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Experimental study and static numerical optimization of scalable design of non-adiabatic and non-isothermal pressure swing adsorption for biogas upgrading

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  • Abd, Ammar Ali
  • Kadhim Shabbani, Hind Jihad
  • Helwani, Zuchra
  • Othman, Mohd Roslee

Abstract

Biogas upgrading to fuel grid quality standards using plate PSA design mediated by raw biomass adsorbent under non-adiabatic and non-isothermal conditions was tested and optimized. The interaction effects of system pressure, CO2 concentration, and adsorption/desorption time on bioCH4 purity in the product line and CO2 purity in the waste line were investigated utilizing a central composite design. The response surface methodology and desirability function were applied to specify the optimum points of the factors to maximize the two responses namely bioCH4 and CO2 purity. The generated quadratic model with experimental error of less than 5% revealed that the factors influenced both responses remarkably. The optimum conditions for bioCH4 purity within 0.95–1 desirability scale were CO2 concentration below 50%, system pressure from 1.7 bar to 3 bar, and adsorption time below 5.9 min. For CO2 purity in the waste line, the optimum conditions were CO2 concentration above 65%, system pressure higher than 2.5 bar, and desorption time of 6 min. With these ranges of conditions, the proposed system achieved bioCH4 purity of ≥ 97% and CO2 purity of ≥ 90%.

Suggested Citation

  • Abd, Ammar Ali & Kadhim Shabbani, Hind Jihad & Helwani, Zuchra & Othman, Mohd Roslee, 2022. "Experimental study and static numerical optimization of scalable design of non-adiabatic and non-isothermal pressure swing adsorption for biogas upgrading," Energy, Elsevier, vol. 257(C).
    • Handle: RePEc:eee:energy:v:257:y:2022:i:c:s036054422201684x
    DOI: 10.1016/j.energy.2022.124781
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    References listed on IDEAS

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    1. Kim, Young Jun & Nam, Young Suk & Kang, Yong Tae, 2015. "Study on a numerical model and PSA (pressure swing adsorption) process experiment for CH4/CO2 separation from biogas," Energy, Elsevier, vol. 91(C), pages 732-741.
    2. Qasem, Naef A.A. & Ben-Mansour, Rached, 2018. "Energy and productivity efficient vacuum pressure swing adsorption process to separate CO2 from CO2/N2 mixture using Mg-MOF-74: A CFD simulation," Applied Energy, Elsevier, vol. 209(C), pages 190-202.
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    1. Abd, Ammar Ali & Othman, Mohd Roslee & Majdi, Hasan Sh & Helwani, Zuchra, 2023. "Green route for biomethane and hydrogen production via integration of biogas upgrading using pressure swing adsorption and steam-methane reforming process," Renewable Energy, Elsevier, vol. 210(C), pages 64-78.
    2. Rumbo-Morales, Jesse Y. & Ortiz-Torres, Gerardo & Sarmiento-Bustos, Estela & Rosales, Antonio Márquez & Calixto-Rodriguez, Manuela & Sorcia-Vázquez, Felipe D.J. & Pérez-Vidal, Alan F. & Rodríguez-Cerd, 2024. "Purification and production of bio-ethanol through the control of a pressure swing adsorption plant," Energy, Elsevier, vol. 288(C).
    3. Abd, Ammar Ali & Othman, Mohd Roslee & Helwani, Zuchra & Kim, Jinsoo, 2023. "Waste to wheels: Performance comparison between pressure swing adsorption and amine-absorption technologies for upgrading biogas containing hydrogen sulfide to fuel grade standards," Energy, Elsevier, vol. 272(C).

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