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Thermodynamic and Kinetic Description of the Main Effects Related to the Memory Effect during Carbon Dioxide Hydrates Formation in a Confined Environment

Author

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  • Federico Rossi

    (Engineering Department, University of Perugia, 93, 06125 Perugia, Italy)

  • Yan Li

    (CAS Key Laboratory of Experimental Study under Deep-Sea Extreme Conditions, Institute of Deep-Sea Science and Engineering, Chinese Academy of Sciences, Sanya 572000, China
    Institute of Deep-Sea Science and Engineering, University of Chinese Academy of Sciences, Beijing 100049, China)

  • Alberto Maria Gambelli

    (Engineering Department, University of Perugia, 93, 06125 Perugia, Italy)

Abstract

This article consists of an experimental description about how the memory effect intervenes on hydrates formation. In particular, carbon dioxide hydrates were formed in a lab–scale apparatus and in presence of demineralized water and a pure quartz porous medium. The same gas-water mixture was used. Half of experiments was carried out in order to ensure that the system retained memory of previous processes, while in the other half, such effect was completely avoided. Experiments were characterized thermodynamically and kinetically. The local conditions, required for hydrates formation, were compared with those of equilibrium. Moreover, the time needed for the process completion and the rate constant trend over time, were defined. The study of these parameters, together with the observation that hydrates formation was quantitatively similar in both types of experiments, allowed to conclude that the memory effect mainly acted as kinetic promoter for carbon dioxide hydrates formation.

Suggested Citation

  • Federico Rossi & Yan Li & Alberto Maria Gambelli, 2021. "Thermodynamic and Kinetic Description of the Main Effects Related to the Memory Effect during Carbon Dioxide Hydrates Formation in a Confined Environment," Sustainability, MDPI, vol. 13(24), pages 1-21, December.
    • Handle: RePEc:gam:jsusta:v:13:y:2021:i:24:p:13797-:d:702010
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    References listed on IDEAS

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    1. Alberto Maria Gambelli & Mirko Filipponi & Federico Rossi, 2022. "Sequential Formation of CO 2 Hydrates in a Confined Environment: Description of Phase Equilibrium Boundary, Gas Consumption, Formation Rate and Memory Effect," Sustainability, MDPI, vol. 14(14), pages 1-22, July.
    2. Alberto Maria Gambelli & Xhino Rushani & Daniela Pezzolla & Federico Rossi & Giovanni Gigliotti, 2023. "Production of CO 2 Hydrates in Aqueous Mixtures Having (NH 4 ) 2 SO 4 at Different Concentrations; Definition of Consequences on the Process Evolution, Quantification of CO 2 Captured and Validation o," Sustainability, MDPI, vol. 15(12), pages 1-26, June.
    3. Yan Li & Alberto Maria Gambelli & Yizhi Rao & Xuejian Liu & Zhenyuan Yin & Federico Rossi, 2024. "Unraveling the Role of Amino Acid L -Tryptophan Concentration in Enhancing CO 2 Hydrate Kinetics," Energies, MDPI, vol. 17(15), pages 1-15, July.
    4. Alberto Maria Gambelli & Giovanni Gigliotti & Federico Rossi, 2024. "Production of CH 4 /C 3 H 8 (85/15 vol%) Hydrate in a Lab-Scale Unstirred Reactor: Quantification of the Promoting Effect Due to the Addition of Propane to the Gas Mixture," Energies, MDPI, vol. 17(5), pages 1-14, February.
    5. Alberto Maria Gambelli & Federico Rossi & Giovanni Gigliotti, 2024. "Cold Energy Storage via Hydrates Production with Pure CO 2 and CO 2 /N 2 (70/30 and 50/50 vol%) Mixtures: Quantification and Comparison between Energy Stored and Energy Spent," Energies, MDPI, vol. 17(9), pages 1-12, May.
    6. Alberto Maria Gambelli & Federico Rossi, 2022. "Experimental Characterization of Memory Effect, Anomalous Self-Preservation and Ice-Hydrate Competition, during Methane-Hydrates Formation and Dissociation in a Lab-Scale Apparatus," Sustainability, MDPI, vol. 14(8), pages 1-19, April.

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