IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i7p3250-d1116425.html
   My bibliography  Save this article

Identification of Key Events and Emissions during Thermal Abuse Testing on NCA 18650 Cells

Author

Listed:
  • Sofia Ubaldi

    (Department of Chemical Engineering Materials Environment, Sapienza University of Rome, via Eudossiana 18, 00184 Rome, Italy)

  • Marco Conti

    (Department of Chemical Engineering Materials Environment, Sapienza University of Rome, via Eudossiana 18, 00184 Rome, Italy
    INSTM Reference Laboratory for Engineering of Surface Treatments, via Eudossiana 18, 00184 Rome, Italy)

  • Francesco Marra

    (Department of Chemical Engineering Materials Environment, Sapienza University of Rome, via Eudossiana 18, 00184 Rome, Italy
    INSTM Reference Laboratory for Engineering of Surface Treatments, via Eudossiana 18, 00184 Rome, Italy)

  • Paola Russo

    (Department of Chemical Engineering Materials Environment, Sapienza University of Rome, via Eudossiana 18, 00184 Rome, Italy)

Abstract

Thermal abuse of lithium-ion batteries (LIBs) leads to the emission of gases, solids, fires and/or explosions. Therefore, it is essential to define the temperatures at which key events occur (i.e., CID activation, venting, and thermal runaway (TR)) and to identify the related emissions for identifying the hazards to which people and especially rescue teams are exposed. For this purpose, thermal abuse tests were performed on commercial lithium nickel cobalt aluminum oxide (NCA) 18650 cells at 50% state of charge in a reactor connected to an FT-IR spectrometer by varying test conditions (feed gas of N 2 or air; heating rates of 5 or 10 °C/min until 300 °C). In particular, the concentrations of the gases and the composition of the condensed-phase emissions were estimated. As regards gases, a high concentration (1695 ppmv) of hydrofluoric acid (HF) was measured, while the emissions of condensed matter consisted of organic compounds such as polyethylene oxide and paraffin oil, and inorganic compounds containing Li (0.173 mg/m 3 ) and Al (0.344 mg/m 3 ). The main safety concerns were caused by the temperatures (564 ± 85 °C) reached by the cell during TR, by the HF concentration which exceeded the toxicity limits of 30 ppm, the IDLH defined by the NIOSH, and the diameter of the particles (1.54 ± 0.69 µm) that rose the PM2.5 concentration. These results are also useful for identifying personal protection equipment for rescue teams.

Suggested Citation

  • Sofia Ubaldi & Marco Conti & Francesco Marra & Paola Russo, 2023. "Identification of Key Events and Emissions during Thermal Abuse Testing on NCA 18650 Cells," Energies, MDPI, vol. 16(7), pages 1-21, April.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:7:p:3250-:d:1116425
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/7/3250/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/16/7/3250/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Ruiz, V. & Pfrang, A. & Kriston, A. & Omar, N. & Van den Bossche, P. & Boon-Brett, L., 2018. "A review of international abuse testing standards and regulations for lithium ion batteries in electric and hybrid electric vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1427-1452.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mohammadmahdi Ghiji & Vasily Novozhilov & Khalid Moinuddin & Paul Joseph & Ian Burch & Brigitta Suendermann & Grant Gamble, 2020. "A Review of Lithium-Ion Battery Fire Suppression," Energies, MDPI, vol. 13(19), pages 1-30, October.
    2. Ostanek, Jason K. & Li, Weisi & Mukherjee, Partha P. & Crompton, K.R. & Hacker, Christopher, 2020. "Simulating onset and evolution of thermal runaway in Li-ion cells using a coupled thermal and venting model," Applied Energy, Elsevier, vol. 268(C).
    3. Okay, Kamil & Eray, Sermet & Eray, Aynur, 2022. "Development of prototype battery management system for PV system," Renewable Energy, Elsevier, vol. 181(C), pages 1294-1304.
    4. E, Jiaqiang & Xiao, Hanxu & Tian, Sicheng & Huang, Yuxin, 2024. "A comprehensive review on thermal runaway model of a lithium-ion battery: Mechanism, thermal, mechanical, propagation, gas venting and combustion," Renewable Energy, Elsevier, vol. 229(C).
    5. David Marcos & Maitane Garmendia & Jon Crego & José Antonio Cortajarena, 2021. "Functional Safety BMS Design Methodology for Automotive Lithium-Based Batteries," Energies, MDPI, vol. 14(21), pages 1-19, October.
    6. Pedram Asef & Marzia Milan & Andrew Lapthorn & Sanjeevikumar Padmanaban, 2021. "Future Trends and Aging Analysis of Battery Energy Storage Systems for Electric Vehicles," Sustainability, MDPI, vol. 13(24), pages 1-28, December.
    7. Zhang, Guangxu & Wei, Xuezhe & Tang, Xuan & Zhu, Jiangong & Chen, Siqi & Dai, Haifeng, 2021. "Internal short circuit mechanisms, experimental approaches and detection methods of lithium-ion batteries for electric vehicles: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    8. Sun, Li & Li, Guanru & You, Fengqi, 2020. "Combined internal resistance and state-of-charge estimation of lithium-ion battery based on extended state observer," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    9. Cao, Jiahao & He, Yangjing & Feng, Jinxin & Lin, Shao & Ling, Ziye & Zhang, Zhengguo & Fang, Xiaoming, 2020. "Mini-channel cold plate with nano phase change material emulsion for Li-ion battery under high-rate discharge," Applied Energy, Elsevier, vol. 279(C).
    10. Shen, Dongxu & Lyu, Chao & Yang, Dazhi & Hinds, Gareth & Wang, Lixin, 2023. "Connection fault diagnosis for lithium-ion battery packs in electric vehicles based on mechanical vibration signals and broad belief network," Energy, Elsevier, vol. 274(C).
    11. Gandoman, Foad H. & Jaguemont, Joris & Goutam, Shovon & Gopalakrishnan, Rahul & Firouz, Yousef & Kalogiannis, Theodoros & Omar, Noshin & Van Mierlo, Joeri, 2019. "Concept of reliability and safety assessment of lithium-ion batteries in electric vehicles: Basics, progress, and challenges," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    12. Pius Victor Chombo & Yossapong Laoonual & Somchai Wongwises, 2021. "Lessons from the Electric Vehicle Crashworthiness Leading to Battery Fire," Energies, MDPI, vol. 14(16), pages 1-21, August.
    13. Ren, Dongsheng & Liu, Xiang & Feng, Xuning & Lu, Languang & Ouyang, Minggao & Li, Jianqiu & He, Xiangming, 2018. "Model-based thermal runaway prediction of lithium-ion batteries from kinetics analysis of cell components," Applied Energy, Elsevier, vol. 228(C), pages 633-644.
    14. Prakash Venugopal & Vigneswaran T., 2019. "State-of-Health Estimation of Li-ion Batteries in Electric Vehicle Using IndRNN under Variable Load Condition," Energies, MDPI, vol. 12(22), pages 1-29, November.
    15. Barone, G. & Buonomano, A. & Calise, F. & Forzano, C. & Palombo, A., 2019. "Building to vehicle to building concept toward a novel zero energy paradigm: Modelling and case studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 625-648.
    16. Buonomano, Annamaria, 2020. "Building to Vehicle to Building concept: A comprehensive parametric and sensitivity analysis for decision making aims," Applied Energy, Elsevier, vol. 261(C).
    17. Nicholas Gordon Garafolo & Siamak Farhad & Manindra Varma Koricherla & Shihao Wen & Roja Esmaeeli, 2022. "Modal Analysis of a Lithium-Ion Battery for Electric Vehicles," Energies, MDPI, vol. 15(13), pages 1-11, July.
    18. Ioan Aschilean & Mihai Varlam & Mihai Culcer & Mariana Iliescu & Mircea Raceanu & Adrian Enache & Maria Simona Raboaca & Gabriel Rasoi & Constantin Filote, 2018. "Hybrid Electric Powertrain with Fuel Cells for a Series Vehicle," Energies, MDPI, vol. 11(5), pages 1-12, May.
    19. Xu, Dongxin & Pan, Yongjun & Zhang, Xiaoxi & Dai, Wei & Liu, Binghe & Shuai, Qi, 2024. "Data-driven modelling and evaluation of a battery-pack system’s mechanical safety against bottom cone impact," Energy, Elsevier, vol. 290(C).
    20. Ren, Dongsheng & Feng, Xuning & Lu, Languang & He, Xiangming & Ouyang, Minggao, 2019. "Overcharge behaviors and failure mechanism of lithium-ion batteries under different test conditions," Applied Energy, Elsevier, vol. 250(C), pages 323-332.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:7:p:3250-:d:1116425. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.