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Cost Efficiency Analysis of H 2 Production from Formic Acid by Molecular Catalysts

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  • Maria Solakidou

    (Laboratory of Biomimetic Catalysis & Hybrid Materials, Department of Chemistry, University of Ioannina, 45110 Ioannina, Greece)

  • Aikaterini Gemenetzi

    (Laboratory of Biomimetic Catalysis & Hybrid Materials, Department of Chemistry, University of Ioannina, 45110 Ioannina, Greece)

  • Georgia Koutsikou

    (Laboratory of Biomimetic Catalysis & Hybrid Materials, Department of Chemistry, University of Ioannina, 45110 Ioannina, Greece)

  • Marinos Theodorakopoulos

    (Laboratory of Biomimetic Catalysis & Hybrid Materials, Department of Chemistry, University of Ioannina, 45110 Ioannina, Greece)

  • Yiannis Deligiannakis

    (Laboratory of Physical Chemistry of Materials & Environment, Department of Physics, University of Ioannina, 45110 Ioannina, Greece)

  • Maria Louloudi

    (Laboratory of Biomimetic Catalysis & Hybrid Materials, Department of Chemistry, University of Ioannina, 45110 Ioannina, Greece)

Abstract

The development of low-carbon technologies that will facilitate the efficient use of hydrogen (H 2 ) as an energy carrier is a critical requirement of contemporary society. To this end, it is anticipated that the cost of H 2 production will become a key factor in tandem with production efficiency, process safety, and transport. Much effort has been made to create and develop new, reversible, and sustainable H 2 storage systems. Among current techniques, formic acid (FA) has been identified as an efficient energy carrier for H 2 storage. Numerous homogeneous catalysts based on transition metals with high activity and selectivity have been reported for selective FA dehydrogenation. In this review, we outline the recent advances in transition-metal molecular catalysts for FA dehydrogenation. Selected catalytic systems that could be implemented on an industrial scale and considered potential materials in fuel cell (FC) technology have been cost-evaluated. We highlight some critical engineering challenges faced during the technology’s scale-up process and explain other factors that are frequently ignored by academic researchers. Finally, we offer a critical assessment and identify several system limitations on an industrial scale that are currently impeding future implementation.

Suggested Citation

  • Maria Solakidou & Aikaterini Gemenetzi & Georgia Koutsikou & Marinos Theodorakopoulos & Yiannis Deligiannakis & Maria Louloudi, 2023. "Cost Efficiency Analysis of H 2 Production from Formic Acid by Molecular Catalysts," Energies, MDPI, vol. 16(4), pages 1-36, February.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:4:p:1723-:d:1062823
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    References listed on IDEAS

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    1. Quarton, Christopher J. & Samsatli, Sheila, 2020. "The value of hydrogen and carbon capture, storage and utilisation in decarbonising energy: Insights from integrated value chain optimisation," Applied Energy, Elsevier, vol. 257(C).
    2. Ruffini, Eleonora & Wei, Max, 2018. "Future costs of fuel cell electric vehicles in California using a learning rate approach," Energy, Elsevier, vol. 150(C), pages 329-341.
    3. Panagiota Stathi & Maria Solakidou & Maria Louloudi & Yiannis Deligiannakis, 2020. "From Homogeneous to Heterogenized Molecular Catalysts for H 2 Production by Formic Acid Dehydrogenation: Mechanistic Aspects, Role of Additives, and Co-Catalysts," Energies, MDPI, vol. 13(3), pages 1-25, February.
    4. Marinos Theodorakopoulos & Maria Solakidou & Yiannis Deligiannakis & Maria Louloudi, 2021. "A Use-Store-Reuse (USR) Concept in Catalytic HCOOH Dehydrogenation: Case-Study of a Ru-Based Catalytic System for Long-Term USR under Ambient O 2," Energies, MDPI, vol. 14(2), pages 1-10, January.
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