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Hydration of Magnesium Carbonate in a Thermal Energy Storage Process and Its Heating Application Design

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  • Rickard Erlund

    (Thermal and Flow Engineering Laboratory, Åbo Akademi University, 20900 Turku, Finland)

  • Ron Zevenhoven

    (Thermal and Flow Engineering Laboratory, Åbo Akademi University, 20900 Turku, Finland)

Abstract

First ideas of applications design using magnesium (hydro) carbonates mixed with silica gel for day/night and seasonal thermal energy storage are presented. The application implies using solar (or another) heat source for heating up the thermal energy storage (dehydration) unit during daytime or summertime, of which energy can be discharged (hydration) during night-time or winter. The applications can be used in small houses or bigger buildings. Experimental data are presented, determining and analysing kinetics and operating temperatures for the applications. In this paper the focus is on the hydration part of the process, which is the more challenging part, considering conversion and kinetics. Various operating temperatures for both the reactor and the water (storage) tank are tested and the favourable temperatures are presented and discussed. Applications both using ground heat for water vapour generation and using water vapour from indoor air are presented. The thermal energy storage system with mixed nesquehonite (NQ) and silica gel (SG) can use both low (25–50%) and high (75%) relative humidity (RH) air for hydration. The hydration at 40% RH gives a thermal storage capacity of 0.32 MJ/kg while 75% RH gives a capacity of 0.68 MJ/kg.

Suggested Citation

  • Rickard Erlund & Ron Zevenhoven, 2018. "Hydration of Magnesium Carbonate in a Thermal Energy Storage Process and Its Heating Application Design," Energies, MDPI, vol. 11(1), pages 1-16, January.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:1:p:170-:d:126367
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    References listed on IDEAS

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    Cited by:

    1. Seyed Ali Ghoreishi-Madiseh & Ali Fahrettin Kuyuk & Marco Antonio Rodrigues de Brito & Durjoy Baidya & Zahra Torabigoodarzi & Amir Safari, 2019. "Application of Borehole Thermal Energy Storage in Waste Heat Recovery from Diesel Generators in Remote Cold Climate Locations," Energies, MDPI, vol. 12(4), pages 1-14, February.
    2. Rickard Erlund & Ron Zevenhoven, 2020. "Simulations on Design and System Performance of Building Heating Boosted by Thermal Energy Storage (TES) with Magnesium Hydro Carbonates/Silica Gel," Energies, MDPI, vol. 13(17), pages 1-14, September.
    3. Amiri, Leyla & de Brito, Marco Antonio Rodrigues & Baidya, Durjoy & Kuyuk, Ali Fahrettin & Ghoreishi-Madiseh, Seyed Ali & Sasmito, Agus P. & Hassani, Ferri P., 2019. "Numerical investigation of rock-pile based waste heat storage for remote communities in cold climates," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    4. Yi Yuan & Yingjie Li & Jianli Zhao, 2018. "Development on Thermochemical Energy Storage Based on CaO-Based Materials: A Review," Sustainability, MDPI, vol. 10(8), pages 1-24, July.

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