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TGA-FTIR Analysis of Biomass Samples Based on the Thermal Decomposition Behavior of Hemicellulose, Cellulose, and Lignin

Author

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  • Esin Apaydın Varol

    (Department of Chemical Engineering, Faculty of Engineering, Eskisehir Technical University, 26555 Eskişehir, Turkey)

  • Ülker Mutlu

    (Department of Chemical Engineering, Faculty of Engineering, Eskisehir Technical University, 26555 Eskişehir, Turkey)

Abstract

The slow pyrolysis characteristics of lignocellulosic biomass and its three major components via a Thermogravimetric Analyzer coupled with a Fourier Transform Infrared Spectrometer (TGA-FTIR) was studied. Different compositions and ratios of cellulose, hemicellulose, and lignin, olive pomace, sunflower waste, and pinecone were selected. The main decomposition temperature ranges of xylose (hemicellulose) and lignin showed a broad range between 173–690 and 170–835 °C, respectively, whereas that of cellulose was detected to be 291–395 °C. All biomass samples presented a three-stage pyrolysis model that is explained by the superposition of the weight losses of major components. Simultaneous FTIR analysis of the evolved gases demonstrated that the greater the cellulose and hemicellulose contents, the higher the CO and CO 2 concentrations. Chemical kinetics were computed with the Coats–Redfern model. The activation energy required for the initiation of the thermal decomposition of biomass samples is in the range of 53–94 kJ/mol. Moreover, the product yields of all samples were determined via laboratory-scale pyrolysis. Pyrolytic oil and char yields were determined to be between 18.9–32.4 wt.% and 26.6–31.2 wt.%, respectively, at 550 °C final temperature for the biomass samples. It is concluded that the bio-oil yield was not only controlled by the cellulose content but also affected by the presence of n-hexane soluble (oil) fraction as well as inorganics.

Suggested Citation

  • Esin Apaydın Varol & Ülker Mutlu, 2023. "TGA-FTIR Analysis of Biomass Samples Based on the Thermal Decomposition Behavior of Hemicellulose, Cellulose, and Lignin," Energies, MDPI, vol. 16(9), pages 1-19, April.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:9:p:3674-:d:1132212
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    References listed on IDEAS

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    1. Radoslaw Slezak & Hilal Unyay & Szymon Szufa & Stanislaw Ledakowicz, 2023. "An Extensive Review and Comparison of Modern Biomass Reactors Torrefaction vs. Biomass Pyrolizers—Part 2," Energies, MDPI, vol. 16(5), pages 1-25, February.
    2. Eric N. Coker & Xavier Lujan-Flores & Burl Donaldson & Nadir Yilmaz & Alpaslan Atmanli, 2023. "An Assessment of the Conversion of Biomass and Industrial Waste Products to Activated Carbon," Energies, MDPI, vol. 16(4), pages 1-14, February.
    3. Javaid Akhtar & Muhammad Imran & Arshid Mahmood Ali & Zeeshan Nawaz & Ayyaz Muhammad & Rehan Khalid Butt & Maria Shahid Jillani & Hafiz Amir Naeem, 2021. "Torrefaction and Thermochemical Properties of Agriculture Residues," Energies, MDPI, vol. 14(14), pages 1-13, July.
    4. Gani, Asri & Naruse, Ichiro, 2007. "Effect of cellulose and lignin content on pyrolysis and combustion characteristics for several types of biomass," Renewable Energy, Elsevier, vol. 32(4), pages 649-661.
    5. Cai, Junmeng & He, Yifeng & Yu, Xi & Banks, Scott W. & Yang, Yang & Zhang, Xingguang & Yu, Yang & Liu, Ronghou & Bridgwater, Anthony V., 2017. "Review of physicochemical properties and analytical characterization of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 309-322.
    6. Sinsel, Simon R. & Riemke, Rhea L. & Hoffmann, Volker H., 2020. "Challenges and solution technologies for the integration of variable renewable energy sources—a review," Renewable Energy, Elsevier, vol. 145(C), pages 2271-2285.
    7. Mishra, Ranjeet Kumar & Mohanty, Kaustubha, 2019. "Pyrolysis of three waste biomass: Effect of biomass bed thickness and distance between successive beds on pyrolytic products yield and properties," Renewable Energy, Elsevier, vol. 141(C), pages 549-558.
    8. Gao, Zixiang & Li, Ning & Yin, Siyuan & Yi, Weiming, 2019. "Pyrolysis behavior of cellulose in a fixed bed reactor: Residue evolution and effects of parameters on products distribution and bio-oil composition," Energy, Elsevier, vol. 175(C), pages 1067-1074.
    9. Klinger, Jordan L. & Westover, Tyler L. & Emerson, Rachel M. & Williams, C. Luke & Hernandez, Sergio & Monson, Glen D. & Ryan, J. Chadron, 2018. "Effect of biomass type, heating rate, and sample size on microwave-enhanced fast pyrolysis product yields and qualities," Applied Energy, Elsevier, vol. 228(C), pages 535-545.
    10. Florinda Martins & Carlos Felgueiras & Miroslava Smitkova & Nídia Caetano, 2019. "Analysis of Fossil Fuel Energy Consumption and Environmental Impacts in European Countries," Energies, MDPI, vol. 12(6), pages 1-11, March.
    11. José Juan Alvarado Flores & Jorge Víctor Alcaraz Vera & María Liliana Ávalos Rodríguez & Luis Bernardo López Sosa & José Guadalupe Rutiaga Quiñones & Luís Fernando Pintor Ibarra & Francisco Márquez Mo, 2022. "Analysis of Pyrolysis Kinetic Parameters Based on Various Mathematical Models for More than Twenty Different Biomasses: A Review," Energies, MDPI, vol. 15(18), pages 1-19, September.
    12. Bartłomiej Igliński & Wojciech Kujawski & Urszula Kiełkowska, 2023. "Pyrolysis of Waste Biomass: Technical and Process Achievements, and Future Development—A Review," Energies, MDPI, vol. 16(4), pages 1-26, February.
    13. Escalante, Jamin & Chen, Wei-Hsin & Tabatabaei, Meisam & Hoang, Anh Tuan & Kwon, Eilhann E. & Andrew Lin, Kun-Yi & Saravanakumar, Ayyadurai, 2022. "Pyrolysis of lignocellulosic, algal, plastic, and other biomass wastes for biofuel production and circular bioeconomy: A review of thermogravimetric analysis (TGA) approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
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    2. Chen, Xuejiao & Wang, Hong & Yang, Rui & Lin, Wei & Qi, Zhiyong & Zhang, Dongdong, 2024. "Effect of severe torrefaction by superheated steam on pinewood pyrolysis kinetics and pyrolytic oil compounds," Renewable Energy, Elsevier, vol. 227(C).

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