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Is the Fischer-Tropsch Conversion of Biogas-Derived Syngas to Liquid Fuels Feasible at Atmospheric Pressure?

Author

Listed:
  • Rawan Hakawati

    (School of Chemistry and Chemical Engineering, Queen’s University Belfast, Belfast BT9 5AG, UK)

  • Beatrice Smyth

    (School of Mechanical and Aerospace Engineering, Queen’s University Belfast, Belfast BT9 5AH, UK)

  • Helen Daly

    (School of Chemistry and Chemical Engineering, Queen’s University Belfast, Belfast BT9 5AG, UK
    Current address: School of Chemical Engineering and Analytical Sciences, University of Manchester, Manchester M13 9PL, UK.)

  • Geoffrey McCullough

    (School of Mechanical and Aerospace Engineering, Queen’s University Belfast, Belfast BT9 5AH, UK)

  • David Rooney

    (School of Chemistry and Chemical Engineering, Queen’s University Belfast, Belfast BT9 5AG, UK)

Abstract

Biogas resulting from anaerobic digestion can be utilized for the production of liquid fuels via reforming to syngas followed by the Fischer-Tropsch reaction. Renewable liquid fuels are highly desirable due to their potential for use in existing infrastructure, but current Fischer-Tropsch processes, which require operating pressures of 2–4 MPa (20–40 bar), are unsuitable for the relatively small scale of typical biogas production facilities in the EU, which are agriculture-based. This paper investigates the feasibility of producing liquid fuels from biogas-derived syngas at atmospheric pressure, with a focus on the system’s response to various interruption factors, such as total loss of feed gas, variations to feed ratio, and technical problems in the furnace. Results of laboratory testing showed that the liquid fuel selectivity could reach 60% under the studied conditions of 488 K (215 °C), H 2 /CO = 2 and 0.1 MPa (1 bar) over a commercial Fischer–Tropsch catalyst. Analysis indicated that the catalyst had two active sites for propagation, one site for the generation of methane and another for the production of liquid fuels and wax products. However, although the production of liquid fuels was verified at atmospheric pressure with high liquid fuel selectivity, the control of such a system to maintain activity is crucial. From an economic perspective, the system would require subsidies to achieve financial viability.

Suggested Citation

  • Rawan Hakawati & Beatrice Smyth & Helen Daly & Geoffrey McCullough & David Rooney, 2019. "Is the Fischer-Tropsch Conversion of Biogas-Derived Syngas to Liquid Fuels Feasible at Atmospheric Pressure?," Energies, MDPI, vol. 12(6), pages 1-28, March.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:6:p:1031-:d:214569
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    1. Scholten, Daniel & Bosman, Rick, 2016. "The geopolitics of renewables; exploring the political implications of renewable energy systems," Technological Forecasting and Social Change, Elsevier, vol. 103(C), pages 273-283.
    2. Dorian, James P. & Franssen, Herman T. & Simbeck, Dale R., 2006. "Global challenges in energy," Energy Policy, Elsevier, vol. 34(15), pages 1984-1991, October.
    3. Mahrokh Samavati & Andrew Martin & Massimo Santarelli & Vera Nemanova, 2018. "Synthetic Diesel Production as a Form of Renewable Energy Storage," Energies, MDPI, vol. 11(5), pages 1-21, May.
    4. Rei-Yu Chein & Wen-Hwai Hsu, 2018. "Analysis of Syngas Production from Biogas via the Tri-Reforming Process," Energies, MDPI, vol. 11(5), pages 1-18, April.
    5. Morten Simonsen & Hans Jakob Walnum, 2011. "Energy Chain Analysis of Passenger Car Transport," Energies, MDPI, vol. 4(2), pages 1-28, February.
    6. Smyth, Beatrice M. & Murphy, Jerry D. & O'Brien, Catherine M., 2009. "What is the energy balance of grass biomethane in Ireland and other temperate northern European climates?," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2349-2360, December.
    7. Marcin Siedlecki & Wiebren De Jong & Adrian H.M. Verkooijen, 2011. "Fluidized Bed Gasification as a Mature And Reliable Technology for the Production of Bio-Syngas and Applied in the Production of Liquid Transportation Fuels—A Review," Energies, MDPI, vol. 4(3), pages 1-46, March.
    8. Hakawati, Rawan & Smyth, Beatrice M. & McCullough, Geoffrey & De Rosa, Fabio & Rooney, David, 2017. "What is the most energy efficient route for biogas utilization: Heat, electricity or transport?," Applied Energy, Elsevier, vol. 206(C), pages 1076-1087.
    9. Scarlat, Nicolae & Dallemand, Jean-François & Fahl, Fernando, 2018. "Biogas: Developments and perspectives in Europe," Renewable Energy, Elsevier, vol. 129(PA), pages 457-472.
    10. Lee, Chul-Yong & Huh, Sung-Yoon, 2017. "Forecasting the diffusion of renewable electricity considering the impact of policy and oil prices: The case of South Korea," Applied Energy, Elsevier, vol. 197(C), pages 29-39.
    11. Ajay Kumar & David D. Jones & Milford A. Hanna, 2009. "Thermochemical Biomass Gasification: A Review of the Current Status of the Technology," Energies, MDPI, vol. 2(3), pages 1-26, July.
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