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Solar-Driven Thermochemical Water-Splitting by Cerium Oxide: Determination of Operational Conditions in a Directly Irradiated Fixed Bed Reactor

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  • Lucía Arribas

    (Unit of High Temperature Processes, IMDEA Energy Institute, Avda. Ramón de la Sagra 3, 28935 Móstoles, Spain
    Department of Chemical and Energy Technology, ESCET, Universidad Rey Juan Carlos, c/Tulipán s/n, 28933 Móstoles, Madrid, Spain)

  • José González-Aguilar

    (Unit of High Temperature Processes, IMDEA Energy Institute, Avda. Ramón de la Sagra 3, 28935 Móstoles, Spain)

  • Manuel Romero

    (Unit of High Temperature Processes, IMDEA Energy Institute, Avda. Ramón de la Sagra 3, 28935 Móstoles, Spain)

Abstract

Concentrated solar energy can be transformed into electricity, heat or even solar fuels, such as hydrogen, via thermochemical routes with high exergetic efficiency. In this work, a specific methodology and experimental setup are described, developed to assess the production of hydrogen by water splitting making use of commercial cerium oxide, ceria (CeO 2 ), in a solarized reactor. A fixed bed reactor, directly irradiated by a 7 kWe high flux solar simulator (HFSS) was used. Released H 2 and sample temperature levels were continuously monitored. Three tests were carried out consisting of three consecutive redox cycles each, with irradiances in the range of 1017–2034 kWm −2 . It was necessary to achieve a compromise between sample temperatures (higher temperatures lead to higher reduction rates) and sample stability, since absorbed radiation can degrade a sample at lower temperature (1280–1480 °C) than in a conventional infrared oven ( T > 2000 °C). Irradiating the surface of the sample with an irradiance of 2034 kWm −2 (270 W of total radiation power) during 9.5 min eventually degraded the sample, resulting in a conversion into stoichiometrically reduced oxide (Ce 2 O 3 ) of 11%. A similar conversion was achieved (9.7%) after 2 min of irradiation at 270 W (100% of radiation), but without irreversibly damaging the sample.

Suggested Citation

  • Lucía Arribas & José González-Aguilar & Manuel Romero, 2018. "Solar-Driven Thermochemical Water-Splitting by Cerium Oxide: Determination of Operational Conditions in a Directly Irradiated Fixed Bed Reactor," Energies, MDPI, vol. 11(9), pages 1-15, September.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:9:p:2451-:d:170019
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    References listed on IDEAS

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    Cited by:

    1. Rahul R. Bhosale, 2023. "Recent Developments in Ceria-Driven Solar Thermochemical Water and Carbon Dioxide Splitting Redox Cycle," Energies, MDPI, vol. 16(16), pages 1-30, August.
    2. Mao, Yanpeng & Gao, Yibo & Dong, Wei & Wu, Han & Song, Zhanlong & Zhao, Xiqiang & Sun, Jing & Wang, Wenlong, 2020. "Hydrogen production via a two-step water splitting thermochemical cycle based on metal oxide – A review," Applied Energy, Elsevier, vol. 267(C).
    3. Gao, Yibo & Mao, Yanpeng & Song, Zhanlong & Zhao, Xiqiang & Sun, Jing & Wang, Wenlong & Chen, Guifang & Chen, Shouyan, 2020. "Efficient generation of hydrogen by two-step thermochemical cycles: Successive thermal reduction and water splitting reactions using equal-power microwave irradiation and a high entropy material," Applied Energy, Elsevier, vol. 279(C).
    4. Daphne Oudejans & Michele Offidani & Achilleas Constantinou & Stefania Albonetti & Nikolaos Dimitratos & Atul Bansode, 2022. "A Comprehensive Review on Two-Step Thermochemical Water Splitting for Hydrogen Production in a Redox Cycle," Energies, MDPI, vol. 15(9), pages 1-24, April.

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