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Renewable Butanol Production via Catalytic Routes

Author

Listed:
  • Heeyoung Choi

    (Department of Environmental and Safety Engineering, Ajou University, Suwon 16499, Korea)

  • Jeehoon Han

    (School of Semiconductor and Chemical Engineering & School of Chemical Engineering, Jeonbuk National University, Jeonju 54896, Korea)

  • Jechan Lee

    (Department of Environmental and Safety Engineering, Ajou University, Suwon 16499, Korea
    Department of Energy Systems Research, Ajou University, Suwon 16499, Korea)

Abstract

Fluctuating crude oil price and global environmental problems such as global warming and climate change lead to growing demand for the production of renewable chemicals as petrochemical substitutes. Butanol is a nonpolar alcohol that is used in a large variety of consumer products and as an important industrial intermediate. Thus, the production of butanol from renewable resources (e.g., biomass and organic waste) has gained a great deal of attention from researchers. Although typical renewable butanol is produced via a fermentative route (i.e., acetone-butanol-ethanol (ABE) fermentation of biomass-derived sugars), the fermentative butanol production has disadvantages such as a low yield of butanol and the formation of byproducts, such as acetone and ethanol. To avoid the drawbacks, the production of renewable butanol via non-fermentative catalytic routes has been recently proposed. This review is aimed at providing an overview on three different emerging and promising catalytic routes from biomass/organic waste-derived chemicals to butanol. The first route involves the conversion of ethanol into butanol over metal and oxide catalysts. Volatile fatty acid can be a raw chemical for the production of butanol using porous materials and metal catalysts. In addition, biomass-derived syngas can be transformed to butanol on non-noble metal catalysts promoted by alkali metals. The prospect of catalytic renewable butanol production is also discussed.

Suggested Citation

  • Heeyoung Choi & Jeehoon Han & Jechan Lee, 2021. "Renewable Butanol Production via Catalytic Routes," IJERPH, MDPI, vol. 18(22), pages 1-14, November.
    • Handle: RePEc:gam:jijerp:v:18:y:2021:i:22:p:11749-:d:675224
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    References listed on IDEAS

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    1. Cho, Seong-Heon & Kim, Juyeon & Han, Jeehoon & Lee, Daewon & Kim, Hyung Ju & Kim, Yong Tae & Cheng, Xun & Xu, Ye & Lee, Jechan & Kwon, Eilhann E., 2019. "Bioalcohol production from acidogenic products via a two-step process: A case study of butyric acid to butanol," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
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