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Double Distribution Activation Energy Model as Suitable Tool in Explaining Biomass and Coal Pyrolysis Behavior

Author

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  • Paolo De Filippis

    (Department of Chemical Engineering, Sapienza University of Rome, via Eudossiana 18, 00184 Roma, Italy)

  • Benedetta De Caprariis

    (Department of Chemical Engineering, Sapienza University of Rome, via Eudossiana 18, 00184 Roma, Italy)

  • Marco Scarsella

    (Department of Chemical Engineering, Sapienza University of Rome, via Eudossiana 18, 00184 Roma, Italy)

  • Nicola Verdone

    (Department of Chemical Engineering, Sapienza University of Rome, via Eudossiana 18, 00184 Roma, Italy)

Abstract

Understanding and modeling of coal and biomass pyrolysis assume particular importance being the first step occurring in both gasification and combustion processes. The complex chemical reaction network occurring in this step leads to a necessary effort in developing a suitable model framework capable of grasping the physics of the phenomenon and allowing a deeper comprehension of the sequence of events. The aim of this work is to show how the intrinsic flexibility of a model based on a double distribution of the activation energy is able to properly describe the two separate steps of primary and secondary pyrolysis, which characterize the thermochemical processing of most of the energetic materials. The model performance was tested by fitting the kinetic parameters from experimental data obtained by thermogravimetric analysis of two materials, which represent very different classes of energy source: a microalgae biomass and a sub-bituminous coal. The model reproduces with high accuracy the pyrolysis behavior of both the materials and adds important information about the relative occurring of the two pyrolysis steps.

Suggested Citation

  • Paolo De Filippis & Benedetta De Caprariis & Marco Scarsella & Nicola Verdone, 2015. "Double Distribution Activation Energy Model as Suitable Tool in Explaining Biomass and Coal Pyrolysis Behavior," Energies, MDPI, vol. 8(3), pages 1-15, March.
    • Handle: RePEc:gam:jeners:v:8:y:2015:i:3:p:1730-1744:d:46289
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    References listed on IDEAS

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    1. Srirangan, Kajan & Akawi, Lamees & Moo-Young, Murray & Chou, C. Perry, 2012. "Towards sustainable production of clean energy carriers from biomass resources," Applied Energy, Elsevier, vol. 100(C), pages 172-186.
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    Cited by:

    1. Gyeong-Min Kim & Dae-Gyun Lee & Chung-Hwan Jeon, 2019. "Fundamental Characteristics and Kinetic Analysis of Lignocellulosic Woody and Herbaceous Biomass Fuels," Energies, MDPI, vol. 12(6), pages 1-16, March.
    2. Hongbin Gao & Jingkuan Li, 2019. "Thermogravimetric analysis of the co-combustion of coal and polyvinyl chloride," PLOS ONE, Public Library of Science, vol. 14(10), pages 1-35, October.
    3. Xiangxi Wang & Zhenzhong Hu & Inamullah Mian & Omar D. Dacres & Jian Li & Bo Wei & Mei Zhong & Xian Li & Noor Rahman & Guangqian Luo & Hong Yao, 2022. "Gasification Kinetics of Organic Solid Waste Pellets: Comparative Study Using Distributed Activation Energy Model and Coats–Redfern Method," Energies, MDPI, vol. 15(24), pages 1-12, December.
    4. Feng, Yipeng & Qiu, Keying & Zhang, Zhiping & Li, Chong & Rahman, Md. Maksudur & Cai, Junmeng, 2022. "Distributed activation energy model for lignocellulosic biomass torrefaction kinetics with combined heating program," Energy, Elsevier, vol. 239(PC).

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