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Experimental Study on the Effect of SDS and Micron Copper Particles Mixture on Carbon Dioxide Hydrates Formation

Author

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  • Yan Li

    (CAS Key Laboratory of Experimental Study under Deep-Sea Extreme Conditions, Institute of Deep-Sea Science and Engineering, Chinese Academy of Sciences, Sanya 572029, China
    University of Chinese Academy of Sciences, Beijing 100049, China)

  • Alberto Maria Gambelli

    (Engineering Department, University of Perugia, Via G. Duranti 93, 06125 Perugia, Italy)

  • Federico Rossi

    (Engineering Department, University of Perugia, Via G. Duranti 93, 06125 Perugia, Italy)

Abstract

CO 2 hydrate formation and dissociation are the fundamental processes for investigating hydrate-based carbon storage. To better understand CO 2 hydrate phase behaviors in the presence of surfactant and solid additives, this study reports the effects of Sodium Dodecyl Sulfate (SDS) and micron Cu particles on the formation of CO 2 hydrates in the presence of porous quartz sands in a lab-scale reactor. This research is part of a wider study focused on defining the properties of solid additives, produced via gas-atomization, on the formation and dissociation of gas hydrates. The morphology of CO 2 hydrate formed in SDS solution shows dispersed crystal particles due to the increase of surface tension. SDS works as the kinetic promoter on CO 2 hydrates formation whereas the addition of Cu particles inhibits CO 2 gas consumption. The mixture additives show a faint kinetic inhibit effect, in which the Brownian motion restrictions may be responsible for the inhibition of CO 2 hydrate production. The solid additives also showed a weak thermodynamic effect on CO 2 hydrate phase equilibrium.

Suggested Citation

  • Yan Li & Alberto Maria Gambelli & Federico Rossi, 2022. "Experimental Study on the Effect of SDS and Micron Copper Particles Mixture on Carbon Dioxide Hydrates Formation," Energies, MDPI, vol. 15(18), pages 1-16, September.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:18:p:6540-:d:909293
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    References listed on IDEAS

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    Cited by:

    1. Alberto Maria Gambelli & Federico Rossi, 2023. "Review on the Usage of Small-Chain Hydrocarbons (C 2 —C 4 ) as Aid Gases for Improving the Efficiency of Hydrate-Based Technologies," Energies, MDPI, vol. 16(8), pages 1-22, April.
    2. Alberto Maria Gambelli, 2023. "CCUS Strategies as Most Viable Option for Global Warming Mitigation," Energies, MDPI, vol. 16(10), pages 1-4, May.

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