IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i3p997-d737586.html
   My bibliography  Save this article

Value-Added Pyrolysis of Waste Sourced High Molecular Weight Hydrocarbon Mixtures

Author

Listed:
  • Dominik Horváth

    (Research Centre for Biochemical, Environmental and Chemical Engineering, Department of MOL Hydrocarbon & Coal Processing, Faculty of Engineering, University of Pannonia, H-8200 Veszprém, Hungary)

  • Szabina Tomasek

    (Research Centre for Biochemical, Environmental and Chemical Engineering, Department of MOL Hydrocarbon & Coal Processing, Faculty of Engineering, University of Pannonia, H-8200 Veszprém, Hungary)

  • Norbert Miskolczi

    (Research Centre for Biochemical, Environmental and Chemical Engineering, Department of MOL Hydrocarbon & Coal Processing, Faculty of Engineering, University of Pannonia, H-8200 Veszprém, Hungary)

Abstract

In this study, Fischer-Tropsch paraffin mixture, heavy residue of waste polyethylene pyrolysis, shredded and crashed agricultural polyethylene waste and their combinations were pyrolysed both thermally and catalytically in a two-stage reactor system. During the experimental work, yields and compositions of pyrolysis products were studied as function of feedstock composition and catalyst placement. It was found that the average molecular weight of feedstocks and the presence of ZSM-5 catalyst also have significant effects on the product yields and the compositions. Feedstocks with high concentration of Fischer-Tropsch paraffin and real waste polyethylene resulted in deeper fragmentation in both thermal and thermo-catalytic pyrolysis. Due to the deeper fragmentation, they seemed to be suitable feedstocks for the production of C 6 –C 9 and C 10 –C 14 hydrocarbons. Meanwhile, for production of C 15 –C 21 hydrocarbons, the use of a higher concentration of heavy residue of waste polyethylene pyrolysis in the feedstocks is recommended. From the point of view of liquid hydrocarbon and isomer production, the placement of the catalyst into the 1st reactor proved to be more advantageous. When the catalyst was placed into the 2nd reactor, the product formation shifted to the more volatiles, isomers took part in secondary cracking reactions and aromatics formed in higher concentrations.

Suggested Citation

  • Dominik Horváth & Szabina Tomasek & Norbert Miskolczi, 2022. "Value-Added Pyrolysis of Waste Sourced High Molecular Weight Hydrocarbon Mixtures," Energies, MDPI, vol. 15(3), pages 1-13, January.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:3:p:997-:d:737586
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/3/997/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/3/997/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Ail, Snehesh Shivananda & Dasappa, S., 2016. "Biomass to liquid transportation fuel via Fischer Tropsch synthesis – Technology review and current scenario," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 267-286.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Iraklis Zahos-Siagos & Vlasios Karathanassis & Dimitrios Karonis, 2018. "Exhaust Emissions and Physicochemical Properties of n -Butanol/Diesel Blends with 2-Ethylhexyl Nitrate (EHN) or Hydrotreated Used Cooking Oil (HUCO) as Cetane Improvers," Energies, MDPI, vol. 11(12), pages 1-20, December.
    2. Magdeldin, Mohamed & Kohl, Thomas & Järvinen, Mika, 2017. "Techno-economic assessment of the by-products contribution from non-catalytic hydrothermal liquefaction of lignocellulose residues," Energy, Elsevier, vol. 137(C), pages 679-695.
    3. Sitka, Andrzej & Szulc, Piotr & Smykowski, Daniel & Jodkowski, Wiesław, 2021. "Application of poultry manure as an energy resource by its gasification in a prototype rotary counterflow gasifier," Renewable Energy, Elsevier, vol. 175(C), pages 422-429.
    4. Zhang, Hanfei & Wang, Ligang & Van herle, Jan & Maréchal, François & Desideri, Umberto, 2020. "Techno-economic evaluation of biomass-to-fuels with solid-oxide electrolyzer," Applied Energy, Elsevier, vol. 270(C).
    5. Savvas L. Douvartzides & Nikolaos D. Charisiou & Kyriakos N. Papageridis & Maria A. Goula, 2019. "Green Diesel: Biomass Feedstocks, Production Technologies, Catalytic Research, Fuel Properties and Performance in Compression Ignition Internal Combustion Engines," Energies, MDPI, vol. 12(5), pages 1-41, February.
    6. Enagi, Ibrahim I. & Al-attab, K.A. & Zainal, Z.A., 2018. "Liquid biofuels utilization for gas turbines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 43-55.
    7. Baena-Moreno, Francisco M. & Sebastia-Saez, Daniel & Pastor-Pérez, Laura & Reina, Tomas Ramirez, 2021. "Analysis of the potential for biogas upgrading to syngas via catalytic reforming in the United Kingdom," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    8. Qin, Shiyue & Chang, Shiyan & Yao, Qiang, 2018. "Modeling, thermodynamic and techno-economic analysis of coal-to-liquids process with different entrained flow coal gasifiers," Applied Energy, Elsevier, vol. 229(C), pages 413-432.
    9. Kreutz, Thomas G. & Larson, Eric D. & Elsido, Cristina & Martelli, Emanuele & Greig, Chris & Williams, Robert H., 2020. "Techno-economic prospects for producing Fischer-Tropsch jet fuel and electricity from lignite and woody biomass with CO2 capture for EOR," Applied Energy, Elsevier, vol. 279(C).
    10. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part I: Chemical pathways and bio-oil upgrading," Renewable Energy, Elsevier, vol. 185(C), pages 483-505.
    11. Pleyer, Olga & Vrtiška, Dan & Straka, Petr & Šimáček, Pavel, 2024. "Co-processing of BTL Fischer-Tropsch wax and heavy vacuum gas oil," Renewable Energy, Elsevier, vol. 225(C).
    12. Dossow, Marcel & Dieterich, Vincent & Hanel, Andreas & Spliethoff, Hartmut & Fendt, Sebastian, 2021. "Improving carbon efficiency for an advanced Biomass-to-Liquid process using hydrogen and oxygen from electrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    13. Snehesh, Ail Shivananda & Mukunda, H.S. & Mahapatra, Sadhan & Dasappa, S., 2017. "Fischer-Tropsch route for the conversion of biomass to liquid fuels - Technical and economic analysis," Energy, Elsevier, vol. 130(C), pages 182-191.
    14. Rakesh N, & Dasappa, S., 2018. "A critical assessment of tar generated during biomass gasification - Formation, evaluation, issues and mitigation strategies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 1045-1064.
    15. Wang, Ligang & Chen, Ming & Küngas, Rainer & Lin, Tzu-En & Diethelm, Stefan & Maréchal, François & Van herle, Jan, 2019. "Power-to-fuels via solid-oxide electrolyzer: Operating window and techno-economics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 110(C), pages 174-187.
    16. Watson, Jamison & Zhang, Yuanhui & Si, Buchun & Chen, Wan-Ting & de Souza, Raquel, 2018. "Gasification of biowaste: A critical review and outlooks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 83(C), pages 1-17.
    17. Saeidi, Samrand & Najari, Sara & Fazlollahi, Farhad & Nikoo, Maryam Khoshtinat & Sefidkon, Fatemeh & Klemeš, Jiří Jaromír & Baxter, Larry L., 2017. "Mechanisms and kinetics of CO2 hydrogenation to value-added products: A detailed review on current status and future trends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1292-1311.
    18. Andrzej Sitka & Wiesław Jodkowski & Piotr Szulc & Daniel Smykowski & Bogusław Szumiło, 2021. "Study of the Properties and Particulate Matter Content of the Gas from the Innovative Pilot-Scale Gasification Installation with Integrated Ceramic Filter," Energies, MDPI, vol. 14(22), pages 1-11, November.
    19. Kejie Wang & Ge Kong & Guanyu Zhang & Xin Zhang & Lujia Han & Xuesong Zhang, 2022. "Steam Gasification of Torrefied/Carbonized Wheat Straw for H 2 -Enriched Syngas Production and Tar Reduction," IJERPH, MDPI, vol. 19(17), pages 1-15, August.
    20. Herz, Gregor & Reichelt, Erik & Jahn, Matthias, 2018. "Techno-economic analysis of a co-electrolysis-based synthesis process for the production of hydrocarbons," Applied Energy, Elsevier, vol. 215(C), pages 309-320.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:3:p:997-:d:737586. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.