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Fundamental Material Properties of the 2LiBH 4 -MgH 2 Reactive Hydride Composite for Hydrogen Storage: (II) Kinetic Properties

Author

Listed:
  • Julian Jepsen

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany)

  • Chiara Milanese

    (Pavia H2 Lab, Department of Chemistry, Physical Chemistry Division, University of Pavia, Viale Taramelli 16, 27100 Pavia, Italy)

  • Julián Puszkiel

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany
    Department of Physicochemistry of Materials, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Centro Atómico Bariloche, Av. Bustillo km 9500, R8402AGP S.C. de Bariloche, Argentina)

  • Alessandro Girella

    (Pavia H2 Lab, Department of Chemistry, Physical Chemistry Division, University of Pavia, Viale Taramelli 16, 27100 Pavia, Italy)

  • Benedetto Schiavo

    (Dipartimento dell’Innovazione Industriale e Digitale (DIID)-Ingegneria Chimica Gestionale Informatica Meccanica, Università degli Studi di Palermo, viale delle Scienze, Ed. 6, 90128 Palermo, Italy, and Istituto per le Tecnologie Avanzate (ITA), SS 113 174, 91100 Trapani, Italy)

  • Gustavo A. Lozano

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany
    Current Address: BASF SE, Carl Bosch Str 38, 67056 Ludwigshafen, Germany.)

  • Giovanni Capurso

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany)

  • José M. Bellosta von Colbe

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany)

  • Amedeo Marini

    (Department of Physicochemistry of Materials, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Centro Atómico Bariloche, Av. Bustillo km 9500, R8402AGP S.C. de Bariloche, Argentina)

  • Stephan Kabelac

    (Institute for Thermodynamics, Leibniz Universität Hannover, Callinstraße 36, 30167 Hannover, Germany)

  • Martin Dornheim

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany)

  • Thomas Klassen

    (Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany)

Abstract

Reaction kinetic behaviour and cycling stability of the 2LiBH 4 –MgH 2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks. In addition to the determination and discussion about the properties; different measurement methods are applied and compared. The activation energies for both hydrogenation and dehydrogenation are determined by the Kissinger method and via the fitting of solid-state reaction kinetic models to isothermal volumetric measurements. Furthermore, the hydrogen absorption–desorption cycling stability is assessed by titration measurements. Finally, the kinetic behaviour and the reversible hydrogen storage capacity of the Li-RHC are discussed.

Suggested Citation

  • Julian Jepsen & Chiara Milanese & Julián Puszkiel & Alessandro Girella & Benedetto Schiavo & Gustavo A. Lozano & Giovanni Capurso & José M. Bellosta von Colbe & Amedeo Marini & Stephan Kabelac & Marti, 2018. "Fundamental Material Properties of the 2LiBH 4 -MgH 2 Reactive Hydride Composite for Hydrogen Storage: (II) Kinetic Properties," Energies, MDPI, vol. 11(5), pages 1-15, May.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:5:p:1170-:d:144991
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    References listed on IDEAS

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    1. Julian Jepsen & Chiara Milanese & Julián Puszkiel & Alessandro Girella & Benedetto Schiavo & Gustavo A. Lozano & Giovanni Capurso & José M. Bellosta von Colbe & Amedeo Marini & Stephan Kabelac & Marti, 2018. "Fundamental Material Properties of the 2LiBH 4 -MgH 2 Reactive Hydride Composite for Hydrogen Storage: (I) Thermodynamic and Heat Transfer Properties," Energies, MDPI, vol. 11(5), pages 1-23, April.
    2. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
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    Cited by:

    1. Gabriele Scarpati & Julián A. Puszkiel & Jan Warfsmann & Fahim Karimi & Elio Jannelli & Claudio Pistidda & Thomas Klassen & Julian Jepsen, 2025. "Comprehensive Overview of the Effective Thermal Conductivity for Hydride Materials: Experimental and Modeling Approaches," Energies, MDPI, vol. 18(1), pages 1-56, January.
    2. Vamsi Krishna Kukkapalli & Sunwoo Kim & Seth A. Thomas, 2023. "Thermal Management Techniques in Metal Hydrides for Hydrogen Storage Applications: A Review," Energies, MDPI, vol. 16(8), pages 1-27, April.
    3. Artem Chesalkin & Petr Kacor & Petr Moldrik, 2021. "Heat Transfer Optimization of NEXA Ballard Low-Temperature PEMFC," Energies, MDPI, vol. 14(8), pages 1-17, April.
    4. Hai Li & Xueteng Gao & Chongzhi Jia & Wan Chen & Bei Liu & Lanying Yang & Changyu Sun & Guangjin Chen, 2018. "Enrichment of Hydrogen from a Hydrogen/Propylene Gas Mixture Using ZIF-8/Water-Glycol Slurry," Energies, MDPI, vol. 11(7), pages 1-13, July.
    5. Julián Puszkiel & José M. Bellosta von Colbe & Julian Jepsen & Sergey V. Mitrokhin & Elshad Movlaev & Victor Verbetsky & Thomas Klassen, 2020. "Designing an AB 2 -Type Alloy (TiZr-CrMnMo) for the Hybrid Hydrogen Storage Concept," Energies, MDPI, vol. 13(11), pages 1-26, June.

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