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Combined Bio-Hydrogen, Heat, and Power Production Based on Residual Biomass Gasification: Energy, Exergy, and Renewability Assessment of an Alternative Process Configuration

Author

Listed:
  • Mauro Prestipino

    (Department of Engineering, University of Messina, C.da di Dio 1, 98166 Messina, Italy)

  • Antonio Piccolo

    (Department of Engineering, University of Messina, C.da di Dio 1, 98166 Messina, Italy)

  • Maria Francesca Polito

    (Department of Engineering, University of Messina, C.da di Dio 1, 98166 Messina, Italy)

  • Antonio Galvagno

    (Department of Engineering, University of Messina, C.da di Dio 1, 98166 Messina, Italy)

Abstract

Bio-hydrogen from residual biomass may involve energy-intensive pre-treatments for drying and size management, as in the case of wet agro-industrial residues. This work assesses the performance of an alternative process layout for bio-hydrogen production from citrus peel gasification, with the aim of cogenerating heat and power along with hydrogen, using minimal external energy sources. The process consists of an air-steam fluidized bed reactor, a hydrogen separation unit, a hydrogen compression unit, and a combined heat and power unit fed by the off-gas of the separation unit. Process simulations were carried out to perform sensitivity analyses to understand the variation in bio-hydrogen production’s thermodynamic and environmental performance when the steam to biomass ratios (S/B) vary from 0 to 1.25 at 850 °C. In addition, energy and exergy efficiencies and the integrated renewability (IR) of bio-hydrogen production are evaluated. As main results, the analysis showed that the highest hydrogen yield is 40.1 kg H2 per mass of dry biomass at S/B = 1.25. Under these conditions, the exergy efficiency of the polygeneration system is 33%, the IR is 0.99, and the carbon footprint is −1.9 kg CO2-eq /kg H2 . Negative carbon emissions and high values of the IR are observed due to the substitution of non-renewable resources operated by the cogenerated streams. The proposed system demonstrated for the first time the potential of bio-hydrogen production from citrus peel and the effects of steam flow variation on thermodynamic performance. Furthermore, the authors demonstrated how bio-hydrogen could be produced with minimal external energy input while cogenerating net heat and power by exploiting the off-gas in a cogeneration unit.

Suggested Citation

  • Mauro Prestipino & Antonio Piccolo & Maria Francesca Polito & Antonio Galvagno, 2022. "Combined Bio-Hydrogen, Heat, and Power Production Based on Residual Biomass Gasification: Energy, Exergy, and Renewability Assessment of an Alternative Process Configuration," Energies, MDPI, vol. 15(15), pages 1-17, July.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:15:p:5524-:d:875830
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    References listed on IDEAS

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    1. Nadia Cerone & Francesco Zimbardi, 2021. "Effects of Oxygen and Steam Equivalence Ratios on Updraft Gasification of Biomass," Energies, MDPI, vol. 14(9), pages 1-18, May.
    2. Marcin Siedlecki & Wiebren De Jong & Adrian H.M. Verkooijen, 2011. "Fluidized Bed Gasification as a Mature And Reliable Technology for the Production of Bio-Syngas and Applied in the Production of Liquid Transportation Fuels—A Review," Energies, MDPI, vol. 4(3), pages 1-46, March.
    3. Prestipino, Mauro & Salmeri, Fabio & Cucinotta, Filippo & Galvagno, Antonio, 2021. "Thermodynamic and environmental sustainability analysis of electricity production from an integrated cogeneration system based on residual biomass: A life cycle approach," Applied Energy, Elsevier, vol. 295(C).
    4. Famoso, F. & Prestipino, M. & Brusca, S. & Galvagno, A., 2020. "Designing sustainable bioenergy from residual biomass: Site allocation criteria and energy/exergy performance indicators," Applied Energy, Elsevier, vol. 274(C).
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    1. Ratikorn Sornumpol & Dang Saebea & Amornchai Arpornwichanop & Yaneeporn Patcharavorachot, 2023. "Process Optimization and CO 2 Emission Analysis of Coal/Biomass Gasification Integrated with a Chemical Looping Process," Energies, MDPI, vol. 16(6), pages 1-17, March.
    2. Squadrito, Gaetano & Maggio, Gaetano & Nicita, Agatino, 2023. "The green hydrogen revolution," Renewable Energy, Elsevier, vol. 216(C).
    3. Matteo Baldelli & Lorenzo Bartolucci & Stefano Cordiner & Giorgio D’Andrea & Emanuele De Maina & Vincenzo Mulone, 2023. "Biomass to H2: Evaluation of the Impact of PV and TES Power Supply on the Performance of an Integrated Bio-Thermo-Chemical Upgrading Process for Wet Residual Biomass," Energies, MDPI, vol. 16(7), pages 1-17, March.
    4. Thuan Duc Mai & Tamás Koós & Emese Sebe & Zoltán Siménfalvi & András Arnold Kállay, 2023. "Efficiency Enhancement of the Single Line Multi-Stage Gasification of Hungarian Low-Rank Coal: Effects of Gasification Temperature and Steam/Carbon (S/C) Ratio," Energies, MDPI, vol. 16(11), pages 1-16, May.
    5. Tera, Ibrahim & Zhang, Shengan & Liu, Guilian, 2024. "A conceptual hydrogen, heat and power polygeneration system based on biomass gasification, SOFC and waste heat recovery units: Energy, exergy, economic and emergy (4E) assessment," Energy, Elsevier, vol. 295(C).
    6. Yiru Zhao & Nathalie Bourgougnon & Jean-Louis Lanoisellé & Thomas Lendormi, 2022. "Biofuel Production from Seaweeds: A Comprehensive Review," Energies, MDPI, vol. 15(24), pages 1-34, December.

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