Simulative Investigation of Thermal Capacity Analysis Methods for Metallic Latent Thermal Energy Storage Systems

Latent heat storage systems are a promising technology for storing and providing thermal energy with low volume, mass and cost requirements, especially when operated at high temperatures. Metallic phase change materials are particularly advantageous for high thermal input and output, which is especially important for mobile applications. When designing a storage system, it is essential to have precise knowledge about the potential storage capacity. However, the system’s storage capacity is typically calculated from material properties determined at lab scale, although systemic boundary conditions can have a considerable influence. Systemic influences can result from thermal and reactive interfaces or from the storage design. In order to consider these influences, we propose three calorimetric procedures to thermally analyse high-temperature metallic latent energy storage systems at an application scale. We examined the procedures in a transient simulation environment, monitoring the storage capacity of the system. The procedure, based on adiabatic conditions, shows the least deviation from the simulation input parameters, but is limited to the heating process of the storage. Discharging the storage can be represented by isoperibolic conditions with controlled heat exchange. The precision of the procedures depends on the evaluation routine, the calibration routine, the heat extraction rate and the thermal inertia of the test bench.