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Hydrofluoroolefin-based novel mixed refrigerant for energy efficient and ecological LNG production

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  • Qyyum, Muhammad Abdul
  • Lee, Moonyong

Abstract

To satisfy the worldwide demand for energy, the liquefied natural gas (LNG) industry has grown significantly in the past three decades owing to its low CO2 emissions and high thermal efficiency compared to the other available energy resources. However, the process of natural gas liquefaction is generally considered to be energy-intensive. In this context, a novel hydrofluoroolefin (HFO-1234yf)-based mixed refrigerant, with the advantages of zero ozone depletion and minimal global warming potential, is proposed to liquefy natural gas in an ecological and energy-efficient manner. A new liquefaction cycle using the HFO-based mixed refrigerant is developed to fully utilize its potential. The results reveal that the overall energy requirement for natural gas liquefaction can be reduced by 46.4% compared with a single mixed refrigerant process, 42.5% compared with a dual mixed refrigerant process, and 36.3% compared with the Linde–single mixed refrigerant process. Economic analysis based on the capacity parameters of each equipment is also performed to emphasize the commercial feasibility of the proposed LNG process. The proposed HFO-based mixed refrigerant system provides an innovative solution to improve the ecological aspects and energy efficiency of natural gas liquefaction processes.

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  • Qyyum, Muhammad Abdul & Lee, Moonyong, 2018. "Hydrofluoroolefin-based novel mixed refrigerant for energy efficient and ecological LNG production," Energy, Elsevier, vol. 157(C), pages 483-492.
    • Handle: RePEc:eee:energy:v:157:y:2018:i:c:p:483-492
    DOI: 10.1016/j.energy.2018.05.173
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    References listed on IDEAS

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    1. Khan, Mohd Shariq & I.A. Karimi, & Bahadori, Alireza & Lee, Moonyong, 2015. "Sequential coordinate random search for optimal operation of LNG (liquefied natural gas) plant," Energy, Elsevier, vol. 89(C), pages 757-767.
    2. Ghorbani, Bahram & Hamedi, Mohammad-Hossein & Amidpour, Majid & Mehrpooya, Mehdi, 2016. "Cascade refrigeration systems in integrated cryogenic natural gas process (natural gas liquids (NGL), liquefied natural gas (LNG) and nitrogen rejection unit (NRU))," Energy, Elsevier, vol. 115(P1), pages 88-106.
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    4. Khan, Mohd Shariq & Lee, Moonyong, 2013. "Design optimization of single mixed refrigerant natural gas liquefaction process using the particle swarm paradigm with nonlinear constraints," Energy, Elsevier, vol. 49(C), pages 146-155.
    5. Qyyum, Muhammad Abdul & Ali, Wahid & Long, Nguyen Van Duc & Khan, Mohd Shariq & Lee, Moonyong, 2018. "Energy efficiency enhancement of a single mixed refrigerant LNG process using a novel hydraulic turbine," Energy, Elsevier, vol. 144(C), pages 968-976.
    6. Khan, Mohd Shariq & Lee, Sanggyu & Rangaiah, G.P. & Lee, Moonyong, 2013. "Knowledge based decision making method for the selection of mixed refrigerant systems for energy efficient LNG processes," Applied Energy, Elsevier, vol. 111(C), pages 1018-1031.
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    Cited by:

    1. Ali Rehman & Muhammad Abdul Qyyum & Ashfaq Ahmad & Saad Nawaz & Moonyong Lee & Li Wang, 2020. "Performance Enhancement of Nitrogen Dual Expander and Single Mixed Refrigerant LNG Processes Using Jaya Optimization Approach," Energies, MDPI, vol. 13(12), pages 1-27, June.
    2. Noushabadi, Abolfazl Sajadi & Lay, Ebrahim Nemati & Dashti, Amir & Mohammadi, Amir H. & Chofreh, Abdoulmohammad Gholamzadeh & Goni, Feybi Ariani & Klemeš, Jiří Jaromír, 2023. "Insights into modelling and evaluation of thermodynamic and transport properties of refrigerants using machine-learning methods," Energy, Elsevier, vol. 262(PA).
    3. Park, Jinwoo & You, Fengqi & Cho, Hyungtae & Lee, Inkyu & Moon, Il, 2020. "Novel massive thermal energy storage system for liquefied natural gas cold energy recovery," Energy, Elsevier, vol. 195(C).
    4. Khaliq Majeed & Muhammad Abdul Qyyum & Alam Nawaz & Ashfaq Ahmad & Muhammad Naqvi & Tianbiao He & Moonyong Lee, 2020. "Shuffled Complex Evolution-Based Performance Enhancement and Analysis of Cascade Liquefaction Process for Large-Scale LNG Production," Energies, MDPI, vol. 13(10), pages 1-20, May.
    5. Rehman, Ali & Qyyum, Muhammad Abdul & Qadeer, Kinza & Zakir, Fatima & Ding, Yulong & Lee, Moonyong & Wang, Li, 2020. "Integrated biomethane liquefaction using exergy from the discharging end of a liquid air energy storage system," Applied Energy, Elsevier, vol. 260(C).
    6. Qyyum, Muhammad Abdul & He, Tianbiao & Qadeer, Kinza & Mao, Ning & Lee, Sanggyu & Lee, Moonyong, 2020. "Dual-effect single-mixed refrigeration cycle: An innovative alternative process for energy-efficient and cost-effective natural gas liquefaction," Applied Energy, Elsevier, vol. 268(C).
    7. Lei Gao & Jiaxin Wang & Maxime Binama & Qian Li & Weihua Cai, 2022. "The Design and Optimization of Natural Gas Liquefaction Processes: A Review," Energies, MDPI, vol. 15(21), pages 1-56, October.
    8. Qyyum, Muhammad Abdul & Qadeer, Kinza & Minh, Le Quang & Haider, Junaid & Lee, Moonyong, 2019. "Nitrogen self-recuperation expansion-based process for offshore coproduction of liquefied natural gas, liquefied petroleum gas, and pentane plus," Applied Energy, Elsevier, vol. 235(C), pages 247-257.
    9. Yu, Taejong & Kim, Donghoi & Gundersen, Truls & Lim, Youngsub, 2023. "A feasibility study of HFO refrigerants for onboard BOG liquefaction processes," Energy, Elsevier, vol. 282(C).

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