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Process integration and economics of gamma-valerolactone using a cellulose-derived ethyl levulinate intermediate and ethanol solvent

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  • Kim, Juyeon
  • Byun, Jaewon
  • Han, Jeehoon

Abstract

This study combines two catalytic conversion strategies, cellulose to ethyl levulinate and subsequently to gamma-valerolactone, into an integrated process. The effect of integrating the cellulose-to-ethyl levulinate and ethyl levulinate-to-gamma-valerolactone processes on a commercial scale is investigated to improve energy efficiency and economics by performing a process simulation study. The conversion strategies show a low energy efficiency of 6.8% using excess ethanol solvent to achieve high yields of ethyl levulinate and gamma-valerolactone; however, in the integrated process, 0.4% of the ethanol and 30.8% of the cellulose-to-ethyl levulinate heat requirements are supplied by the ethyl levulinate-to-gamma-valerolactone process. The minimum selling price for the integrated process is estimated to be $5.63/kggamma-valerolactone, which makes it an economically feasible option for gamma-valerolactone production. Finally, we conducted a sensitivity analysis of key parameters (cellulose price, steam price, and ethanol price) highly depending on the minimum selling price of gamma-valerolactone.

Suggested Citation

  • Kim, Juyeon & Byun, Jaewon & Han, Jeehoon, 2022. "Process integration and economics of gamma-valerolactone using a cellulose-derived ethyl levulinate intermediate and ethanol solvent," Energy, Elsevier, vol. 239(PA).
    • Handle: RePEc:eee:energy:v:239:y:2022:i:pa:s036054422102212x
    DOI: 10.1016/j.energy.2021.121964
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    References listed on IDEAS

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    1. Byun, Jaewon & Han, Jeehoon, 2016. "Process synthesis and analysis for catalytic conversion of lignocellulosic biomass to fuels: Separate conversion of cellulose and hemicellulose using 2-sec-butylphenol (SBP) solvent," Applied Energy, Elsevier, vol. 171(C), pages 483-490.
    2. Wang, Zhiwei & Li, Zaifeng & Lei, Tingzhou & Yang, Miao & Qi, Tian & Lin, Lu & Xin, Xiaofei & Ajayebi, Atta & Yang, Yantao & He, Xiaofeng & Yan, Xiaoyu, 2016. "Life cycle assessment of energy consumption and environmental emissions for cornstalk-based ethyl levulinate," Applied Energy, Elsevier, vol. 183(C), pages 170-181.
    3. Kim, Juyeon & Han, Jeehoon, 2018. "Simulation study of a strategy to produce gamma-valerolactone from ethyl levulinate," Energy, Elsevier, vol. 163(C), pages 986-991.
    4. Cho, Seong-Heon & Kim, Juyeon & Han, Jeehoon & Lee, Daewon & Kim, Hyung Ju & Kim, Yong Tae & Cheng, Xun & Xu, Ye & Lee, Jechan & Kwon, Eilhann E., 2019. "Bioalcohol production from acidogenic products via a two-step process: A case study of butyric acid to butanol," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
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    Cited by:

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    3. Wu, Zhicong & Xu, Gang & Zhang, Wentao & Xue, Xiaojun & Chen, Heng, 2023. "Thermodynamic and economic analysis of a new methanol steam reforming system integrated with CO2 heat pump and cryogenic separation system," Energy, Elsevier, vol. 283(C).

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