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Estimation of Fuel Properties for the Heavy Fraction of Biomass Pyrolysis Oil Consisting of Proposed Structures for Pyrolytic Lignin and Humins

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  • Evan Terrell

    (U.S. Department of Agriculture, Agricultural Research Service, Southern Regional Research Center, New Orleans, LA 70124, USA)

Abstract

The organic component of biomass pyrolysis oils is composed of a light fraction (C2–C4 volatiles, sugar- and lignin-derived monomers) and a less polar heavy fraction (pyrolytic lignin/humins, greater than approximately 200 g/mol). Importantly, this heavy fraction can account for roughly one-third to one-half of the total pyrolysis oil. While the composition and characteristics of the light fraction are generally well understood, research is still needed for the characterization of the heavy fraction. Some important thermodynamic fuel properties of this fraction are the heat of combustion, normal boiling point, heat of vaporization, and flash point, which are (computationally) estimated in this work with regularized regression and empirical correlations. The quantification of these properties has implications on downstream utilization, particularly in the context of co-processing bio-oils with plastic and coal liquefaction products and/or crude petroleum. Finally, challenges and opportunities for (experimental) work are discussed for the advancement of sustainable valorization of biomass pyrolysis oils.

Suggested Citation

  • Evan Terrell, 2024. "Estimation of Fuel Properties for the Heavy Fraction of Biomass Pyrolysis Oil Consisting of Proposed Structures for Pyrolytic Lignin and Humins," Energies, MDPI, vol. 17(9), pages 1-16, April.
    • Handle: RePEc:gam:jeners:v:17:y:2024:i:9:p:2011-:d:1381747
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    References listed on IDEAS

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    1. Mika Pahnila & Aki Koskela & Petri Sulasalmi & Timo Fabritius, 2023. "A Review of Pyrolysis Technologies and the Effect of Process Parameters on Biocarbon Properties," Energies, MDPI, vol. 16(19), pages 1-27, October.
    2. Hu, Xun & Gholizadeh, Mortaza, 2020. "Progress of the applications of bio-oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    3. Marathe, P.S. & Westerhof, R.J.M. & Kersten, S.R.A., 2019. "Fast pyrolysis of lignins with different molecular weight: Experiments and modelling," Applied Energy, Elsevier, vol. 236(C), pages 1125-1137.
    4. Burl Donaldson & Brian Hughes & Eric N. Coker & Nadir Yilmaz, 2023. "Pyrolysis of Oils from Unconventional Resources," Energies, MDPI, vol. 16(8), pages 1-16, April.
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