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Calorimetric Evaluation of Thermal Stability of Organic Liquid Hydrogen Storage Materials and Metal Oxide Additives

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  • Lin-Jie Xie

    (School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China)

  • Jun-Cheng Jiang

    (School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China)

  • An-Chi Huang

    (School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China)

  • Yan Tang

    (School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China)

  • Ye-Cheng Liu

    (School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China)

  • Hai-Lin Zhou

    (School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China)

  • Zhi-Xiang Xing

    (School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China)

Abstract

The effects of two different metal oxide catalysts, SnO and Li 2 O, on the dehydrogenation temperature of Carbazole and N-Ethylcarbazole (NE), respectively, were investigated by the Thermogravimetric analyzer and Differential Scanning Calorimetry. Thermogravimetric experiments were performed with 10wt% SnO and Li 2 O added to Carbazole and N-Ethylcarbazole, respectively, and compared to pure Carbazole and N-Ethylcarbazole. The results showed that the dehydrogenation temperature of N-Ethylcarbazole was lower than that of Carbazole, and the dehydrogenation temperature of N-Ethylcarbazole +SnO was the lowest, and SnO is an ideal dehydrogenation catalyst for N-Ethylcarbazole. Experiments using Differential Scanning Calorimetry and a Thermogravimetric analyzer showed that with the addition of catalyst, the activation energy of the mixture was more significant and stable, and the thermal hazard was reduced, whereas the relative dehydrogenation temperature was increased. This study provides important information for improving the design of dehydrogenation catalysts for organic liquid hydrogen storage processes.

Suggested Citation

  • Lin-Jie Xie & Jun-Cheng Jiang & An-Chi Huang & Yan Tang & Ye-Cheng Liu & Hai-Lin Zhou & Zhi-Xiang Xing, 2022. "Calorimetric Evaluation of Thermal Stability of Organic Liquid Hydrogen Storage Materials and Metal Oxide Additives," Energies, MDPI, vol. 15(6), pages 1-13, March.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:6:p:2236-:d:774566
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    References listed on IDEAS

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    1. A. C. Dillon & K. M. Jones & T. A. Bekkedahl & C. H. Kiang & D. S. Bethune & M. J. Heben, 1997. "Storage of hydrogen in single-walled carbon nanotubes," Nature, Nature, vol. 386(6623), pages 377-379, March.
    2. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
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    1. Yi Zhang & Dapeng Zhang & Haoyu Jiang, 2023. "A Review of Artificial Intelligence-Based Optimization Applications in Traditional Active Maritime Collision Avoidance," Sustainability, MDPI, vol. 15(18), pages 1-20, September.

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