IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i5p1272-d506004.html
   My bibliography  Save this article

Influence of Water Saturation, Grain Size of Quartz Sand and Hydrate-Former on the Gas Hydrate Formation

Author

Listed:
  • Yulia Zaripova

    (Department of Physical Chemistry, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

  • Vladimir Yarkovoi

    (Department of Physical Chemistry, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

  • Mikhail Varfolomeev

    (Department of Physical Chemistry, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia
    Department of Petroleum Engineering, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

  • Rail Kadyrov

    (Department of Petroleum Engineering, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia)

  • Andrey Stoporev

    (Department of Physical Chemistry, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia
    Department of Petroleum Engineering, Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia
    Nikolaev Institute of Inorganic Chemistry SB RAS, Ac. Lavrentiev Ave. 3, 630090 Novosibirsk, Russia
    Department of Natural Sciences, Novosibirsk State University, Pirogova Str. 1, 630090 Novosibirsk, Russia)

Abstract

The development of technologies for the accelerated formation or decomposition of gas hydrates is an urgent topic. This will make it possible to utilize a gas, including associated petroleum one, into a hydrate state for its further use or to produce natural gas from hydrate-saturated sediments. In this work, the effect of water content in wide range (0.7–50 mass%) and the size of quartz sand particles (porous medium; <50 μm, 125–160 μm and unsifted sand) on the formation of methane and methane-propane hydrates at close conditions (subcooling value) has been studied. High-pressure differential scanning calorimetry and X-ray computed tomography techniques were employed to analyze the hydrate formation process and pore sizes, respectively. The exponential growth of water to hydrate conversion with a decrease in the water content due to the rise of water–gas surface available for hydrate formation was revealed. Sieving the quartz sand resulted in a significant increase in water to hydrate conversion (59% for original sand compared to more than 90% for sieved sand). It was supposed that water suction due to the capillary forces influences both methane and methane-propane hydrates formation as well with latent hydrate forming up to 60% either without a detectable heat flow or during the ice melting. This emphasizes the importance of being developed for water–gas (ice–gas) interface to effectively transform water into the hydrate state. In any case, the ice melting (presence of thawing water) may allow a higher conversion degree. Varying the water content and the sand grain size allows to control the degree of water to hydrate conversion and subcooling achieved before the hydrate formation. Taking into account experimental error, the equilibrium conditions of hydrates formation do not change in all studied cases. The data obtained can be useful in developing a method for obtaining hydrates under static conditions.

Suggested Citation

  • Yulia Zaripova & Vladimir Yarkovoi & Mikhail Varfolomeev & Rail Kadyrov & Andrey Stoporev, 2021. "Influence of Water Saturation, Grain Size of Quartz Sand and Hydrate-Former on the Gas Hydrate Formation," Energies, MDPI, vol. 14(5), pages 1-15, February.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:5:p:1272-:d:506004
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/5/1272/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/14/5/1272/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Fatima Doria Benmesbah & Livio Ruffine & Pascal Clain & Véronique Osswald & Olivia Fandino & Laurence Fournaison & Anthony Delahaye, 2020. "Methane Hydrate Formation and Dissociation in Sand Media: Effect of Water Saturation, Gas Flowrate and Particle Size," Energies, MDPI, vol. 13(19), pages 1-21, October.
    2. Misyura, S.Y., 2019. "Non-stationary combustion of natural and artificial methane hydrate at heterogeneous dissociation," Energy, Elsevier, vol. 181(C), pages 589-602.
    3. Feng, Jing-Chun & Wang, Yi & Li, Xiao-Sen & Chen, Zhao-Yang & Li, Gang & Zhang, Yu, 2015. "Investigation into optimization condition of thermal stimulation for hydrate dissociation in the sandy reservoir," Applied Energy, Elsevier, vol. 154(C), pages 995-1003.
    4. Misyura, S.Y., 2020. "Dissociation of various gas hydrates (methane hydrate, double gas hydrates of methane-propane and methane-isopropanol) during combustion: Assessing the combustion efficiency," Energy, Elsevier, vol. 206(C).
    5. Xie, Yan & Zheng, Tao & Zhong, Jin-Rong & Zhu, Yu-Jie & Wang, Yun-Fei & Zhang, Yu & Li, Rui & Yuan, Qing & Sun, Chang-Yu & Chen, Guang-Jin, 2020. "Experimental research on self-preservation effect of methane hydrate in porous sediments," Applied Energy, Elsevier, vol. 268(C).
    6. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.
    7. Yu Zhang & Xiaosen Li & Yi Wang & Zhaoyang Chen & Gang Li, 2017. "Methane Hydrate Formation in Marine Sediment from South China Sea with Different Water Saturations," Energies, MDPI, vol. 10(4), pages 1-13, April.
    8. Sun, Yi-Fei & Wang, Yun-Fei & Zhong, Jin-Rong & Li, Wen-Zhi & Li, Rui & Cao, Bo-Jian & Kan, Jing-Yu & Sun, Chang-Yu & Chen, Guang-Jin, 2019. "Gas hydrate exploitation using CO2/H2 mixture gas by semi-continuous injection-production mode," Applied Energy, Elsevier, vol. 240(C), pages 215-225.
    9. Chong, Zheng Rong & Yang, She Hern Bryan & Babu, Ponnivalavan & Linga, Praveen & Li, Xiao-Sen, 2016. "Review of natural gas hydrates as an energy resource: Prospects and challenges," Applied Energy, Elsevier, vol. 162(C), pages 1633-1652.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yiwei Wang & Lin Wang & Zhen Hu & Youli Li & Qiang Sun & Aixian Liu & Lanying Yang & Jing Gong & Xuqiang Guo, 2021. "The Thermodynamic and Kinetic Effects of Sodium Lignin Sulfonate on Ethylene Hydrate Formation," Energies, MDPI, vol. 14(11), pages 1-19, June.
    2. Olga Gaidukova & Sergei Misyura & Pavel Strizhak, 2022. "Key Areas of Gas Hydrates Study: Review," Energies, MDPI, vol. 15(5), pages 1-18, February.
    3. Daria Sergeeva & Vladimir Istomin & Evgeny Chuvilin & Boris Bukhanov & Natalia Sokolova, 2021. "Influence of Hydrate-Forming Gas Pressure on Equilibrium Pore Water Content in Soils," Energies, MDPI, vol. 14(7), pages 1-17, March.
    4. Yulia F. Chirkova & Ulukbek Zh. Mirzakimov & Matvei E. Semenov & Roman S. Pavelyev & Mikhail A. Varfolomeev, 2022. "Promising Hydrate Formation Promoters Based on Sodium Sulfosuccinates of Polyols," Energies, MDPI, vol. 16(1), pages 1-9, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Olga Gaidukova & Sergei Misyura & Pavel Strizhak, 2022. "Key Areas of Gas Hydrates Study: Review," Energies, MDPI, vol. 15(5), pages 1-18, February.
    2. Li, Bo & Zhang, Ting-Ting & Wan, Qing-Cui & Feng, Jing-Chun & Chen, Ling-Ling & Wei, Wen-Na, 2021. "Kinetic study of methane hydrate development involving the role of self-preservation effect in frozen sandy sediments," Applied Energy, Elsevier, vol. 300(C).
    3. Beckwée, Emile Jules & Houlleberghs, Maarten & Ciocarlan, Radu-George & Chandran, C. Vinod & Radhakrishnan, Sambhu & Hanssens, Lucas & Cool, Pegie & Martens, Johan & Breynaert, Eric & Baron, Gino V. &, 2024. "Structure I methane hydrate confined in C8-grafted SBA-15: A highly efficient storage system enabling ultrafast methane loading and unloading," Applied Energy, Elsevier, vol. 353(PA).
    4. Ren, Liang-Liang & Jiang, Min & Wang, Ling-Ban & Zhu, Yi-Jian & Li, Zhi & Sun, Chang-Yu & Chen, Guang-Jin, 2020. "Gas hydrate exploitation and carbon dioxide sequestration under maintaining the stiffness of hydrate-bearing sediments," Energy, Elsevier, vol. 194(C).
    5. Sergey Y. Misyura & Igor G. Donskoy, 2021. "Dissociation and Combustion of a Layer of Methane Hydrate Powder: Ways to Increase the Efficiency of Combustion and Degassing," Energies, MDPI, vol. 14(16), pages 1-16, August.
    6. Xie, Yan & Zheng, Tao & Zhong, Jin-Rong & Zhu, Yu-Jie & Wang, Yun-Fei & Zhang, Yu & Li, Rui & Yuan, Qing & Sun, Chang-Yu & Chen, Guang-Jin, 2020. "Experimental research on self-preservation effect of methane hydrate in porous sediments," Applied Energy, Elsevier, vol. 268(C).
    7. Ren, Liang-Liang & Qi, Ya-Hui & Chen, Jun-Li & Sun, Yi-Fei & Sun, Chang-Yu & Wang, Xiao-Hui & Chen, Guang-Jin & Yuan, Qing & Pang, Wei-Xin & Li, Qing-Ping, 2020. "Dependence of acoustic properties on hydrate-bearing sediments with heterogeneous distribution," Applied Energy, Elsevier, vol. 275(C).
    8. Dmitrii Antonov & Olga Gaidukova & Galina Nyashina & Dmitrii Razumov & Pavel Strizhak, 2022. "Prospects of Using Gas Hydrates in Power Plants," Energies, MDPI, vol. 15(12), pages 1-20, June.
    9. Olga Gaidukova & Sergey Misyura & Vladimir Morozov & Pavel Strizhak, 2023. "Gas Hydrates: Applications and Advantages," Energies, MDPI, vol. 16(6), pages 1-19, March.
    10. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    11. Wang, Yi & Feng, Jing-Chun & Li, Xiao-Sen & Zhang, Yu, 2018. "Influence of well pattern on gas recovery from methane hydrate reservoir by large scale experimental investigation," Energy, Elsevier, vol. 152(C), pages 34-45.
    12. Stanislav L. Borodin & Nail G. Musakaev & Denis S. Belskikh, 2022. "Mathematical Modeling of a Non-Isothermal Flow in a Porous Medium Considering Gas Hydrate Decomposition: A Review," Mathematics, MDPI, vol. 10(24), pages 1-17, December.
    13. Feng, Jing-Chun & Wang, Yi & Li, Xiao-Sen, 2017. "Entropy generation analysis of hydrate dissociation by depressurization with horizontal well in different scales of hydrate reservoirs," Energy, Elsevier, vol. 125(C), pages 62-71.
    14. Wang, Yi & Feng, Jing-Chun & Li, Xiao-Sen & Zhang, Yu, 2017. "Experimental investigation of optimization of well spacing for gas recovery from methane hydrate reservoir in sandy sediment by heat stimulation," Applied Energy, Elsevier, vol. 207(C), pages 562-572.
    15. Lei Wang & Jin Yang & Lilin Li & Ting Sun & Dongsheng Xu, 2022. "Study on the Mechanical Properties of Natural Gas Hydrate Reservoirs with Multicomponent under Different Engineering Conditions," Energies, MDPI, vol. 15(23), pages 1-23, November.
    16. Yin, Zhenyuan & Zhang, Shuyu & Koh, Shanice & Linga, Praveen, 2020. "Estimation of the thermal conductivity of a heterogeneous CH4-hydrate bearing sample based on particle swarm optimization," Applied Energy, Elsevier, vol. 271(C).
    17. Feng, Qian & Liu, Xian-jie & Peng, Zhi-gang & Zheng, Yong & Huo, Jin-hua & Liu, Huan, 2019. "Preparation of low hydration heat cement slurry with micro-encapsulated thermal control material," Energy, Elsevier, vol. 187(C).
    18. Dong, Shuang & Yang, Mingjun & Zhang, Lei & Zheng, Jia-nan & Song, Yongchen, 2023. "Methane hydrate exploitation characteristics and thermodynamic non-equilibrium mechanisms by long depressurization method," Energy, Elsevier, vol. 280(C).
    19. Sergey Misyura & Pavel Strizhak & Anton Meleshkin & Vladimir Morozov & Olga Gaidukova & Nikita Shlegel & Maria Shkola, 2023. "A Review of Gas Capture and Liquid Separation Technologies by CO 2 Gas Hydrate," Energies, MDPI, vol. 16(8), pages 1-20, April.
    20. Wang, Xiao-Hui & Chen, Yun & Li, Xing-Xun & Xu, Qiang & Kan, Jing-Yu & Sun, Chang-Yu & Chen, Guang-Jin, 2021. "An exergy-based energy efficiency analysis on gas production from gas hydrates reservoir by brine stimulation combined depressurization method," Energy, Elsevier, vol. 231(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:5:p:1272-:d:506004. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.