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A Mini Review: Recent Advances in Asymmetrically Coordinated Atom Sites for High-Efficiency Hydrogen Evolution Reaction

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  • Junyang Ding

    (Institute for New Energy Materials and Low-Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
    State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, School of Resource, Environments and Materials, Nanning 530004, China)

  • Wenxian Liu

    (College of Materials Science and Engineering, Zhejiang University of Technology, 18 Chaowang Road, Hangzhou 310014, China)

  • Shusheng Zhang

    (College of Chemistry, Zhengzhou University, Zhengzhou 450001, China)

  • Jun Luo

    (Institute for New Energy Materials and Low-Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
    Shensi Laboratory, Shenzhen Institute for Advanced Study, University of Electronic Science and Technology of China, Longhua District, Shenzhen 518110, China)

  • Xijun Liu

    (State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, School of Resource, Environments and Materials, Nanning 530004, China)

Abstract

Energy is the substance foundation of human society. Single−atom catalysts (SACs) have emerged as promising electrode materials in the energy field owing to their unique characteristics. It was demonstrated that the hydrogen evolution reaction (HER) performance of SACs relies on the metal−centric species and the corresponding local coordination engineering. Herein, the recent progress relating to asymmetric atomic catalysts for the HER is reviewed, including low coordination, heteroatomic coordination, and bimetallic coordination. In addition, the connection between the coordination structures and the presented electrocatalytic performance was discussed. The main challenges that need to be addressed for the asymmetric atomic catalysts in the HER are summarized. Finally, some insights into the development of high−quality asymmetric atomic catalysts are included.

Suggested Citation

  • Junyang Ding & Wenxian Liu & Shusheng Zhang & Jun Luo & Xijun Liu, 2023. "A Mini Review: Recent Advances in Asymmetrically Coordinated Atom Sites for High-Efficiency Hydrogen Evolution Reaction," Energies, MDPI, vol. 16(6), pages 1-18, March.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:6:p:2664-:d:1095199
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    References listed on IDEAS

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    Cited by:

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