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A non-stoichiometric equilibrium model for the simulation of the biomass gasification process

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  • Gambarotta, Agostino
  • Morini, Mirko
  • Zubani, Andrea

Abstract

This paper presents a non-stoichiometric equilibrium model for the simulation of the biomass gasification process in downdraft gasifiers to be used within simulation models of complex energy systems. The chemical equilibrium is determined by minimizing the Gibbs free energy. The feedstock is composed of five elements, while fifteen chemical species are considered for the syngas. The model calculates the relative quantities of gasification products and the lower heating value of the syngas. An advantage of the non-stoichiometric approach is that it can easily calculate not only the concentrations of the main gasification products, but also the concentrations of minor products, especially the pollutant chemical species containing nitrogen and sulfur.

Suggested Citation

  • Gambarotta, Agostino & Morini, Mirko & Zubani, Andrea, 2018. "A non-stoichiometric equilibrium model for the simulation of the biomass gasification process," Applied Energy, Elsevier, vol. 227(C), pages 119-127.
    • Handle: RePEc:eee:appene:v:227:y:2018:i:c:p:119-127
    DOI: 10.1016/j.apenergy.2017.07.135
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