant factors in addition to coarsening of the anode material. Thermal management and strategies to minimize these impacts are a topic of future research.

Suggested Citation

  • Alexander R. Hartwell & Cole A. Wilhelm & Thomas S. Welles & Ryan J. Milcarek & Jeongmin Ahn, 2022. "Effects of Synthesis Gas Concentration, Composition, and Operational Time on Tubular Solid Oxide Fuel Cell Performance," Sustainability, MDPI, vol. 14(13), pages 1-16, June.
    • Handle: RePEc:gam:jsusta:v:14:y:2022:i:13:p:7983-:d:852423
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    References listed on IDEAS

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    3. Wang, Yuqing & Zeng, Hongyu & Shi, Yixiang & Cao, Tianyu & Cai, Ningsheng & Ye, Xiaofeng & Wang, Shaorong, 2016. "Power and heat co-generation by micro-tubular flame fuel cell on a porous media burner," Energy, Elsevier, vol. 109(C), pages 117-123.
    4. Yari, Mortaza & Mehr, Ali Saberi & Mahmoudi, Seyed Mohammad Seyed & Santarelli, Massimo, 2016. "A comparative study of two SOFC based cogeneration systems fed by municipal solid waste by means of either the gasifier or digester," Energy, Elsevier, vol. 114(C), pages 586-602.
    5. Zeng, Hongyu & Gong, Siqi & Shi, Yixiang & Wang, Yuqing & Cai, Ningsheng, 2019. "Micro-tubular solid oxide fuel cell stack operated with catalytically enhanced porous media fuel-rich combustor," Energy, Elsevier, vol. 179(C), pages 154-162.
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    Cited by:

    1. Orlando Corigliano & Leonardo Pagnotta & Petronilla Fragiacomo, 2022. "On the Technology of Solid Oxide Fuel Cell (SOFC) Energy Systems for Stationary Power Generation: A Review," Sustainability, MDPI, vol. 14(22), pages 1-73, November.

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