IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i3p609-d486858.html
   My bibliography  Save this article

High Purity/Recovery Separation of Propylene from Propyne Using Anion Pillared Metal-Organic Framework: Application of Vacuum Swing Adsorption (VSA)

Author

Listed:
  • Majeda Khraisheh

    (Department of Chemical Engineering, College of Engineering, Qatar University, Doha P.O. Box 2713, Qatar)

  • Fares AlMomani

    (Department of Chemical Engineering, College of Engineering, Qatar University, Doha P.O. Box 2713, Qatar)

  • Gavin Walker

    (Department of Chemical Sciences, SSPC, Bernal Institute, University of Limerick, V94 T9PX Limerick, Ireland)

Abstract

Propylene is one of the world’s most important basic olefin raw material used in the production of a vast array of polymers and other chemicals. The need for high purity grade of propylene is essential and traditionally achieved by the very energy-intensive cryogenic separation. In this study, a pillared inorganic anion SIF 6 2− was used as a highly selective C 3 H 4 due to the square grid pyrazine-based structure. Single gas adsorption revealed a very high C 3 H 4 uptake value (3.32, 3.12, 2.97 and 2.43 mmol·g −1 at 300, 320, 340 and 360 K, respectively). The values for propylene for the same temperatures were 2.73, 2.64, 2.31 and 1.84 mmol·g −1 , respectively. Experimental results were obtained for the two gases fitted using Langmuir and Toth models. The former had a varied degree of representation of the system with a better presentation of the adsorption of the propylene compared to the propyne system. The Toth model regression offered a better fit of the experimental data over the entire range of pressures. The representation and fitting of the models are important to estimate the energy in the form of the isosteric heats of adsorption (Q st ), which were found to be 45 and 30 kJ·Kmol −1 for propyne and propylene, respectively. A Higher Q st value reveals strong interactions between the solid and the gas. The dynamic breakthrough for binary mixtures of C 3 H 4 /C 3 H 6 (30:70 v / v )) were established. Heavier propylene molecules were eluted first from the column compared to the lighter propyne. Vacuum swing adsorption was best suited for the application of strongly bound materials in adsorbents. A six-step cycle was used for the recovery of high purity C 3 H 4 and C 3 H 6 . The VSA system was tested with respect to changing blowdown time and purge time as well as energy requirements. It was found that the increase in purge time had an appositive effect on C 3 H 6 recovery but reduced productivity and recovery. Accordingly, under the experimental conditions used in this study for VSA, the purge time of 600 s was considered a suitable trade-off time for purging. Recovery up to 99%, purity of 98.5% were achieved at a purge time of 600 s. Maximum achieved purity and recovery were 97.4% and 98.5% at 100 s blowdown time. Energy and power consumption varied between 63–70 kWh/ton at the range of purge and blowdown time used. The VSA offers a trade-off and cost-effective technology for the recovery and separation of olefins and paraffin at low pressure and high purity.

Suggested Citation

  • Majeda Khraisheh & Fares AlMomani & Gavin Walker, 2021. "High Purity/Recovery Separation of Propylene from Propyne Using Anion Pillared Metal-Organic Framework: Application of Vacuum Swing Adsorption (VSA)," Energies, MDPI, vol. 14(3), pages 1-19, January.
  • Handle: RePEc:gam:jeners:v:14:y:2021:i:3:p:609-:d:486858
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/3/609/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/14/3/609/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Qasem, Naef A.A. & Ben-Mansour, Rached, 2018. "Adsorption breakthrough and cycling stability of carbon dioxide separation from CO2/N2/H2O mixture under ambient conditions using 13X and Mg-MOF-74," Applied Energy, Elsevier, vol. 230(C), pages 1093-1107.
    2. Hedin, Niklas & Andersson, Linnéa & Bergström, Lennart & Yan, Jinyue, 2013. "Adsorbents for the post-combustion capture of CO2 using rapid temperature swing or vacuum swing adsorption," Applied Energy, Elsevier, vol. 104(C), pages 418-433.
    3. Qasem, Naef A.A. & Ben-Mansour, Rached & Habib, Mohamed A., 2018. "An efficient CO2 adsorptive storage using MOF-5 and MOF-177," Applied Energy, Elsevier, vol. 210(C), pages 317-326.
    4. Qasem, Naef A.A. & Ben-Mansour, Rached, 2018. "Energy and productivity efficient vacuum pressure swing adsorption process to separate CO2 from CO2/N2 mixture using Mg-MOF-74: A CFD simulation," Applied Energy, Elsevier, vol. 209(C), pages 190-202.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xiang, Wenlong & Ren, Jie & Chen, Si & Shen, Chenyang & Chen, Yifei & Zhang, Minhua & Liu, Chang-jun, 2020. "The metal–organic framework UiO-66 with missing-linker defects: A highly active catalyst for carbon dioxide cycloaddition," Applied Energy, Elsevier, vol. 277(C).
    2. Jiang, L. & Gonzalez-Diaz, A. & Ling-Chin, J. & Roskilly, A.P. & Smallbone, A.J., 2019. "Post-combustion CO2 capture from a natural gas combined cycle power plant using activated carbon adsorption," Applied Energy, Elsevier, vol. 245(C), pages 1-15.
    3. Plaza, M.G. & Rubiera, F., 2019. "Evaluation of a novel multibed heat-integrated vacuum and temperature swing adsorption post-combustion CO2 capture process," Applied Energy, Elsevier, vol. 250(C), pages 916-925.
    4. Lu, Junhui & Cao, Haishan & Li, JunMing, 2020. "Energy and cost estimates for separating and capturing CO2 from CO2/H2O using condensation coupled with pressure/vacuum swing adsorption," Energy, Elsevier, vol. 202(C).
    5. Liu, Xuetao & Saren, Sagar & Chen, Haonan & Jeong, Ji Hwan & Li, Minxia & Dang, Chaobin & Miyazaki, Takahiko & Thu, Kyaw, 2024. "Open adsorption system for atmospheric CO2 capture: Scaling and sensitivity analysis," Energy, Elsevier, vol. 294(C).
    6. Li, Shuangjun & Deng, Shuai & Zhao, Li & Zhao, Ruikai & Lin, Meng & Du, Yanping & Lian, Yahui, 2018. "Mathematical modeling and numerical investigation of carbon capture by adsorption: Literature review and case study," Applied Energy, Elsevier, vol. 221(C), pages 437-449.
    7. Qasem, Naef A.A. & Ben-Mansour, Rached, 2018. "Adsorption breakthrough and cycling stability of carbon dioxide separation from CO2/N2/H2O mixture under ambient conditions using 13X and Mg-MOF-74," Applied Energy, Elsevier, vol. 230(C), pages 1093-1107.
    8. Zhang, Minkai & Guo, Yincheng, 2013. "Rate based modeling of absorption and regeneration for CO2 capture by aqueous ammonia solution," Applied Energy, Elsevier, vol. 111(C), pages 142-152.
    9. Ganapathy, Harish & Steinmayer, Sascha & Shooshtari, Amir & Dessiatoun, Serguei & Ohadi, Michael M. & Alshehhi, Mohamed, 2016. "Process intensification characteristics of a microreactor absorber for enhanced CO2 capture," Applied Energy, Elsevier, vol. 162(C), pages 416-427.
    10. Prabu, V., 2015. "Integration of in-situ CO2-oxy coal gasification with advanced power generating systems performing in a chemical looping approach of clean combustion," Applied Energy, Elsevier, vol. 140(C), pages 1-13.
    11. Zhang, Xiaowen & Zhang, Xin & Liu, Helei & Li, Wensheng & Xiao, Min & Gao, Hongxia & Liang, Zhiwu, 2017. "Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts," Applied Energy, Elsevier, vol. 202(C), pages 673-684.
    12. Chen, S.J. & Tao, Z.C. & Fu, Y. & Zhu, M. & Li, W.L. & Li, X.D., 2017. "CO2 separation from offshore natural gas in quiescent and flowing states using 13X zeolite," Applied Energy, Elsevier, vol. 205(C), pages 1435-1446.
    13. Choi, Munkyoung & Cho, Minki & Lee, J.W., 2016. "Empirical formula for the mass flux in chemical absorption of CO2 with ammonia droplets," Applied Energy, Elsevier, vol. 164(C), pages 1-9.
    14. Ganapathy, H. & Shooshtari, A. & Dessiatoun, S. & Alshehhi, M. & Ohadi, M., 2014. "Fluid flow and mass transfer characteristics of enhanced CO2 capture in a minichannel reactor," Applied Energy, Elsevier, vol. 119(C), pages 43-56.
    15. Umair Yaqub Qazi, 2022. "Future of Hydrogen as an Alternative Fuel for Next-Generation Industrial Applications; Challenges and Expected Opportunities," Energies, MDPI, vol. 15(13), pages 1-40, June.
    16. Wei, Ning & Li, Xiaochun & Wang, Yan & Zhu, Qianlin & Liu, Shengnan & Liu, Naizhong & Su, Xuebing, 2015. "Geochemical impact of aquifer storage for impure CO2 containing O2 and N2: Tongliao field experiment," Applied Energy, Elsevier, vol. 145(C), pages 198-210.
    17. Wang, Weilong & Li, Jiang & Wei, Xiaolan & Ding, Jing & Feng, Haijun & Yan, Jinyue & Yang, Jianping, 2015. "Carbon dioxide adsorption thermodynamics and mechanisms on MCM-41 supported polyethylenimine prepared by wet impregnation method," Applied Energy, Elsevier, vol. 142(C), pages 221-228.
    18. Alexander García-Mariaca & Eva Llera-Sastresa, 2021. "Review on Carbon Capture in ICE Driven Transport," Energies, MDPI, vol. 14(21), pages 1-30, October.
    19. Zhu, Xuancan & Shi, Yixiang & Cai, Ningsheng, 2016. "Integrated gasification combined cycle with carbon dioxide capture by elevated temperature pressure swing adsorption," Applied Energy, Elsevier, vol. 176(C), pages 196-208.
    20. Chen, S.J. & Zhu, M. & Fu, Y. & Huang, Y.X. & Tao, Z.C. & Li, W.L., 2017. "Using 13X, LiX, and LiPdAgX zeolites for CO2 capture from post-combustion flue gas," Applied Energy, Elsevier, vol. 191(C), pages 87-98.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:3:p:609-:d:486858. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.