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Estimation of Effective Diffusion Coefficient of O 2 in Ash Layer in Underground Coal Gasification by Thermogravimetric Apparatus

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  • Xi Lin

    (Beijing Advanced Innovation Center for Soft Matter Science and Engineering, and State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

  • Qingya Liu

    (Beijing Advanced Innovation Center for Soft Matter Science and Engineering, and State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

  • Zhenyu Liu

    (Beijing Advanced Innovation Center for Soft Matter Science and Engineering, and State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

Abstract

Underground coal gasification (UCG) proceeds generally in the presence of an ash layer on coal (or char) surface. The ash layer increases the mass transfer resistance of O 2 to the gasification surface, which may become the limiting step of whole process. This paper studies O 2 diffusion in ash layer formed on cylindrical char samples using a specially designed one-dimension setup in a thermogravimetric apparatus (TGA). The effective internal diffusion coefficient ( D e ) is found to increase with an increase in ash layer thickness, due to an increase in median pore diameter. Methods are established to correlate D e with operating conditions and to estimate the role of internal diffusion resistance in overall mass transfer resistance.

Suggested Citation

  • Xi Lin & Qingya Liu & Zhenyu Liu, 2018. "Estimation of Effective Diffusion Coefficient of O 2 in Ash Layer in Underground Coal Gasification by Thermogravimetric Apparatus," Energies, MDPI, vol. 11(2), pages 1-14, February.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:2:p:460-:d:132777
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    References listed on IDEAS

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    Cited by:

    1. Fa-qiang Su & Akihiro Hamanaka & Ken-ichi Itakura & Gota Deguchi & Wenyan Zhang & Hua Nan, 2018. "Evaluation of a Compact Coaxial Underground Coal Gasification System Inside an Artificial Coal Seam," Energies, MDPI, vol. 11(4), pages 1-11, April.
    2. Mejdi Jeguirim & Lionel Limousy, 2019. "Biomass Chars: Elaboration, Characterization and Applications II," Energies, MDPI, vol. 12(3), pages 1-6, January.
    3. Li, Xin & Tian, Jijun & Ju, Yiwen & Chen, Yanpeng, 2022. "Permeability variations of lignite and bituminous coals under elevated pyrolysis temperatures (35–600 °C): An experimental study," Energy, Elsevier, vol. 254(PA).

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