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Pure and Hydrocarbon Binary Mixtures as Possible Alternatives Working Fluids to the Usual Organic Rankine Cycles Biomass Conversion Systems

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  • Costante M. Invernizzi

    (Department of Mechanical and Industrial Engineering, University of Brescia, 25123 Brescia, Italy
    Current address: Department of Mechanical and Industrial Engineering, University of Brescia, via Branze, 38, 25123 Brescia, Italy.)

  • Abubakr Ayub

    (Department of Mechanical and Industrial Engineering, University of Brescia, 25123 Brescia, Italy
    Current address: Department of Mechanical and Industrial Engineering, University of Brescia, via Branze, 38, 25123 Brescia, Italy.)

  • Gioele Di Marcoberardino

    (Department of Mechanical and Industrial Engineering, University of Brescia, 25123 Brescia, Italy
    Current address: Department of Mechanical and Industrial Engineering, University of Brescia, via Branze, 38, 25123 Brescia, Italy.)

  • Paolo Iora

    (Department of Mechanical and Industrial Engineering, University of Brescia, 25123 Brescia, Italy
    Current address: Department of Mechanical and Industrial Engineering, University of Brescia, via Branze, 38, 25123 Brescia, Italy.)

Abstract

This study investigates the use of pure and hydrocarbons binary mixtures as potential alternatives working fluids in a usual biomass powered organic Rankine cycle (ORC). A typical biomass combined heat and power plant installed in Cremona (Italy) is considered as the benchmark. Eight pure hydrocarbons (linear and cyclic) and four binary mixtures of linear hydrocarbons were selected. The critical points of the binary mixtures at different composition were calculated using an in-house code developed in MATLAB © (R2018b) environment. Based on the critical point of a working fluid, supercritical and subcritical cycle configurations of ORC were analysed. A detailed thermodynamic comparison with benchmark cycle was carried out in view of cycle efficiency, maximum operating pressure, size of the turbine and heat exchangers. The supercritical cycles showed 0.02 to 0.03 points lower efficiency, whereas, subcritical cycles showed comparable efficiencies than that of the benchmark cycle. The cycles operating with hydrocarbons (pure and mixtures) exhibited considerably lower volume flow ratios in turbine which indicates lower turbine size. Also, size parameter of regenerator is comparatively lower due to the lower molecular complexity of the hydrocarbons. A noticeable increase in turbine power output was observed with change in composition of the iso-octane/n-octane binary mixture at the same thermodynamic efficiency.

Suggested Citation

  • Costante M. Invernizzi & Abubakr Ayub & Gioele Di Marcoberardino & Paolo Iora, 2019. "Pure and Hydrocarbon Binary Mixtures as Possible Alternatives Working Fluids to the Usual Organic Rankine Cycles Biomass Conversion Systems," Energies, MDPI, vol. 12(21), pages 1-17, October.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:21:p:4140-:d:281733
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    References listed on IDEAS

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    2. Savvas L. Douvartzides & Aristidis Tsiolikas & Nikolaos D. Charisiou & Manolis Souliotis & Vayos Karayannis & Nikolaos Taousanidis, 2022. "Energy and Exergy-Based Screening of Various Refrigerants, Hydrocarbons and Siloxanes for the Optimization of Biomass Boiler–Organic Rankine Cycle (BB–ORC) Heat and Power Cogeneration Plants," Energies, MDPI, vol. 15(15), pages 1-26, July.
    3. Piotr Kolasiński, 2020. "Domestic Organic Rankine Cycle-Based Cogeneration Systems as a Way to Reduce Dust Emissions in Municipal Heating," Energies, MDPI, vol. 13(15), pages 1-22, August.
    4. Liangchuan Wei & Bing Guo & Nanyi Li & Zhonghao Heng, 2023. "Design and Internal Flow Characteristic Investigation of High-Temperature H 2 /Steam-Mixed Working Fluid Turbine," Energies, MDPI, vol. 16(13), pages 1-19, June.
    5. Piotr Kolasiński, 2020. "The Method of the Working Fluid Selection for Organic Rankine Cycle (ORC) Systems Employing Volumetric Expanders," Energies, MDPI, vol. 13(3), pages 1-28, January.
    6. Muhammad Haroon & Nadeem Ahmed Sheikh & Abubakr Ayub & Rasikh Tariq & Farooq Sher & Aklilu Tesfamichael Baheta & Muhammad Imran, 2020. "Exergetic, Economic and Exergo-Environmental Analysis of Bottoming Power Cycles Operating with CO 2 -Based Binary Mixture," Energies, MDPI, vol. 13(19), pages 1-19, September.
    7. Abubakr Ayub & Costante M. Invernizzi & Gioele Di Marcoberardino & Paolo Iora & Giampaolo Manzolini, 2020. "Carbon Dioxide Mixtures as Working Fluid for High-Temperature Heat Recovery: A Thermodynamic Comparison with Transcritical Organic Rankine Cycles," Energies, MDPI, vol. 13(15), pages 1-18, August.
    8. Shi, Shaofei & Wang, Yufei & Wang, Youlei & Feng, Xiao, 2022. "A new optimization method for cooling systems considering low-temperature waste heat utilization in a polysilicon industry," Energy, Elsevier, vol. 238(PA).
    9. Świerzewski, Mateusz & Kalina, Jacek & Musiał, Arkadiusz, 2021. "Techno-economic optimization of ORC system structure, size and working fluid within biomass-fired municipal cogeneration plant retrofitting project," Renewable Energy, Elsevier, vol. 180(C), pages 281-296.
    10. Dominika Matuszewska & Piotr Olczak, 2020. "Evaluation of Using Gas Turbine to Increase Efficiency of the Organic Rankine Cycle (ORC)," Energies, MDPI, vol. 13(6), pages 1-21, March.

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