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Simulation of a Pilot Scale Power-to-Liquid Plant Producing Synthetic Fuel and Wax by Combining Fischer–Tropsch Synthesis and SOEC

Author

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  • Simon Pratschner

    (Institute of Chemical, Environmental and Bioscience Engineering, TU Wien, Getreidemarkt 9/166, 1060 Vienna, Austria)

  • Martin Hammerschmid

    (Institute of Chemical, Environmental and Bioscience Engineering, TU Wien, Getreidemarkt 9/166, 1060 Vienna, Austria)

  • Florian J. Müller

    (Institute of Chemical, Environmental and Bioscience Engineering, TU Wien, Getreidemarkt 9/166, 1060 Vienna, Austria)

  • Stefan Müller

    (Institute of Chemical, Environmental and Bioscience Engineering, TU Wien, Getreidemarkt 9/166, 1060 Vienna, Austria)

  • Franz Winter

    (Institute of Chemical, Environmental and Bioscience Engineering, TU Wien, Getreidemarkt 9/166, 1060 Vienna, Austria)

Abstract

Power-to-Liquid (PtL) plants can viably implement carbon capture and utilization technologies in Europe. In addition, local CO 2 sources can be valorized to substitute oil and gas imports. This work’s aim was to determine the PtL efficiency obtained by combining a solid oxide electrolyzer (SOEC) and Fischer–Tropsch synthesis. In addition, a recommended plant configuration to produce synthetic fuel and wax at pilot scale is established. The presented process configurations with and without a tail gas reformer were modeled and analyzed using IPSEpro as simulation software. A maximum mass flow rate of naphtha, middle distillate and wax of 57.8 kg/h can be realized by using a SOEC unit operated in co-electrolysis mode, with a rated power of 1 MW el. . A maximum PtL efficiency of 50.8% was found for the process configuration without a tail gas reformer. Implementing a tail gas reformer resulted in a maximum PtL efficiency of 62.7%. Hence, the reforming of tail gas is highly beneficial for the PtL plant’s productivity and efficiency. Nevertheless, a process configuration based on the recirculation of tail gas without a reformer is recommended as a feasible solution to manage the transition from laboratory scale to industrial applications.

Suggested Citation

  • Simon Pratschner & Martin Hammerschmid & Florian J. Müller & Stefan Müller & Franz Winter, 2022. "Simulation of a Pilot Scale Power-to-Liquid Plant Producing Synthetic Fuel and Wax by Combining Fischer–Tropsch Synthesis and SOEC," Energies, MDPI, vol. 15(11), pages 1-22, June.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:11:p:4134-:d:831673
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    References listed on IDEAS

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    1. Herz, Gregor & Reichelt, Erik & Jahn, Matthias, 2018. "Techno-economic analysis of a co-electrolysis-based synthesis process for the production of hydrocarbons," Applied Energy, Elsevier, vol. 215(C), pages 309-320.
    2. Simon Pratschner & Pavel Skopec & Jan Hrdlicka & Franz Winter, 2021. "Power-to-Green Methanol via CO 2 Hydrogenation—A Concept Study including Oxyfuel Fluidized Bed Combustion of Biomass," Energies, MDPI, vol. 14(15), pages 1-33, July.
    3. Becker, W.L. & Braun, R.J. & Penev, M. & Melaina, M., 2012. "Production of Fischer–Tropsch liquid fuels from high temperature solid oxide co-electrolysis units," Energy, Elsevier, vol. 47(1), pages 99-115.
    4. Cinti, Giovanni & Baldinelli, Arianna & Di Michele, Alessandro & Desideri, Umberto, 2016. "Integration of Solid Oxide Electrolyzer and Fischer-Tropsch: A sustainable pathway for synthetic fuel," Applied Energy, Elsevier, vol. 162(C), pages 308-320.
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    Cited by:

    1. Vishal Ram & Surender Reddy Salkuti, 2023. "An Overview of Major Synthetic Fuels," Energies, MDPI, vol. 16(6), pages 1-35, March.
    2. Atsonios, Konstantinos & Li, Jun & Inglezakis, Vassilis J., 2023. "Process analysis and comparative assessment of advanced thermochemical pathways for e-kerosene production," Energy, Elsevier, vol. 278(PA).
    3. Martin Hammerschmid & Alexander Bartik & Florian Benedikt & Marton Veress & Simon Pratschner & Stefan Müller & Hermann Hofbauer, 2023. "Economic and Ecological Impacts on the Integration of Biomass-Based SNG and FT Diesel in the Austrian Energy System," Energies, MDPI, vol. 16(16), pages 1-29, August.

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