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Production of Acrylic Acid from Biomass-Derived Fumaric Acid under Hydrothermal Conditions

Author

Listed:
  • Guodong Yin

    (State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092, China
    These authors contributed equally to this work.)

  • Heng Zhong

    (School of Environmental Science and Engineering, State Key Lab of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China
    Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
    These authors contributed equally to this work.)

  • Guodong Yao

    (State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092, China)

  • Fangming Jin

    (School of Environmental Science and Engineering, State Key Lab of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China
    Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China)

  • Jianfu Zhao

    (State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092, China)

Abstract

Production of energy and chemicals from biomass resources has been regarded as one promising method to address the challenge of global warming. In this research, production of acrylic acid from fumaric acid, one of the biomass-derived building blocks, is proposed. CuO was employed as a solid oxidant, which showed excellent activity and selectivity for the production of acrylic acid, and water played an essential role in acting as not only a solvent but also a catalyst in this process. An optimum acrylic acid yield of 76.4% was successfully obtained after the reaction of fumaric acid with CuO at 300 °C for only 60 s.This research provides a green and highly efficient way to produce value-added chemicals from biomass-derived building blocks, and thus is promising for practical application.

Suggested Citation

  • Guodong Yin & Heng Zhong & Guodong Yao & Fangming Jin & Jianfu Zhao, 2021. "Production of Acrylic Acid from Biomass-Derived Fumaric Acid under Hydrothermal Conditions," Energies, MDPI, vol. 14(17), pages 1-9, September.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:17:p:5456-:d:627418
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    References listed on IDEAS

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    1. Gollakota, A.R.K. & Kishore, Nanda & Gu, Sai, 2018. "A review on hydrothermal liquefaction of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1378-1392.
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    3. Massimo Melchiorre & Roberto Esposito & Martino Di Serio & Giancarlo Abbate & Alessandro Lampasi & Andrea Balducci & Francesco Ruffo, 2021. "Lactic Acid-Based Solvents for Sustainable EDLC Electrolytes," Energies, MDPI, vol. 14(14), pages 1-17, July.
    4. Shen, Zheng & Zhou, Jingfei & Zhou, Xuefei & Zhang, Yalei, 2011. "The production of acetic acid from microalgae under hydrothermal conditions," Applied Energy, Elsevier, vol. 88(10), pages 3444-3447.
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    Cited by:

    1. Katarzyna Sroka & Paweł Sroka, 2024. "Superabsorbent Hydrogels in the Agriculture and Reclamation of Degraded Areas," Sustainability, MDPI, vol. 16(7), pages 1-27, April.

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