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Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable Energy

Author

Listed:
  • Daegi Kim

    (Department of Civil and Environmental System Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 143-701, Korea)

  • Kunio Yoshikawa

    (Department of Environmental Science and Technology, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503, Japan)

  • Ki Young Park

    (Department of Civil and Environmental System Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 143-701, Korea)

Abstract

The effect of hydrothermal carbonization on the properties of cellulose present in lignocellulosic biomass was investigated for converting it into a renewable energy resource with high energy recovery efficiency. The biochar obtained from cellulose subjected to hydrothermal carbonization showed a significant increase in its carbon content and a calorific value. 13 C NMR spectroscopy showed that when raw cellulose was subjected to hydrothermal carbonization above 220 °C, the resulting biochar had more aromatic and aliphatic fractions than those in raw cellulose. The resulting composition of the biochars was comparable to that of solid fuels and was between that of lignite and sub-bituminous coal. Therefore, cellulose, the main component of lignocellulosic biomass, was used to investigate the effects of varying the reaction temperature during hydrothermal carbonization. The energy recovery efficiency calculations showed that the optimum reaction temperature for the transformation of a mixture of cellulose was approximately 220 °C.

Suggested Citation

  • Daegi Kim & Kunio Yoshikawa & Ki Young Park, 2015. "Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable Energy," Energies, MDPI, vol. 8(12), pages 1-9, December.
    • Handle: RePEc:gam:jeners:v:8:y:2015:i:12:p:12412-14048:d:60464
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    References listed on IDEAS

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    1. Liu, Zhengang & Balasubramanian, Rajasekhar, 2014. "Upgrading of waste biomass by hydrothermal carbonization (HTC) and low temperature pyrolysis (LTP): A comparative evaluation," Applied Energy, Elsevier, vol. 114(C), pages 857-864.
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    2. Denisa Djordjevićová & Marco Carnevale Miino & Jakub Raček & Tomáš Chorazy & Petr Hlavínek & Zuzana Vranayova, 2024. "Separation of Cellulose from Wastewater and Valorisation via Pyrolysis: A Case Study in the Czech Republic," Resources, MDPI, vol. 13(4), pages 1-11, April.
    3. Yang Ma & Yan Gao & Xiumin Jiang, 2023. "Influences of the Introduced O-Containing Functional Groups on the Gaseous Pyrolysis Product of Superfine Pulverized Coal," Energies, MDPI, vol. 16(11), pages 1-17, May.
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    5. Ye, Lian & Zhang, Jianliang & Wang, Guangwei & Wang, Chen & Mao, Xiaoming & Ning, Xiaojun & Zhang, Nan & Teng, Haipeng & Li, Jinhua & Wang, Chuan, 2023. "Feasibility analysis of plastic and biomass hydrochar for blast furnace injection," Energy, Elsevier, vol. 263(PD).
    6. Zhiyu Li & Weiming Yi & Zhihe Li & Chunyan Tian & Peng Fu & Yuchun Zhang & Ling Zhou & Jie Teng, 2020. "Preparation of Solid Fuel Hydrochar over Hydrothermal Carbonization of Red Jujube Branch," Energies, MDPI, vol. 13(2), pages 1-10, January.
    7. Lee, Jongkeun & Lee, Kwanyong & Sohn, Donghwan & Kim, Young Mo & Park, Ki Young, 2018. "Hydrothermal carbonization of lipid extracted algae for hydrochar production and feasibility of using hydrochar as a solid fuel," Energy, Elsevier, vol. 153(C), pages 913-920.
    8. Kim, Daegi & Park, Seyong & Park, Ki Young, 2017. "Upgrading the fuel properties of sludge and low rank coal mixed fuel through hydrothermal carbonization," Energy, Elsevier, vol. 141(C), pages 598-602.
    9. Ilaria Zambon & Fabrizio Colosimo & Danilo Monarca & Massimo Cecchini & Francesco Gallucci & Andrea Rosario Proto & Richard Lord & Andrea Colantoni, 2016. "An Innovative Agro-Forestry Supply Chain for Residual Biomass: Physicochemical Characterisation of Biochar from Olive and Hazelnut Pellets," Energies, MDPI, vol. 9(7), pages 1-11, July.
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