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N Evolution and Physiochemical Structure Changes in Chars during Co-Pyrolysis: Effects of Abundance of Glucose in Fiberboard

Author

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  • Deliang Xu

    (Joint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China)

  • Liu Yang

    (Joint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China)

  • Ming Zhao

    (Joint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China)

  • Yu Song

    (Joint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China)

  • Karnowo

    (Joint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
    Faculty of Engineering, Universitas Negeri Semarang (UNNES), Jawa Tengah 50229, Indonesia)

  • Hong Zhang

    (Joint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China)

  • Xun Hu

    (School of Material Science and Engineering, University of Jinan, Jinan 250022, China)

  • Hongqi Sun

    (School of Engineering, Edith Cowan University, 270 Joondalup Drive, Joondalup, WA 6027, Australia)

  • Shu Zhang

    (Joint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China)

Abstract

The simple incineration of wood-based panels (WBPs) waste generates a significant amount of NO x , which has led to urgency in developing a new method for treating the N-containing biomass residues. This work aims to examine the N evolution and physiochemical structural changes during the co-pyrolysis of fiberboard and glucose, where the percentage of glucose in the feedstock was varied from 0% to 70%. It was found that N retention in chars was monotonically increased with increasing use of glucose, achieving ~60% N fixation when the glucose accounted for 70% in the mixture. Pyrrole-N (N-5) and Pyridine-N (N-6) were preferentially formed at high ratios of glucose to fiberboard. While the relevant importance of volatile–char interactions to N retention and transformation could be observed, the volatile–volatile reactions from the two feedstocks played a vital role in the increase in abundance of glucose. With the introduction of glucose, the porous structure and porosity in chars from the co-pyrolysis were dramatically altered, whereas the devolatilization of glucose tended to generate larger pores than the fiberboard. The insignificant changes in carbon structure of all chars revealed by Raman spectroscopy would practically allow us to apply the monosaccharides to the WBPs for regulating N evolution without concerns about its side effects for char carbon structures.

Suggested Citation

  • Deliang Xu & Liu Yang & Ming Zhao & Yu Song & Karnowo & Hong Zhang & Xun Hu & Hongqi Sun & Shu Zhang, 2020. "N Evolution and Physiochemical Structure Changes in Chars during Co-Pyrolysis: Effects of Abundance of Glucose in Fiberboard," Energies, MDPI, vol. 13(19), pages 1-13, October.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:19:p:5105-:d:422339
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    References listed on IDEAS

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    1. Chen, Wei & Fang, Yang & Li, Kaixu & Chen, Zhiqun & Xia, Mingwei & Gong, Meng & Chen, Yingquan & Yang, Haiping & Tu, Xin & Chen, Hanping, 2020. "Bamboo wastes catalytic pyrolysis with N-doped biochar catalyst for phenols products," Applied Energy, Elsevier, vol. 260(C).
    2. Xiaorui Liu & Zhongyang Luo & Chunjiang Yu & Bitao Jin & Hanchao Tu, 2018. "Release Mechanism of Fuel-N into NO x and N 2 O Precursors during Pyrolysis of Rice Straw," Energies, MDPI, vol. 11(3), pages 1-13, February.
    3. Zheng, Anqing & Li, Luwei & Tippayawong, Nakorn & Huang, Zhen & Zhao, Kun & Wei, Guoqiang & Zhao, Zengli & Li, Haibin, 2020. "Reducing emission of NOx and SOx precursors while enhancing char production from pyrolysis of sewage sludge by torrefaction pretreatment," Energy, Elsevier, vol. 192(C).
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    Cited by:

    1. Yang, Liu & Guo, Mengyao & Qian, Yiwen & Xu, Deliang & Gholizadeh, Mortaza & Karnowo, & Zhang, Hong & Hu, Xun & Zhang, Shu, 2022. "The effects of interactions between fiberboard-derived volatiles and glucose-derived biochar on N retention and char structure during the decoupled pyrolysis of fiberboard and glucose using a double-b," Renewable Energy, Elsevier, vol. 191(C), pages 134-140.
    2. Mengyao Guo & Shu Yu & Shu Zhang & Juntao Wei & Wenran Gao & Weina Bao & Lei Shi & Hong Zhang & Deliang Xu, 2022. "Nitrogen Migration and Conversion in Chars from Co-Pyrolysis of Lignocellulose Derived Pyrolysis Model Compounds and Urea-Formaldehyde Resin Adhesive," Energies, MDPI, vol. 15(19), pages 1-11, October.

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