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Influence of Nickel Loading and the Synthesis Method on the Efficiency of Ni/TiO 2 Catalysts for Renewable Diesel Production

Author

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  • George Petropoulos

    (School of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, 26335 Patras, Greece)

  • John Zafeiropoulos

    (School of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, 26335 Patras, Greece)

  • Eleana Kordouli

    (School of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, 26335 Patras, Greece
    Department of Chemistry, University of Patras, 26504 Patras, Greece)

  • Alexis Lycourghiotis

    (School of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, 26335 Patras, Greece
    Department of Chemistry, University of Patras, 26504 Patras, Greece)

  • Christos Kordulis

    (Department of Chemistry, University of Patras, 26504 Patras, Greece
    Foundation of Research and Technology, Institute of Chemical Engineering Science (FORTH/ICE-HT) Stadiou Str. Platani, 26500 Patras, Greece)

  • Kyriakos Bourikas

    (School of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, 26335 Patras, Greece)

Abstract

The efficiency of Ni/TiO 2 catalysts for renewable diesel production was evaluated in the present study. Two series of catalysts were synthesized and characterized using various physicochemical techniques (N 2 physisorption, XRD, SEM, XPS, H 2 -TPR, and NH 3 –TPD). In the first series of catalysts, successive dry impregnations (SDI) were used for depositing 10, 20, 30, 50, and 60 wt.% Ni. The yield towards renewable diesel is maximized over the catalyst with 50 wt.% Ni loading. Selecting this optimum loading, a second series of catalysts were synthesized via three additional preparation methods: wet impregnation (WI) and deposition–precipitation using either ammonia (DP-NH 3 ) or urea (DP-Urea) as the precipitation agent. The catalysts’ efficiency in the production of green diesel is influenced by the preparation method following the order: DP-Urea > DP-NH 3 > WI ≈ SDI. The metallic surface area and the balanced acidity mainly determine the performance of the catalysts.

Suggested Citation

  • George Petropoulos & John Zafeiropoulos & Eleana Kordouli & Alexis Lycourghiotis & Christos Kordulis & Kyriakos Bourikas, 2023. "Influence of Nickel Loading and the Synthesis Method on the Efficiency of Ni/TiO 2 Catalysts for Renewable Diesel Production," Energies, MDPI, vol. 16(11), pages 1-15, May.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:11:p:4333-:d:1156006
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    References listed on IDEAS

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    1. Savvas L. Douvartzides & Nikolaos D. Charisiou & Kyriakos N. Papageridis & Maria A. Goula, 2019. "Green Diesel: Biomass Feedstocks, Production Technologies, Catalytic Research, Fuel Properties and Performance in Compression Ignition Internal Combustion Engines," Energies, MDPI, vol. 12(5), pages 1-41, February.
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